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Optical properties of gold nano-square plates synthesized in dynamic phase separating media of 2-butoxyethanol water

Research Project

Project/Area Number 23710117
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials/Nanobioscience
Research InstitutionTohoku University

Principal Investigator

KAJIMOTO Shinji  東北大学, 理学(系)研究科(研究院), 助教 (80463769)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords金ナノ構造体 / レーザー合成 / 相分離 / 反応場 / 金ナノ粒子 / ナノ秒レーザー / レーザー光化学 / ナノ反応場 / ナノ粒子 / 相分離過程 / ダイナミクス / レーザー誘起 / 金属ナノ構造体
Research Abstract

The formation and growth mechanism and the optical property of gold nano-square plates synthesized via laser-induced photo-reduction gold ions in dynamic phase separating media were investigated. Phase separation was initiated by a nanosecond IR pulse, and after certain delay time, a UV pulse was introduced to induce photo-reduction in phase separating media, leading the formation of gold nanostructures. Based on the irradiation time and delay time dependence of the size distribution of gold nano-square plates synthesized, we concluded that the growth process of nano-squares by repetitive irradiation of IR and UV pulses was governed by the size of nanophases during phase separation. Optical properties of gold nano-square plates were also investigated. By taking SEM images, dark field images and scattering spectra of the same nanostructures, the size and orientation dependence of optical property was determined.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (39 results)

All 2014 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (28 results) (of which Invited: 9 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Picosecond Dynamics of Hydrogen Bond Rearrangements During Phase Separation of a Triethylamine and Water Mixture2014

    • Author(s)
      S. Kajimoto, N.-H. Seong, H. Fukumura, D. D. Dlott
    • Journal Title

      Photoch Photobio Sci

      Volume: (In press) Issue: 6 Pages: 891-897

    • DOI

      10.1039/c4pp00048j

    • Related Report
      2013 Final Research Report
  • [Journal Article] Bias Voltage-Dependent STM-Tip-Enhanced Raman Spectroscopy of Benzenethiol-Modified Gold Nanoplates2013

    • Author(s)
      Y. Fujita, N. N. Horimoto, S. Kajimoto, and H. Fukumura
    • Journal Title

      Chem. Phys. Lett.

      Volume: 582 Pages: 110-114

    • Related Report
      2013 Final Research Report
  • [Journal Article] Additive-Free Size-Controlled Synthesis of Gold Square Nanoplates Using Photochemical Reaction in Dynamic Phase-Separating Media2013

    • Author(s)
      S. Kajimoto, D. Shirasawa, N. N. Horimoto, H. Fukumura
    • Journal Title

      Langmuir

      Volume: 29 Pages: 5889-5895

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Journal Article] Excitation energy migration in yellow fluorescent protein (citrine) layers adsorbed on modified gold surfaces2013

    • Author(s)
      H. M. Yusoff, I. I. Rze.nicka, H. Hoshi, S. Kajimoto, N. N. Horimoto, K. Sogawa, and H. Fukumura
    • Journal Title

      Applied Surface Science

      Volume: 280 Pages: 776-782

    • Related Report
      2013 Final Research Report
  • [Journal Article] Bias voltage- dependent STM-tip-enhanced Raman spectroscopy of benzenethiol-modified gold nanoplates2013

    • Author(s)
      Fujita, Y.; Horimoto, N. N.; Kajimoto, S.; Fukumura, H.
    • Journal Title

      Chem. Phys. Lett.

      Volume: 582 Pages: 110-114

    • DOI

      10.1016/j.cplett.2013.07.028

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Excitation energy migration in yellow fluorescent protein (citrine) layers adsorbed on modified gold surfaces.2013

    • Author(s)
      Hanis Mohd Yusoff, Izabela I. Rzeznicka, Hirotaka Hoshi, Shinji Kajimoto, Noriko Nishizawa Horimoto, Kazuhiro Sogawa, Hiroshi Fukumura
    • Journal Title

      Applied Surface Science

      Volume: 280 Pages: 776-782

    • DOI

      10.1016/j.apsusc.2013.05.060

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] VUV Luminescence With Nd Doped KCaF3 Under X-Ray Excitation2012

    • Author(s)
      Noriaki Kawaguchi, Takayuki Yanagida, Yutaka Fujimoto, Yoshisuke Futami, Kentaro Fukuda, Shinji Kajimoto, Hiroshi Fukumura, Yuui Yokota, and Akira Yoshikawa
    • Journal Title

      IEEE TRANSACTIONS ON NUCLEAR SCIENCE

      Volume: 59 Issue: 5 Pages: 2183-2187

    • DOI

      10.1109/tns.2012.2212459

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dynamics of Volume Expansion of De-Mixing Liquids after Pulsed IR Heating2011

    • Author(s)
      J. Hobley, S. Gorelik, Y. Kuge, S. Kajimoto, M. Kasuya, K. Hatanaka, and H. Fukumura
    • Journal Title

      Australian Journal of Chemistry

      Volume: 64 Pages: 1274-1281

    • Related Report
      2013 Final Research Report
  • [Journal Article] Dynamics of volume expansion od de-mixing liquids after pulse IR heating2011

    • Author(s)
      J. Hobley, S. Gorelik, Y. Kuge, S. Kajimoto, M. Kasuya, K. Hatanaka, H. Fukumura
    • Journal Title

      Australian Journal of Chemistry

      Volume: 64 Issue: 9 Pages: 1272-1279

    • DOI

      10.1071/ch11171

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Hydrogen-Bond Breaking during Phase Separation in Triethylamine-Water Mixture : A Molecular Dynamics Study2013

    • Author(s)
      S. Kajimoto
    • Organizer
      Satellite Meeting of ICMS 2013
    • Place of Presentation
      Sendai(依頼講演)
    • Year and Date
      2013-11-22
    • Related Report
      2013 Final Research Report
  • [Presentation] 相分離過程に現れる溶液内ナノ構造を反応場とした金属ナノ粒子作製2013

    • Author(s)
      梶本真司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2013-10-22
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 相分離溶液を反応場として作製した(100)面を持つ金ナノ四角プレートの光学特性の評価2013

    • Author(s)
      岡本隆志,白澤大輔,梶本真司,福村裕史
    • Organizer
      光化学討論会
    • Place of Presentation
      愛媛大学,松山
    • Year and Date
      2013-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Photochemical synthesis of metal nanoparticles in dynamic and static solution of water and butoxyethanol; the mechanism studied by transient absorption2013

    • Author(s)
      S. Kajimoto, D. Shirasawa, U. Y. Qazi, S. Kim, H. Fukumura (Tohoku Univ.)
    • Organizer
      IPC2013
    • Place of Presentation
      Leuven, Belgium
    • Related Report
      2013 Final Research Report
  • [Presentation] Photo-synthesis of metal nano-particles in phase separating media and aqueous solution2013

    • Author(s)
      S. Kajimoto
    • Organizer
      Collaborative Conference on Materials Research
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Photo-synthesis of gold nanoparticles in dynamic phase separating media and aqueous solutions2013

    • Author(s)
      Shinji Kajimoto, Daisuke Shirasawa, Umair Yaqub Qazi, Hiroshi Fukumura
    • Organizer
      the collaborative conference on Materials Research (CCMR) 2013
    • Place of Presentation
      Jeju Island, South Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Photochemical synthesis of metal nanoparticles in dynamic and static solution of water and butoxyethanol; the mechanism studied by transient absorption2013

    • Author(s)
      Shinji Kajimoto, Daisuke Shirasawa, Umair Yaqub Qazi, Sungjae Kim, Makoto Hanagata, Hiroshi Fukumura
    • Organizer
      International Conference on Photochemistry (ICP2013)
    • Place of Presentation
      Leuven, Belgium
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fluorescence lifetime changes of dyes nearby gold nanowires due to plasmon excitation revealed by two-colour laser experiment2013

    • Author(s)
      Shinji Kajimoto, Yusuke Chiba, Chio Ishida, Noriko Horimoto, Hiroshi Fukumura
    • Organizer
      International Conference on Photochemistry (ICP2013)
    • Place of Presentation
      Leuven, Belgium
    • Related Report
      2013 Annual Research Report
  • [Presentation] 相分離溶液を反応場として作製した(100)面を持つ金ナノ四角プレート の光学特性の評価2013

    • Author(s)
      岡本 隆志, 白澤 大輔, 梶本 真司, 福村 裕史
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      松山,愛媛
    • Related Report
      2013 Annual Research Report
  • [Presentation] 相分離過程に現れる溶液内ナノ構造を反応場とした金属ナノ粒子作製2013

    • Author(s)
      梶本真司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      船堀,東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Hydrogen-Bond Breaking during Phase Separation in Triethylamine-Water Mixture: A Molecular Dynamics Study2013

    • Author(s)
      Shinji Kajimoto
    • Organizer
      Satellite Meeting of ICMS2013 in Sendai "Molecular Simulation of Liquids and Interfaces”
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Photo-synthesis of gold nanoparticles in dynamic phase separating media and aqueous solutions2013

    • Author(s)
      Shinji Kajimoto, Daisuke Shirasawa, Umair Yaqub Qazi, Hiroshi Fukumura
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2013.
    • Place of Presentation
      Jeju Island, South Korea
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] レーザー誘起相分離初期過程における気泡の発生と発光現象2012

    • Author(s)
      梶本真司
    • Organizer
      東京工業大学応用セラミックス研究所ワークショップ「局所高密度励起の化学と応用」
    • Place of Presentation
      東京
    • Year and Date
      2012-12-07
    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Invited
  • [Presentation] Detergent-free synthesis of Au nano-square plates in dynamic nano-phases during laser-induced phase separation; Effect of repetitive laser-irradiation2012

    • Author(s)
      D. Shirasawa, S. Kajimoto, U. Qazi, H. Fukumura
    • Organizer
      ANGEL2012
    • Place of Presentation
      Sicily, Italy
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of repetitive laser-irradiation on gold nanocrystal synthesis in dynamic nano-phases during laser-induced phase separation2012

    • Author(s)
      D. Shirasawa, S. Kajimoto, H. Fukumura
    • Organizer
      IACIS2012
    • Place of Presentation
      Sendai
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of repetitive laser-irradiation on gold nanocrystal synthesis in dynamic nano-phases during laser-induced phase separation2012

    • Author(s)
      Daisuke Shirasawa, Shinji Kajimoto, Hiroshi Fukumura
    • Organizer
      IACIS2012(International Association of Colloid and Interface Scientists, Conference)
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Luminescence from bubbles formed by laser induced phase separation in water and 2-butoxyethanol mixtures2012

    • Author(s)
      Shuichi Toyouchi, Shinji Kajimoto, Hiroshi Fukumura
    • Organizer
      IACIS2012(International Association of Colloid and Interface Scientists, Conference)
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Detergent-free synthesis of Au nano-square plates in dynamic nano-phases during laser-induced phase separation; Effect of repetitive laser-irradiation2012

    • Author(s)
      Daisuke Shirasawa, Shinji Kajimoto, Umair Qazi, Hiroshi Fukumura
    • Organizer
      Angel 2012-2nd Conference on Laser Ablation and Nanoparticle Generation in Liquids
    • Place of Presentation
      Taormina, Italy
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of plasmon excitation on fluorescence lifetime of dye molecules nearby gold nanoparticles; two-color experiment2011

    • Author(s)
      S. Kajimoto
    • Organizer
      Workshop on characterizations for OPV materials and devices: part II
    • Place of Presentation
      Miyazaki
    • Year and Date
      2011-09-05
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 相分離状態において過渡的に現れる微小相を用いた銀・銅ナノ構造体の作製2011

    • Author(s)
      中村尭祉,白澤大輔,梶本真司,福村裕史
    • Organizer
      平成23年度化学系学協会東北大会
    • Place of Presentation
      仙台
    • Related Report
      2013 Final Research Report
  • [Presentation] レーザー誘起相分離過程にある溶液を反応場とした金属ナノ構造体の作製2011

    • Author(s)
      梶本真司 ,白澤大輔 ,中村尭祉 ,福村裕史
    • Organizer
      液相中の固体とレーザー光との相互作用:ナノ材料作製のための基礎から応用
    • Place of Presentation
      香川大学,高松
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Photo-fabrication of gold nano-square crystals in dynamic phase separating media2011

    • Author(s)
      S. Kajimoto, D. Shirasawa, T. Nakamura, H. Fukumura
    • Organizer
      E-MRS 2011 Spring Meeting
    • Place of Presentation
      Nice, France
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of plasmon excitation on fluorescence lifetime of dye molecules nearby gold nanopartcles; two-color experiment2011

    • Author(s)
      Shinji Kajimoto
    • Organizer
      International workshop on characterizations for OPV materials and devices(招待講演)
    • Place of Presentation
      Miyazaki
    • Related Report
      2011 Research-status Report
  • [Presentation] Photo-fabrication of gold nano-square crystals in dynamic phase separating media2011

    • Author(s)
      Shinji Kajimoto, Daisuke Shirasawa, Takashi Nakamura, Hiroshi Fukumura
    • Organizer
      E-MRS ICAM IUMRS 2011 Spring Meeting
    • Place of Presentation
      Nice, France
    • Related Report
      2011 Research-status Report
  • [Presentation] Development of nanosecond structured illumination microscopy for the observation of periodic nano-structures in solution2011

    • Author(s)
      Shuichi Toyouchi, Shinji Kajimoto, Kenta Kitabatake, Hiroshi Fukumura, Takanobu Kamijo, Yohji Akama, Motoko Kotani
    • Organizer
      ICMAT2011
    • Place of Presentation
      Singapore
    • Related Report
      2011 Research-status Report
  • [Presentation] レーザー誘起相分離過程にある溶液を反応場とした金属ナノ構造体の作製2011

    • Author(s)
      梶本 真司,白澤 大輔,中村 尭祉,福村 裕史
    • Organizer
      液相中の固体とレーザー光との相互作用:ナノ材料作製のための基礎から応用
    • Place of Presentation
      高松
    • Related Report
      2011 Research-status Report
  • [Presentation] 金ナノ構造体の表面プラズモン励起に伴う近傍色素分子の蛍光寿命の変化2011

    • Author(s)
      石田千緒,千葉裕介,梶本真司,堀本訓子,福村裕史
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Research-status Report
  • [Presentation] レーザー誘起相分離を反応場とした金ナノ結晶作製における繰り返し光照射の効果2011

    • Author(s)
      白澤大輔, 梶本真司, 福村裕史
    • Organizer
      第30回 固体・表面光化学討論会
    • Place of Presentation
      長野
    • Related Report
      2011 Research-status Report
  • [Book] "Photothermal Laser Material Interactions . From the Sledgehammer to Nano-GPS" in "Advances in Bio-Imageing: From Physics to Signal Understanding Issues", Edited by Nicolas Lomenie, Daniel Racoceanu, Alexandre Gouaillard2012

    • Author(s)
      J. Hobley, D. Paramelle, P. Free, D. G. Fenig, S. Kajimoto, S. Gorelik
    • Publisher
      Springer
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.opc.chem.tohoku.ac.jp/

    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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