Development of chiral organic conductor based on TTF-functionalized oligo(imidazole)-helicates
| Project/Area Number |
23750039
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
MURATA Tsuyoshi 大阪大学, 大学院・理学研究科, 招へい研究員 (40535358)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
|
|---|
| Keywords | 有機導体 / キラリティー / ヘリケート / 合成化学 / 有機導電体 |
|---|
| Research Abstract |
In order to explore multi-functional molecular materials by the combination of the helical chirality of oligoimidazole-helicates and TTF-based molecular conductors, we designed TTF-functionalized oligoimidazoles. We succeeded in the synthesis of a benzo-TTF substituted quaterimidazole, which selectively formed a dinuclear triple-helicate with Ni(II) ion. TTF skeletons of the helicate were oxidized with iodine to give a semiconducting salt.
|
Report
(3 results)
Research Products
(37 results)
