| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Research Abstract |
In order to explore multi-functional molecular materials by the combination of the helical chirality of oligoimidazole-helicates and TTF-based molecular conductors, we designed TTF-functionalized oligoimidazoles. We succeeded in the synthesis of a benzo-TTF substituted quaterimidazole, which selectively formed a dinuclear triple-helicate with Ni(II) ion. TTF skeletons of the helicate were oxidized with iodine to give a semiconducting salt.
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