| Project/Area Number |
23750042
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
NAGANO Takashi 高知大学, 教育研究部自然科学系, 助教 (80500587)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | グリーンケミストリー / 酸化反応 / 脱水素カップリング反応 / ハロゲン / ハロゲン化物イオン / CDC反応 / カップリング反応 |
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| Research Abstract |
We have studied on catalytic cross-dehydrogenative coupling (CDC) reaction using redox property of halide ions. In the course of this study, we have developed (i) intramolecular carbon-oxygen-bond-forming reaction using iodide ion/oxygen gas, (ii) intramolecular carbon-carbon-bond-forming reaction using iodide ion/TBHP, and (iii) alcohol oxidation using bromide ion/hydrogen peroxide.
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