Cooperative catalysis between deposited gold nanoparticles and metal oxide support

• Project/Area Number: 23750044
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Kyushu University
• Principal Investigator: HAMASAKI Akiyuki 九州大学, 大学院・理学研究院, 助教 (00515174)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
• Keywords: 金ナノ粒子 / 金属酸化物 / ワンポット反応 / 酸化銅担体 / カップリング反応 / 銅触媒

Research Abstract

A development of novel catalytic system consisted of copper oxide and gold nanoparticles was attempted. In this system, a cooperative catalysis of deposited gold and copper support was expected. A synthesis of indole derivatives via copper-catalyzed Sonogashira-Hagihara coupling and subsequent gold-catalyzed hydrogenation-cyclization sequence was investigated with copper oxide supported gold nanoparticles.

Research Products

• [Journal Article] Promotion Effects of Gold Nanoparticles on the Generation of Active Co(0) and Ni(0) Species (2012)
  • Author(s): Akiyuki Hamasaki, Hiroaki Nishikawa, Xiaohao Liu, Tamao Ishida, Makoto Tokunaga
  • Journal Title: Kyushu University Global-COE program Science for Future Molecular Systems Journal Volume: 5 Pages: 37-40
• [Journal Article] Promotion Effects of Gold Nanoparticles on the Generation of Active Co(0) and Ni(0) Species (2012)
  • Author(s): Akiyuki Hamasakiほか4名
  • Journal Title: Science for Future Molecular Systems, G-COE jounal Volume: 5 Pages: 37-40
• [Journal Article] Cobalt oxide supported gold nanoparticles as a stable and readily-prepared precursor for the in situ generation of cobalt carbonyl like species (2011)
  • Author(s): Hamasaki, A.; Muto, A.; Haraguchi, S.; Liu, X.; Sakakibara, T.; Yokoyama, T.; Tokunaga, M.
  • Journal Title: Tetrahedron Lett. Volume: 52 Issue: 51 Pages: 6869-6872
  • DOI: 10.1016/j.tetlet.2011.09.067
  • Peer Reviewed
• [Journal Article] Anti-ASF distribution in Fischer-Tropsch Synthesis over Unsupported Cobalt Catalysts in a Batch Slurry Phase Reactor (2011)
  • Author(s): Liu, X.; Hamasaki, A.; Honma, T.; Tokunaga, M.
  • Journal Title: Catal.Today Volume: 175 Issue: 1 Pages: 494-503
  • DOI: 10.1016/j.cattod.2011.03.030
  • Peer Reviewed
• [Presentation] パラジウムナノ粒子と酸化コバルト担体の協奏的触媒作用によるヨウ化アリールのホルミル化 (2012)
  • Author(s): 安武 裕太郎, 則尾 貴史, 濱崎 昭行, 石田 玉青, 大橋 弘範, 横山 拓史, 秋田 知樹, 本間 徹生, 徳永 信
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 佐賀市
  • Year and Date: 2012-11-10
• [Presentation] Carbonylation Reactions using Cobalt Oxide Supported Gold Nanoparticles as Alternative Catalyst for Dicobalt Octacarbonyl (2012)
  • Author(s): Akiyuki Hamasaki, Akiko Muto, Shingo Haraguchi, Xiaohao Liu, Tetsuo Honma, Tamao Ishida, Makoto Tokunaga
  • Organizer: The 6th International Conference on Gold Science、Technology and its Applications (Gold2012)
  • Place of Presentation: 東京都
  • Year and Date: 2012-09-06
• [Presentation] 酸化コバルト担持パラジウム触媒によるヨウ化アリールのホルミル化 (2012)
  • Author(s): 安武 裕太郎, 則尾 貴史, 濱崎 昭行, 石田 玉青, 大橋 弘範, 横山 拓史, 秋田 知樹, 本間 徹生, 徳永 信
  • Organizer: 日本化学会第92 春季年会
  • Place of Presentation: 横浜市
  • Year and Date: 2012-03-25
• [Presentation] コバルト酸化物担持ナノ粒子触媒を用いたカルボニル化反応 (2012)
  • Author(s): 武藤亜希子、濱崎昭行、石田玉青、徳永信
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県）
• [Presentation] 酸化コバルト担持パラジウム触媒によるヨウ化アリールのホルミル化 (2012)
  • Author(s): 安武裕太郎、則尾貴史、濱崎昭行、石田玉青、大橋弘範、横山拓史、秋田知樹、本間徹生、徳永信
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県）
• [Presentation] 沈殿法により調製した銅固体触媒を用いた薗頭-萩原カップリング反応 (2011)
  • Author(s): 安武 裕太郎, 濱崎 昭行, 石田 玉青, 徳永 信
  • Organizer: 第48回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2011-05-09
• [Presentation] 沈殿法により調製した銅固体触媒を用いた薗頭-萩原カップリング反応 (2011)
  • Author(s): 安武裕太郎、濱崎昭行、石田玉青、徳永信
  • Organizer: 第48回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場（北九州市）
• [Presentation] パラジウムナノ粒子と酸化コバルト担体の協奏的触媒作用によるヨウ化アリールのホルミル化
  • Author(s): 安武裕太郎ほか8名
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 佐賀市
• [Presentation] Carbonylation Reactions using Cobalt Oxide Supported Gold Nanoparticles as Alternative Catalyst for Dicobalt Octacarbonyl
  • Author(s): Akiyuki Hamasakiほか6名
  • Organizer: The 6th International Conference on Gold Science, Technology and its Applications (Gold2012)
  • Place of Presentation: 東京都