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Creation of novel π-electron materials with peculiar polarized structures

Research Project

Project/Area Number 23750045
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

TAKASE Masayoshi  首都大学東京, 大学院・理工学研究科, 助教 (90516121)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsπ電子共役系 / ピロール / シクロファン / ドナー・アクセプター
Research Abstract

In this study, we have studied on the synthesis and physical characterization of novel π-electron materials with peculiar electron structures in their neutral and redox states. As the results
(1) a series of extended disk-shaped π-system composed of pyrroles and benzenes were synthesized and characterized, and
(2) conceptually new donor-acceptor segregated cyclophanes were developed.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (40 results)

All 2013 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (34 results) (of which Invited: 1 results) Book (1 results)

  • [Journal Article] Pyrrole-Fused Azacoronene Family: The Influence of Replacement with Dialkoxybenzenes on the Optical and Electronic Properties in Neutral and Oxidized States2013

    • Author(s)
      M. Takase, T. Narita, W. Fujita, M. S. Asano, T. Nishinaga, H. Benten, K. Yoza, K. Mullen
    • Journal Title

      J. Am. Chem. Soc

      Volume: (印刷中)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sterically Congested Pyrrole-fused Tetrathiafulvalene Decamers as Highly Conductive Amorphous Molecular Materials2012

    • Author(s)
      M. Takase, N. Yoshida, T. Narita, T. Fujio, T. Nishinaga, M. Iyoda
    • Journal Title

      RSC Adv

      Volume: 2 Pages: 3221-3224

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sterically congested pyrrole-fused tetrathiafulvalene decamers as highly conductive amorphous molecular materials2012

    • Author(s)
      M. Takase
    • Journal Title

      RSC Advances

      Volume: 2 Issue: 8 Pages: 3221-3224

    • DOI

      10.1039/c2ra00035k

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Controlled Self-Assembly of Covalently Linked Hexa- peri-hexabenzocoronene/Perylene Diimide Dyads as Models To Study Fundamental Energy and Electron Transfer Processes2012

    • Author(s)
      L. F.Dössel, V. Kamm,I. A.Howard,F. Laquai, W. Pisula, X. Feng, C. Li, M. Takase, T. Kudernac, S. De Feyter, K. Müllen
    • Journal Title

      Journal of American Chemical Society

      Volume: 134 Issue: 13 Pages: 5876-5886

    • DOI

      10.1021/ja211504a

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Star-shaped Pyrrole-fused Tatrathiafulvalene Oligomers: Synthesis and Redox, Self-assembling, and Conductive Properties2011

    • Author(s)
      M. Takase, N. Yoshida, T. Nishinaga, M. Iyoda
    • Journal Title

      Org. Lett

      Volume: 13 Pages: 3896-3899

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] ピロール縮環アザコロネン類縁体の構造物性相関2013

    • Author(s)
      成田智幸, 高瀬雅祥, 西長 亨, 野村琴広, Klaus Mullen
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      草津
    • Related Report
      2012 Final Research Report
  • [Presentation] スタックしたフルオロアレーン部位を有するドナー・アクセプター分離型π電子系の合成と物性2013

    • Author(s)
      菅原由紀, 稲邊あゆみ, 高瀬雅祥, 西長亨, 野村琴広
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      草津
    • Related Report
      2012 Final Research Report
  • [Presentation] ピロール縮環アザコロネン類縁体の構造物性相関2013

    • Author(s)
      成田智幸, 高瀬雅祥, 西長 亨, 野村琴広, Klaus Muellen
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Related Report
      2012 Annual Research Report
  • [Presentation] スタックしたフルオロアレーン部位を有するドナー・アクセプター分離型π電子系の合成と物性2013

    • Author(s)
      菅原由紀, 稲邊あゆみ, 高瀬雅祥, 西長 亨, 野村琴広
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and properties of pyrrole-fused azacoronene family in neutral and oxidation states2012

    • Author(s)
      M. Takase, T. Narita, T. Nishinaga, K. Nomura, K. Mullen
    • Organizer
      International Symposium on Electronic/Optic Functional Molecules (ISEOFM2012)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2012 Final Research Report
  • [Presentation] 内部窒素原子に由来したピロール縮環アザコロネン類の物性変化2012

    • Author(s)
      成田智幸, 高瀬雅祥, 西長 亨, 野村琴広, Klaus Mullen
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] ドナー・アクセプター分離型シクロファン類の合成と物性2012

    • Author(s)
      稲邊あゆみ, 高瀬雅祥, 西長 亨, 野村琴広
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] ナフトビピロールで架橋されたクリップ型分子の合成2012

    • Author(s)
      菅原由紀, 稲邊あゆみ, 高瀬雅祥, 西長亨, 野村琴広
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] Pyrrole-containing functional π-electron materials2012

    • Author(s)
      M. Takase
    • Organizer
      7th International Symposium on High-Tech Polymer Materials (HTPM-VII)
    • Place of Presentation
      Shaanxi, China
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Pyrrole-fused azacoronenes: influence of dialkoxyphenyl rings on optical and electronic properties in neutral and oxidation states2012

    • Author(s)
      M. Takase, T. Narita, T. Nishinaga, K. Nomura, K. Mullen
    • Organizer
      IUMRS-International Conference on Electronic Materials (IUMRS-ICEM 2012)
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 酸化還元特性を有するピロール縮環アザコロネン類の合成と性質2012

    • Author(s)
      成田智幸, 高瀬雅祥, 西長 亨, 野村琴広, Klaus Mullen
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Synthesis and properties of pyrrole-fused azacoronenes in neutral and oxidationstates2012

    • Author(s)
      M. Takase
    • Organizer
      International Conference on Emerging Advanced Nanomaterials (ICEAN-2012)
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Final Research Report
  • [Presentation] ピロール縮環アザコロネン類の合成と物性2012

    • Author(s)
      高瀬雅祥, 成田智幸, 西長 亨, 野村琴広, Klaus Mullen
    • Organizer
      第39回有機典型元素化学討論会
    • Place of Presentation
      盛岡
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] ドナー・アクセプター部位を有するナフトビピロール類の合成2012

    • Author(s)
      菅原由紀, 稲邊あゆみ, 高瀬雅祥, 西長亨, 野村琴広
    • Organizer
      第6回有機π電子系シンポジウム
    • Place of Presentation
      松山
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and properties of pyrrole-fused azacoronenes in neutral and oxidation states2012

    • Author(s)
      M. Takase
    • Organizer
      International Conference on Emerging Advanced Nanomaterials (ICEAN-2012)
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Properties of Pyrrole-Fused Azacoronene Family in Neutral and Oxidation States2012

    • Author(s)
      M. Takase, T. Narita, T. Nishinaga, K. Nomura, K. Muellen
    • Organizer
      International Symposium on Electronic/Optic Functional Molecules (ISEOFM2012)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2011 Research-status Report
  • [Presentation] Synthesis and Properties of Nitrogen-Containing pi-Electron Materials: Design, Synthesis, and Properties2012

    • Author(s)
      M. Takase
    • Organizer
      Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences(招待講演)
    • Place of Presentation
      Suzhou, China
    • Related Report
      2011 Research-status Report
  • [Presentation] ドナー・アクセプター界面を有するヘキサアザトリナフタレンの合成と物性2012

    • Author(s)
      藤尾隆史, 高瀬雅祥, 西長 亨, 伊與田正彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report
  • [Presentation] Synthesis and Properties of Donor-Acceptor Segregated Cyclophanes2011

    • Author(s)
      M. Takase, T. Narita, T. Nishinaga, K. Nomura, K. Mullen
    • Organizer
      14th International Symposium on Novel Aromatic Compounds (ISNA-14)
    • Place of Presentation
      Eugene, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] ピロール縮環テトラチアフルバレンオリゴマーの合成と物性2011

    • Author(s)
      高瀬雅祥, 吉田尚史, 西長 亨, 野村琴広
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] ピロール縮環アザコロネン類の構造物性相関2011

    • Author(s)
      成田智幸, 西長 亨, 野村琴広, Klaus Mullen
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] Bergman 環化反応を利用したジチエノ[a,c]アントラセン誘導体の合成と物性2011

    • Author(s)
      長谷山かほり, 高瀬雅祥, 西長 亨, 伊與田正彦
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] S_Nar 反応を利用したドナー・アクセプター分離型シクロファンの合成と物性2011

    • Author(s)
      稲邊あゆみ, 高瀬雅祥, 西長 亨, 野村琴広
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and properties of nitrogen-incorporated large π-systems2011

    • Author(s)
      T. Narita, M. Takase, T. Nishinaga, K. Nomura, K. Mullen
    • Organizer
      International Symposium on Functional π-Electron Systems (Fπ-10)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Final Research Report
  • [Presentation] Pyrrole-Fused Tetrathiafulvalene Oligomers: Synthesis and Properties2011

    • Author(s)
      M. Takase, N. Yoshida, T. Nishinaga, M. Iyoda
    • Organizer
      International Symposium on Functional π-Electron Systems (Fπ-10)
    • Place of Presentation
      Beijing, China
    • Related Report
      2012 Final Research Report
  • [Presentation] ドナー・アクセプター界面を有する含窒素縮合ヘテロ環の合成と物性2011

    • Author(s)
      藤尾隆史, 西長 亨, 伊與田正彦
    • Organizer
      第38回有機典型元素化学討論会
    • Place of Presentation
      金沢
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] Synthesis and Properties of Donor-Acceptor Segregated Cyclophanes2011

    • Author(s)
      M. Takase, A. Inabe, T. Nishinaga, K. Nomura
    • Organizer
      14th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Eugene, USA
    • Related Report
      2011 Research-status Report
  • [Presentation] 分子内にドナー・アクセプター界面を有するディスク状分子の合成と物性2011

    • Author(s)
      藤尾隆史,高瀬雅祥,西長 亨,伊與田正彦
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京
    • Related Report
      2011 Research-status Report
  • [Presentation] 芳香族求核置換反応を利用したドナー・アクセプター分離型シクロファンの合成と物性2011

    • Author(s)
      稲邊あゆみ,高瀬雅祥,西長 亨,野村琴広
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京
    • Related Report
      2011 Research-status Report
  • [Presentation] SNAr反応を利用したドナー・アクセプター分離型シクロファンの合成と物性2011

    • Author(s)
      稲邊あゆみ,高瀬雅祥,西長 亨,野村琴広
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2011 Research-status Report
  • [Presentation] Synthesis and properties of nitrogen-incorpolated large pi-systems2011

    • Author(s)
      T. Narita, M. Takase, T. Nishinaga, K. Nomura, K. Müllen
    • Organizer
      International Symposium on Functional pi-Electron Systems (Fpi10)
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Research-status Report
  • [Presentation] Pyrrole-Fused Tetrathiafulvalene Oligomers: Synthesis and Properties2011

    • Author(s)
      M. Takase, N. Yoshida, T. Nishinaga, M. Iyoda
    • Organizer
      International Symposium on Functional pi-Electron Systems (Fpi10)
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Research-status Report
  • [Presentation] Pyrrole-containing pi-electron materials: Design, synthesis, properties2011

    • Author(s)
      M. Takase
    • Organizer
      Institute of Chemistry, Chinese Academy of Sciences(招待講演)
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Research-status Report
  • [Presentation] Pyrrole-containing pi-electron materials: Design, synthesis, properties2011

    • Author(s)
      M. Takase
    • Organizer
      Beijing University of Chemical Technology(招待講演)
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Research-status Report
  • [Book] Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry2011

    • Author(s)
      M. Iyoda, Y. Kuwatani, T. Nishinaga, M. Takase, T. Nishiuchi
    • Publisher
      Inc. NJ
    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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