| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
The chemistry of phosphinine, a heavier analogue of pyridine, has been studied extensively for a long time since the synthesis of the first stable phosphinine in 1966. In contrast to the chemistry of phosphinine, there have been limitedly reports on the synthesis and characterization of its polyaromatic analogue, such as phosphanaphthalenes and phosphaanthracenes. We report herein synthesis and novel property of a new type of phosphinines and phosphanaphthalenes. We have succeeded in the synthesis of polyaromatics containing a phosphorus atom by using carbon-phosphorus triple bond molecules as a key compound.
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