Development of helical metal complexes for strategic helicity inversion based on mechanical motion

• Project/Area Number: 23750055
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: University of Tsukuba
• Principal Investigator: AKINE Shigehisa 筑波大学, 数理物質系, 准教授 (30323265)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: 超分子化学 / らせん構造 / 分子機械 / 金属錯体 / 分子認識 / 金属交換 / らせん型錯体 / 多核錯体 / 亜鉛 / ランタニド

Research Abstract

A molecular system that allows strategic helicity inversion based on molecular machine mechanism was developed. A single-helical metal complex bearing two crown ether moieties was synthesized. Upon interaction with alkanediammonium salts with different chain lengths, the distance between the two crown ether moieties was altered. Associated with the structural change, inversion of the helical handedness of the metal complex took place (right-handed with shorter guests; left-handed with longer guests).

Research Products

• [Journal Article] Ligand Modification of Cyclometalated Ruthenium Complexes in the Aerobic Oxidative Dehydrogenation of Imidazolines (2013)
  • Author(s): Aiki, S.; Kijima, Y.; Kuwabara, J.; Taketoshi, A.; Koizumi, T.; Akine, S.; Kanbara, T
  • Journal Title: ACS Catal Volume: 3 Issue: 5 Pages: 812-816
  • DOI: 10.1021/cs300811w
  • Peer Reviewed
• [Journal Article] Conformational control of electron-rich calix[6]arene skeleton by paraquat recognition (2013)
  • Author(s): Akine, S.; Kusama, D.; Nabeshima, T
  • Journal Title: Tetrahedron Lett Volume: 54 Issue: 3 Pages: 205-209
  • DOI: 10.1016/j.tetlet.2012.10.105
  • Peer Reviewed
• [Journal Article] Oligometallic Template Strategy for Synthesis of a Macrocyclic Dimer-Type Octaoxime Ligand for Its Cooperative Complexation (2012)
  • Author(s): Akine, S.; Tadokoro, T.; Nabeshima, T
  • Journal Title: Inorg. Chem Volume: 51 Issue: 21 Pages: 11478-11486
  • DOI: 10.1021/ic3012525
  • Peer Reviewed
• [Journal Article] Design and controlled emission properties of bioorganometallic compounds composed of uracils and organoplatinum(II) moieties (2012)
  • Author(s): Moriuchi, T.; Sakamoto, Y.; Noguchi, S.; Fujiwara, T.; Akine, S.; Nabeshima, T.; Hirao, T
  • Journal Title: Dalton Trans Volume: 41 Issue: 28 Pages: 8524-8531
  • DOI: 10.1039/c2dt30533j
  • Peer Reviewed
• [Journal Article] Hierarchical Helix of Helix in the Crystal: Formation of Variable-Pitch Helical π-Stacked Array of Single-Helical Dinuclear Metal Complexes (2012)
  • Author(s): Akine, S.; Nagumo, H.; Nabeshima, T
  • Journal Title: Inorg. Chem Volume: 51 Issue: 10 Pages: 5506-5508
  • DOI: 10.1021/ic3004273
  • Peer Reviewed
• [Journal Article] Novel Ion Recognition Systems Based on Cyclic and Acyclic Oligo(salen)-type Ligands (2012)
  • Author(s): Akine, S.
  • Journal Title: J.Inclusion Phenom.Macrocycl.Chem. Volume: 72 Issue: 1-2 Pages: 25-54
  • DOI: 10.1007/s10847-011-0026-3
  • Peer Reviewed
• [Journal Article] Remarkably Selective Recognition of Iodobenzene Derivatives by a Macrocyclic Bis-Pt^<II> Metallohost (2011)
  • Author(s): Trokowski, R.; Akine, S; Nabeshima, T.
  • Journal Title: Chem.Eur.J. Volume: 17 Issue: 51 Pages: 14420-14428
  • DOI: 10.1002/chem.201101650
  • Peer Reviewed
• [Journal Article] A Molecular Leverage for Helicity Control and Helix Inversion (2011)
  • Author(s): Akine, S.; Hotate, S.; Nabeshima, T.
  • Journal Title: J.Am.Chem.Soc. Volume: 133 Issue: 35 Pages: 13868-13871
  • DOI: 10.1021/ja205570z
  • Peer Reviewed
• [Journal Article] Highly Cooperative Double Metalation of a Bis(N_2O_2) Ligand Based on Bipyridine-Phenol Framework Driven by Intramolecular π-Stacking of Square Planar Nickel(II) Complex Moieties (2011)
  • Author(s): Akine, S.; Shimada, T.; Nagumo, H.; Nabeshima, T.
  • Journal Title: Dalton Trans. Volume: 40 Issue: 34 Pages: 8507-8509
  • DOI: 10.1039/c1dt10124b
  • Peer Reviewed
• [Journal Article] Nuclearity Control of a Trisaloph Zinc Cluster Complex Dependent on Minute Structural Differences in the Bridging Anions (2011)
  • Author(s): Yamamura, M.; Miyazaki, H.; Iida, M.; Akine, S.; Nabeshima, T.
  • Journal Title: Inorg.Chem. Volume: 50 Issue: 12 Pages: 5315-5317
  • DOI: 10.1021/ic2002833
  • Peer Reviewed
• [Journal Article] Multistep Oligometal Complexation of the Macrocyclic Tris(N_2O_2) Hexaoxime Ligand (2011)
  • Author(s): Akine, S.; Sunaga, S.; Nabeshima, T.
  • Journal Title: Chem.Eur.J. Volume: 17 Issue: 24 Pages: 6853-6861
  • DOI: 10.1002/chem.201100122
  • Peer Reviewed
• [Journal Article] Wheel-shaped Er^<III>Zn^<II>_3 Sinele-Molecule Magnet : A Macrocyclic Approch to Designing Magnetic Anisotropy (2011)
  • Author(s): T.Kajiwara, et al
  • Journal Title: Angew.Chem.Int.Ed. Volume: 50 Issue: 17 Pages: 4016-4019
  • DOI: 10.1002/anie.201008180
  • Peer Reviewed
• [Journal Article] Synthesis of Acyclic Tetrakis-and Pentakis(N2O2) Ligands for Single-helical Heterometallic Complexes with a Greater Number of Winding Turns (2011)
  • Author(s): Akine, S.; Matsumoto, T.; Sairenji, S.; Nabeshima, T
  • Journal Title: Supramol. Chem Volume: 23 Issue: 1-2 Pages: 106-112
  • DOI: 10.1080/10610278.2010.514906
  • Peer Reviewed
• [Journal Article] Spontaneous Enrichment of One-handed Helices by Dissolution of Quasiracemic Crystals of a Tetranuclear Single Helical Complex (2011)
  • Author(s): Akine, S.; Hotate, S.; Matsumoto, T.; Nabeshima, T
  • Journal Title: Chem. Commun Volume: 47 Issue: 10 Pages: 2925-2927
  • DOI: 10.1039/c0cc04998k
  • Peer Reviewed
• [Presentation] 化学変換を活用したらせん型ヘキサオキシム多核錯体の動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学,草津
  • Year and Date: 2013-03-24
• [Presentation] らせん構造をもつクリプタンド型Trisalophメタロホストの合成とゲスト認識 (2013)
  • Author(s): 宮下真人・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学,草津
  • Year and Date: 2013-03-24
• [Presentation] らせん型多核錯体の合成・機能と動的ヘリシティー制御 (2013)
  • Author(s): 秋根茂久
  • Organizer: 第13回リング・チューブ超分子研究会
  • Place of Presentation: 東京工業大学 ,横浜
  • Year and Date: 2013-02-23
• [Presentation] らせん型多核錯体の合成・機能と動的ヘリシティー制御 (2013)
  • Author(s): 秋根茂久
  • Organizer: 第13回リング・チューブ超分子研究会
  • Place of Presentation: 東京工業大学，横浜市
  • Invited
• [Presentation] らせん構造をもつクリプタンド型Trisalophメタロホストの合成とゲスト認識 (2013)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学，草津市
• [Presentation] 化学変換を活用したらせん型ヘキサオキシム多核錯体の動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学，草津市
• [Presentation] Multi-step Helicity Inversion of Helical Metallofoldamers by Metal Exchange (2012)
  • Author(s): Shiho Sairenji, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creationof Functional Materials
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2012-12-10
• [Presentation] Synthesis of Cage-like Trisaloph Metallohost and Guest Recognition (2012)
  • Author(s): Masato Miyashita, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2012-12-10
• [Presentation] Helicity Control of Helical Metal Complexes by Molecular Leverage Mechanism (2012)
  • Author(s): Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
  • Place of Presentation: Rihga Royal Hotel Kyoto, Kyoto
  • Year and Date: 2012-11-15
• [Presentation] Controlling helical handedness of dynamic single-helical metal complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: Japan-India Bilateral Seminar on Supramolecular Nanomaterials for Energy Innovation
  • Place of Presentation: Alpha Anabuki Hall, Takamatsu
  • Year and Date: 2012-10-15
• [Presentation] らせん型ヘキサオキシム金属錯体を利用したヘリシティー制御・反転システム (2012)
  • Author(s): 西連地志穂・秋根茂久・鍋島達弥
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学,富山
  • Year and Date: 2012-09-22
• [Presentation] Strategic Helicity Control of Single-Helical Metal Complexes (2012)
  • Author(s): 秋根茂久
  • Organizer: 錯体化学会第62回討論会ミニシンポジウム
  • Place of Presentation: 富山大学,富山
  • Year and Date: 2012-09-21
• [Presentation] かご型trisaloph メタロホストの合成とゲスト認識 (2012)
  • Author(s): 宮下真人・秋根茂久・鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テルサ,京都
  • Year and Date: 2012-09-20
• [Presentation] Strategic Helicity Control of Helical Metal Complexes by Molecular Leverage (2012)
  • Author(s): Shigehisa Akine, Sayaka Hotate, Tatsuya Nabeshima
  • Organizer: The 40th International Conference on Coordination Chemistry (ICCC40)
  • Place of Presentation: Valencia Conference Centre, Valencia, Spain
  • Year and Date: 2012-09-10
• [Presentation] ジアンモニウム認識を駆動力とするらせん型錯体のヘリシティー制御 (2012)
  • Author(s): 秋根茂久・保立さやか・鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学,札幌
  • Year and Date: 2012-05-27
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ大環状ホスト分子による芳香族化合物の認識 (2012)
  • Author(s): 小沼孝大・秋根茂久・鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学,札幌
  • Year and Date: 2012-05-27
• [Presentation] Dynamic and Strategic Control of Helical Handedness of Helical Metal Complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: The 3rd Tsukuba International Mini-symposium on Hybridization between Main Group Element Chemistry and π-Electron Chemistry
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2012-05-19
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ新規な大環状化合物の合成とそのゲスト認識 (2012)
  • Author(s): 小沼孝大・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-28
• [Presentation] 直線状YbZn2,ホイール状YbZn3多核錯体における磁気異方性と遅い磁化緩和 (2012)
  • Author(s): 日野志織・前田萌絵・山下愛花・片岡悠美子・梶原孝志・秋根茂久・鍋島達弥・中野元裕・山村朝雄
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-28
• [Presentation] 金属イオン結合部位を導入したペンタセンキノンの合成と性質 (2012)
  • Author(s): 高槻百合・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-26
• [Presentation] 3 つのsaloph 部位を持つ新規なクリプタンド型配位子の合成 (2012)
  • Author(s): 宮下真人・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-26
• [Presentation] らせん型メタロフォルダマーの金属交換によるヘリシティー反転 (2012)
  • Author(s): 西連地志穂・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-25
• [Presentation] ペンチプチセン誘導体の自己集合による新規な環状化合物の合成 (2012)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学,横浜
  • Year and Date: 2012-03-25
• [Presentation] Strategic and Dynamic Helicity Control of Single-Helical Metal Complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: 2nd International Symposium on Creation of Functional Materials -Coordination Chemistry at the Front -
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2012-02-09
• [Presentation] Conformational Conversion of Calix[6]arenes Having Electron-donating Groups by Recognition of a Bipyridinium Salt (2012)
  • Author(s): Daisuke Kusama, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 2nd International Symposium on Creation of Functional Materials -Coordination Chemistry at the Front -
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2012-02-09
• [Presentation] Dynamic and Strategic Control of Helical Handedness of Helical Metal Complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: The 3rd Tsukuba International Mini-symposium on Hybridization between Main Group Element Chemistry and π-Electron Chemistry
  • Place of Presentation: University of Tsukuba, Tsukuba, Japan
  • Invited
• [Presentation] Strategic Helicity Control of Helical Metal Complexes by Molecular Leverage (2012)
  • Author(s): Shigehisa Akine, Sayaka Hotate, Tatsuya Nabeshima
  • Organizer: The 40th International Conference on Coordination Chemistry (ICCC40)
  • Place of Presentation: Valencia, Spain
• [Presentation] Controlling helical handedness of dynamic single-helical metal complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: Japan-India Bilateral Seminar on Supramolecular Nanomaterials for Energy Innovation
  • Place of Presentation: Alpha Anabuki Hall, Takamatsu, Japan
  • Invited
• [Presentation] Helicity Control of Helical Metal Complexes by Molecular Leverage Mechanism (2012)
  • Author(s): Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
  • Place of Presentation: Rihga Royal Hotel Kyoto, Kyoto, Japan
• [Presentation] Multi-step Helicity Inversion of Helical Metallofoldamers by Metal Exchange (2012)
  • Author(s): Shiho Sairenji, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba, Tsukuba, Japan
• [Presentation] Synthesis of Cage-like Trisaloph Metallohost and Guest Recognition (2012)
  • Author(s): Masato Miyashita, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba, Tsukuba, Japan
• [Presentation] ジアンモニウム認識を駆動力とするらせん型錯体のヘリシティー制御 (2012)
  • Author(s): 秋根茂久、保立さやか、鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学，札幌市
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ大環状ホスト分子による芳香族化合物の認識 (2012)
  • Author(s): 小沼孝大、秋根茂久、鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学，札幌市
• [Presentation] かご型trisalophメタロホストの合成とゲスト認識 (2012)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テルサ，京都市
• [Presentation] Strategic Helicity Control of Single-Helical Metal Complexes (2012)
  • Author(s): 秋根茂久
  • Organizer: 錯体化学会第62回討論会ミニシンポジウム“Supramolecular Systems for Materials Science by Coordination Chemistry”
  • Place of Presentation: 富山大学，富山市
  • Invited
• [Presentation] らせん型ヘキサオキシム金属錯体を利用したヘリシティー制御・反転システム (2012)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学，富山市
• [Presentation] Strategic and Dynamic Helicity Control of Single-Helical Metal Complexes (2012)
  • Author(s): Shigehisa Akine
  • Organizer: 2nd International Symposium on Creation of Functional Materials ― Coordination Chemistry at the Front ―(招待講演)
  • Place of Presentation: 筑波大学大学会館（つくば市）
• [Presentation] Conformational Conversion of Calix[6]arenes Having Electron-donating Groups by Recognition of a Bipyridinium Salt (2012)
  • Author(s): Daisuke Kusama, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 2nd International Symposium on Creation of Functional Materials ― Coordination Chemistry at the Front ―
  • Place of Presentation: 筑波大学大学会館（つくば市）
• [Presentation] らせん型メタロフォルダマーの金属交換によるヘリシティー反転 (2012)
  • Author(s): 西連地志穂・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] ペンチプチセン誘導体の自己集合による新規な環状化合物の合成 (2012)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ新規な大環状化合物の合成とそのゲスト認識 (2012)
  • Author(s): 小沼孝大・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] 直線状 YbZn2，ホイール状 YbZn3多核錯体における磁気異方性と遅い磁化緩和 (2012)
  • Author(s): 日野志織・前田萌絵・山下愛花・片岡悠美子・梶原孝志・秋根茂久・鍋島達弥・中野元裕・山村朝雄
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] 金属イオン結合部位を導入したペンタセンキノンの合成と性質 (2012)
  • Author(s): 高槻百合・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] 3 つの saloph 部位を持つ新規なクリプタンド型配位子の合成 (2012)
  • Author(s): 宮下真人・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学（横浜市）
• [Presentation] Induced-fit Recognition of Electron-poor Organic Guest by Calix[6]arenes Having Electron-donating Groups (2011)
  • Author(s): Daisuke Kusama, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 1st International Symposium on Creation of Functional Materials -Hybridization between Main Group Element Chemistry and π-Electron Chemistry -
  • Place of Presentation: University of Tsukuba, Tsukuba
  • Year and Date: 2011-12-17
• [Presentation] 動的特性を持つらせん型錯体の合成・機能とヘリシティー制御 (2011)
  • Author(s): 秋根茂久
  • Organizer: 錯体化学若手の会関東支部2011年度後期勉強会
  • Place of Presentation: 東京大学,東京
  • Year and Date: 2011-11-26
• [Presentation] 大環状サレン型配位子上における金属多核錯体の形成と架橋アニオン交換による精密構造制御 (2011)
  • Author(s): 山村正樹・飯田昌也・秋根茂久・鍋島達弥
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場
  • Year and Date: 2011-09-23
• [Presentation] ペンチプチセン骨格を有する新規な環状化合物の設計と合成 (2011)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場,つくば
  • Year and Date: 2011-09-22
• [Presentation] ホイール状LnZn3四核錯体における単分子磁石特性発現の希土類金属依存性 (2011)
  • Author(s): 山下愛花・渡辺明子・片岡悠美子・梶原孝志・秋根茂久・鍋島達弥・中野元裕・山村朝雄
  • Organizer: 体化学会第61回討論会
  • Place of Presentation: 岡山理科大学,岡山
  • Year and Date: 2011-09-18
• [Presentation] 分子てこ機構を活用した亜鉛(II)-ランタン(III)四核らせん型錯体のヘリシティー制御 (2011)
  • Author(s): 秋根茂久・保立さやか・鍋島達弥
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山理科大学,岡山
  • Year and Date: 2011-09-18
• [Presentation] キラルカルボン酸の配位による一重らせん型三核錯体の動的ヘリシティー制御 (2011)
  • Author(s): 秋根茂久・保立さやか・鍋島達弥
  • Organizer: 第5回バイオ関連化学シンポジウム
  • Place of Presentation: つくば国際会議場,つくば
  • Year and Date: 2011-09-12
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ新規な大環状配位子の設計と合成 (2011)
  • Author(s): 小沼孝大・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学,小金井
  • Year and Date: 2011-08-30
• [Presentation] 電子供与基を有するカリックス[6]アレーンのゲスト認識による配座の制御 (2011)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学,小金井
  • Year and Date: 2011-08-30
• [Presentation] π共役大環状配位子上に集積させた金属クラスター錯体の動的構造制御 (2011)
  • Author(s): 山村正樹・飯田昌也・秋根茂久・鍋島達弥
  • Organizer: 第7回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 広島大学,東広島
  • Year and Date: 2011-05-29
• [Presentation] Helicity control and dynamic helix inversion of single-helical zinc(II)-containing oligonuclear complexes (2011)
  • Author(s): Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: ISMSC 2011 -International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: University of Sussex, Brighton, UK
• [Presentation] Helicity control and dynamic helix inversion of single-helical zinc(II)-containing oligonuclear complexes (2011)
  • Author(s): Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: ISMSC 2011 - International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: Brighton, UK
• [Presentation] Induced-fit Recognition of Electron-poor Organic Guest by Calix[6]arenes Having Electron-donating Groups (2011)
  • Author(s): Daisuke Kusama, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 1st International Symposium on Creation of Functional Materials ― Hybridization between Main Group Element Chemistry and π-Electron Chemistry ―
  • Place of Presentation: 筑波大学大学会館（つくば市）
• [Presentation] π共役大環状配位子上に集積させた金属クラスター錯体の動的構造制御 (2011)
  • Author(s): 山村正樹・飯田昌也・秋根茂久・鍋島達弥
  • Organizer: 第7回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 広島大学（東広島市）
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ新規な大環状配位子の設計と合成 (2011)
  • Author(s): 小沼孝大・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学（小金井市）
• [Presentation] 電子供与基を有するカリックス[6]アレーンのゲスト認識による配座の制御 (2011)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 日本化学会第5回関東支部大会
  • Place of Presentation: 東京農工大学（小金井市）
• [Presentation] キラルカルボン酸の配位による一重らせん型三核錯体の動的ヘリシティー制御 (2011)
  • Author(s): 秋根茂久・保立さやか・鍋島達弥
  • Organizer: 第5回バイオ関連化学シンポジウム
  • Place of Presentation: つくば国際会議場（つくば市）
• [Presentation] ホイール状LnZn3四核錯体における単分子磁石特性発現の希土類金属依存性 (2011)
  • Author(s): 山下愛花・渡辺明子・片岡悠美子・梶原孝志・ 秋根茂久・鍋島達弥・中野元裕・山村朝雄
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山理科大学（岡山市）
• [Presentation] 分子てこ機構を活用した亜鉛(II)-ランタン(III)四核らせん型錯体のヘリシティー制御 (2011)
  • Author(s): 秋根茂久・保立さやか・鍋島達弥
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山理科大学（岡山市）
• [Presentation] 大環状サレン型配位子上における金属多核錯体の形成と架橋アニオン交換による精密構造制御 (2011)
  • Author(s): 山村正樹・飯田昌也・秋根茂久・鍋島達弥
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場（つくば市）
• [Presentation] ペンチプチセン骨格を有する新規な環状化合物の設計と合成 (2011)
  • Author(s): 草間大輔・秋根茂久・鍋島達弥
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場（つくば市）
• [Presentation] 動的特性を持つらせん型錯体の合成・機能とヘリシティー制御 (2011)
  • Author(s): 秋根茂久
  • Organizer: 若手の会関東支部2011年度後期勉強会(招待講演)
  • Place of Presentation: 東京大学（東京都）