| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
Organic-acetylide copper species which tend to afford cluster structures was exploited and developed a new orthogonal coupling reaction scheme converted merely by a input value of electric potential applied to copper.
It has been a general strategy to obtain desired structures by tuning of the molecular catalyst structure, but we propose direct link of an electric potential value (external stimuli) and to an optional coupling pair among several candidate.When applied two different potential, ethynyl moiety immobilized on carbon electrode coupled with different pair substrate, and these two reaction were orthogonally active upon the applied potential value.
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