Development of dehydrogenative group 14 element-boran bond formation reaction catalyzed by an iron complex
| Project/Area Number |
23750063
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
ITAZAKI Masumi 大阪市立大学, 大学院・理学研究科, 講師 (60382032)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 有機金属化学 / 鉄触媒 / ヒドロシラン / ホウ素化合物 / 鉄錯体 / 触媒反応 / ホウ素 / 14 族元素 |
|---|
| Research Abstract |
Reaction of Cp(CO)Fe(GePh_3)(py) with HBpin afforded the iron(IV) hydrido complex Cp(CO)Fe(H)(GePh_3)(Bpin). On the other hand, photoreaction of HBpin with 3 equimolar amount of Et_3SiH for 3 days at 5 ℃ in the presence of 10 mol% of Cp(
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Report
(3 results)
Research Products
(45 results)
