| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
Rhodium and iridium complexes bearing a EP3- or PEP-type ligand (E = Si, Ge, Sn) were prepared. It should be noted that this synthetic method is the first exapmle to prepare GeP3, SnP3, PGeP, PSnP-type complexes. Systematic investigations using novel complexes enable to evaluate trans influence and electron donating ability of E; electron donating ability of E increases in the order Ge < Si < Sn and trans influence of E increases in the order Ge < Si = Sn. Further, we found that some of novel complexes catalized acceptorless dehydrogenation of ethanol.
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