Synthesis of novel pincer-type complexes: Their applications to catalytic reactions using ammonia
Project/Area Number |
23750064
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
|
Research Institution | Osaka Prefecture University (2013) Osaka City University (2011-2012) |
Principal Investigator |
KAMEO Hajime 大阪府立大学, 理学(系)研究科(研究院), 助教 (50597218)
|
Project Period (FY) |
2011 – 2013
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | 金属錯体 / 多座配位子 / 高電子供与性 / ゲルマニウム / スズ / 無機化学 / 錯体化学 / 有機金属化学 |
Research Abstract |
Rhodium and iridium complexes bearing a EP3- or PEP-type ligand (E = Si, Ge, Sn) were prepared. It should be noted that this synthetic method is the first exapmle to prepare GeP3, SnP3, PGeP, PSnP-type complexes. Systematic investigations using novel complexes enable to evaluate trans influence and electron donating ability of E; electron donating ability of E increases in the order Ge < Si < Sn and trans influence of E increases in the order Ge < Si = Sn. Further, we found that some of novel complexes catalized acceptorless dehydrogenation of ethanol.
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Report
(4 results)
Research Products
(57 results)