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Synthesis of Coordination Polymers with High Carrier Mobilities and Application to Field Effect Transistors

Research Project

Project/Area Number 23750066
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionKinki University

Principal Investigator

OKUBO Takashi  近畿大学, 理工学部, 准教授 (90322677)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords配位高分子 / 電界効果トランジスタ / キャリア移動度 / 強誘電性
Research Abstract

Recently, we determined that mixed-valence copper coordination polymers including a dithiocarbamate ligand and bromide or iodide anions exhibited semiconducting properties with relatively high carrier mobilities, and we have attempted to apply the coordination polymers to the semiconducting materials of field-effect transistors (FETs). In this research, we found that a FET device with a ferroelectric coordination polymer CuBrBu2D performed at extremely lower voltage than those of the conventional organic FETs. The carrier mobility estimated from the output characteristics was found to be 30.1 cm2/Vs, which was higher than that of amorphous silicon. In addition, this FET shows ambipolar FET characteristics in the measurements of the transfer characteristics.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (22 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 1 results) Presentation (12 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] μ9-Bromido-tetra-μ2-bromido-tris(μ4-azepa ne-1-carbodithioato)bis(μ3-azepane-1-carbo dithioato)octacopper(I)copper(II)2013

    • Author(s)
      Takashi Okubo, Haruho Anma, Masahiko Maekawa, and Takayoshi Kuroda-Sowa
    • Journal Title

      Acta Ctystallographica, Section E; Structure Reports Online

      Volume: E69

    • Related Report
      2012 Final Research Report
  • [Journal Article] Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand2013

    • Author(s)
      Takashi Okubo, Haruho Anma, Naoya Tanaka, Kento Himoto, Shu Seki, Akinori Saeki, Masahiko Maekawa and Takayoshi Kuroda-Sowa
    • Journal Title

      Chem. Commum.

      Volume: 49 Pages: 4316-4318

    • Related Report
      2012 Final Research Report
  • [Journal Article] Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I).Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand2012

    • Author(s)
      Takashi Okubo, Naoya Tanaka, Haruho Anma, Kyung Ho Kim, Masahiko Maekawa and Takayoshi Kuroda-Sowa
    • Journal Title

      Polymers 2012

      Volume: 4 Pages: 1613-1626

    • Related Report
      2012 Final Research Report
  • [Journal Article] Influence of NiO anode buffer layer prepared by solution on performance of bulk-heterojunction solar cells2012

    • Author(s)
      Kyung Ho Kim, Chiaki Takahashi, Takashi Okubo, Yoshio Abe, Midori Kawamura
    • Journal Title

      Applied Surface Science

      Volume: 258 Pages: 7809-7812

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Synthesis of a New Mixed-valence Decanuclear Cu(I)-Cu(II) Cluster with a Hexamethylene Dithiocarbamate Ligand2012

    • Author(s)
      Takashi Okubo, Naoya Tanaka, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Journal Title

      Annual reports by Research Institute for Science and Technology

      Volume: 24 Pages: 53-57

    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Journal Article] Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)–Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand2012

    • Author(s)
      Takashi Okubo
    • Journal Title

      Polymers

      Volume: 4 Issue: 3 Pages: 1613-1626

    • DOI

      10.3390/polym4031613

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Conducting Properties of a New Mixed-Valence Cu(I)-Cu(II) 1D Coordination Polymer Bridged by Morpholine-Dithiocarbamate2011

    • Author(s)
      Kyung Ho Kim, Takashi Ueta, Takashi Okubo, Shinya Hayami, Haruho Anma, Kazuya Kato, Tetsuya Shimizu, Jyunji Fujimori, Masahiko Maekawa, and Takayoshi Kuroda-Sowa
    • Journal Title

      Chem. Lett.

      Volume: 40 Pages: 1184-1186

    • Related Report
      2012 Final Research Report
  • [Journal Article] Halide-Bridged 1D Mixed-Valence CuI.CuII Coordination Polymers Bearing a Piperidine-1-carbodithioato Ligand: Crystal Structure, Magnetic and Conductive Properties, and Application in Dye-Sensitized Solar Cells

    • Author(s)
      Naoya Tanaka, Takashi Okubo, Haruho Anma, Kyung Ho Kim, Yoshie Inuzuka, Masahiko Maekawa, and Takayoshi Kuroda-Sowa
    • Journal Title

      Eur. J. Inorg. Chem.

    • Related Report
      2012 Final Research Report
  • [Presentation] ハロゲン化銅 (I)ラダー骨格を含む配位高分子の構造、キャリア輸送特性および太陽電池への展開2013

    • Author(s)
      大久保貴志・安間晴穂・中谷研二・田中秀征・金敬鎬・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2013-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] ジチオカルバミン酸を配位子とした強誘電性配位高分子の結晶構造、誘電性およびキャリア輸送特性2013

    • Author(s)
      安間晴穂・徳川健太・関修平・佐伯昭紀・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2013-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] オクタメチレンジチオカルバミン酸を配位子とした混合原子価配位高分子の結晶構造および電気伝導性2013

    • Author(s)
      安間晴穂・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第92春期年会
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2013-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] ジチオカルバミン酸誘導体を配位子とした一次元配位高分子の構造とキャリア輸送特性2013

    • Author(s)
      大久保貴志・安間晴穂・樋元健人・前川雅彦・黒田孝義
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Year and Date
      2013-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] ジチオカルバミン酸配位高分子を用いた電界効果トランジスタの作製と物性評価2013

    • Author(s)
      樋元健人・安間晴穂・徳川健太・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Year and Date
      2013-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] ジチオカルバミン酸配位高分子を用いた電界効果トランジスタの作製と物性評価2013

    • Author(s)
      樋元健人
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 誘電性配位高分子のキャリア輸送特性2012

    • Author(s)
      大久保貴志・徳川健太・安間晴穂・関 修平・佐伯昭紀・前川雅彦・黒田孝義
    • Organizer
      日本化学会第92春期年会
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] ハロゲン化銅(I)ラダー骨格を含む配位高分子の構造、キャリア輸送特性および太陽電池への展開2012

    • Author(s)
      大久保貴志
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジチオカルバミン酸を配位子とした強誘電性配位高分子の結晶構造、誘電 性およびキャリア輸送特性2012

    • Author(s)
      安間晴穂
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 強誘電性配位高分子のキャリア輸送特性2012

    • Author(s)
      大久保貴志・徳川健太・安間晴穂・関 修平・佐伯昭紀・前川雅彦・黒田孝義
    • Organizer
      日本化学会第92春期年会
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Carrier Transport Properties of Coordination Polymers with Dithiocarbamate Lignds, and its Application to Solar Cell Devices2011

    • Author(s)
      大久保貴志
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Carrier Transport Properties of Coordination Polymers with Dithiocarbamate Lignds, and its Application to Solar Cell Devices2011

    • Author(s)
      大久保貴志
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 電界効果トランジスタ及びそれを含むメモリ素子2013

    • Inventor(s)
      大久保貴志、樋元健人、西川尚男、前川雅彦、黒田孝義
    • Industrial Property Rights Holder
      学校法人近畿大学
    • Industrial Property Number
      2013-031099
    • Filing Date
      2013-02-20
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 電界効果トランジスタ及びそれを含むメモリ素子2013

    • Inventor(s)
      大久保貴志、樋元 健人、西川 尚男、前川 雅彦、黒田 孝義
    • Industrial Property Rights Holder
      学校法人近畿大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-031099
    • Filing Date
      2013-02-20
    • Related Report
      2012 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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