Selective C=O bond cleavage by a transition-metal complex
Project/Area Number |
23750067
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
|
Research Institution | Kobe City College of Technology |
Principal Investigator |
FUKUMOTO Kozo 神戸市立工業高等専門学校, 一般科, 准教授 (80549816)
|
Co-Investigator(Renkei-kenkyūsha) |
NAKAZAWA Hiroshi 大阪市立大学, 大学院・理学研究科, 教授 (00172297)
ITAZAKI Masumi 大阪市立大学, 大学院・理学研究科, 講師 (60382032)
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 有機金属化学 / 脱硫反応 / 触媒反応 / カルベン錯体 / 触媒 / 鉄 / ケイ素 |
Research Abstract |
This project showed the first example of inert bonds cleavage which are O-CN in cyanate, S-H in thiol, C=O in amide, C=S in thioamide by a transition metal complex. In the reactions with amide and thioamide, we also found a new type reaction to give imine. The carbene complexes were produced and characterized as intermediate products.
|
Report
(3 results)
Research Products
(45 results)
-
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Formation of a Disposable Coolant2012
Author(s)
Mao Namba, Takeshi Ito, Yuu Kimura, Ippei Fukuhara, Taisei Watanabe, Makiha Shoto, Masaya Baba, Hiroyuki Nunoura, Takamitu Yoshimoto, Yoshihiko Yagi, Shigeaki Ohtaki and Kozo Fukumoto
-
Journal Title
Reserch Reports of Kobe City College of Technology
Volume: 50
Pages: 177-180
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-