| Project/Area Number |
23750067
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kobe City College of Technology |
|---|
Principal Investigator |
FUKUMOTO Kozo 神戸市立工業高等専門学校, 一般科, 准教授 (80549816)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
NAKAZAWA Hiroshi 大阪市立大学, 大学院・理学研究科, 教授 (00172297)
ITAZAKI Masumi 大阪市立大学, 大学院・理学研究科, 講師 (60382032)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Keywords | 有機金属化学 / 脱硫反応 / 触媒反応 / カルベン錯体 / 触媒 / 鉄 / ケイ素 |
|---|
| Research Abstract |
This project showed the first example of inert bonds cleavage which are O-CN in cyanate, S-H in thiol, C=O in amide, C=S in thioamide by a transition metal complex. In the reactions with amide and thioamide, we also found a new type reaction to give imine. The carbene complexes were produced and characterized as intermediate products.
|
