Structural Chirality Based on Side-chain Ordering of Polymer and its application of Stimuli-responsive Chiral Discrimination
Project/Area Number |
23750086
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Analytical chemistry
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Research Institution | Kyushu University |
Principal Investigator |
SHUNDO Atsuomi 九州大学, 大学院・工学研究院, 助教 (40585915)
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 表面・界面 / キラリティー / 薄膜 / 濡れ性 / 誘起キラリティー |
Research Abstract |
We have designed and synthesized a polymer having the structural chirality induced by the side-chain ordering. The contact angle measurements using chiral liquids as a probe revealed that the polymer film has the enantioselective surface properties. The enantioselectivity was associated with a surface organization via the local conformational change of the polymer chains. Also, we have successfully fabricated a polymer film, which enables us to determine the enantiomeric purity of the liquids by observing the change in the fluorescence emission.
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Report
(3 results)
Research Products
(18 results)