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Development of the nanoporous metal materials as the catalyst in the molecular transformation

Research Project

Project/Area Number 23750098
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Synthetic chemistry
Research InstitutionTohoku University

Principal Investigator

TANAKA Shinya  東北大学, 大学院・工学研究科, 助教 (80570142)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsナノポーラス金属 / 固体金属触媒 / 脱合金 / パラジウム / カップリング反応 / 金 / 酸素酸化 / 化学選択性 / 金属ガラス / 合金
Research Abstract

In this work, Suzuki-coupling and Heck reaction catalyzed by nanoporous Pd (PdNPore) which was fabricated by dealloying of the metallic glass alloy consists of Ni-Pd-P system were developed. This material can be used repeatedly without support, stabilizer, and ligand, because the morphology is the monolithic bulk metal. Furthermore, the one step synthetic method of formamides via aerobic oxidation in the presence of nanoporous Au (AuNPore) as a catalyst was developed. This reaction proceeds under ambient pressure, and methanol is preferentially-oxidized in the coexistence of alkylamine.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (22 results)

All 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (13 results) Remarks (6 results)

  • [Journal Article] From molecular catalysts to nanostructured materials skeleton catalysts2012

    • Author(s)
      Naoki Asao, Tienan Jin, Shinya Tanaka, Yoshinori Yamamoto
    • Journal Title

      Pure Appl. Chem.

      Volume: 84 Issue: 8 Pages: 1771-1771

    • DOI

      10.1351/pac-con-11-10-28

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reusable and Sustainable Nanostructured Skeleton Catalyst: Heck Reaction with Nanoporous Metallic Glass Pd (PdNPore) as a Support, Stabilizer and Ligand Free Catalyst2011

    • Author(s)
      T. Kaneko, S. Tanaka, N. Asao, Y. Yamamoto, M. Chen, W. Zhang, A. Inoue
    • Journal Title

      Adv. Syn. Catal

      Volume: 353 Pages: 2927-2932

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] A nanostructured skeleton catalyst : Suzuki-coupling with a reusable and sustainable nanoporous metallic glass Pd-catalyst2011

    • Author(s)
      Tanaka, S.; Kaneko, T.; Asao, N.; Yamamoto, Y.; Chen, M.; Zhang, W.; Inoue, A.
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 21 Pages: 5985-5987

    • DOI

      10.1039/c1cc10710k

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] ナノポーラスPdを非担持型固体金属触媒とするカップリング反応の開発2012

    • Author(s)
      田中信也
    • Organizer
      第109回触媒討論会,2P62
    • Place of Presentation
      東京工業大学(東京)
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノポーラスPdを非担持型固体金属触媒とする分子変換反応の開発2012

    • Author(s)
      田中信也
    • Organizer
      日本化学会第92春季年会,1K8-44
    • Place of Presentation
      慶應義塾大学(東京)
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノポーラス構造を有するバイメタリックPd-Au触媒を用いた環状共役エノンの1,4-ヒドロシリル化2012

    • Author(s)
      陳強
    • Organizer
      日本化学会第92春季年会,1K8-46
    • Place of Presentation
      慶應義塾大学(東京)
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノポーラスPdを非担持型固体金属触媒とする分子変換反応の開発2012

    • Author(s)
      田中信也,金子哲朗,浅尾直樹,山本嘉則,陳明偉,張偉,井上明久
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノポーラス構造を有するバイメタリックPd-Au 触媒を用いた環状共役エノンの1,4-ヒドロシリル化2012

    • Author(s)
      陳強・金鉄男・湊丈俊・田中信也・山本嘉則
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノポーラスPdを非担持型固体金属触媒とするカップリング反応の開発2012

    • Author(s)
      田中信也,金子哲朗,浅尾直樹,山本嘉則,陳明偉,張偉,井上明久
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノポーラスPdを固体金属触媒とするカップリング反応の開発2011

    • Author(s)
      田中信也
    • Organizer
      第22回万有仙台シンポジウム,P-14
    • Place of Presentation
      仙台国際センター(宮城)
    • Year and Date
      2011-12-19
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノ多孔質骨格触媒:ナノポーラスPdを非担持型金属触媒とする鈴木カップリングおよびHeck反応2011

    • Author(s)
      田中信也
    • Organizer
      第58回有機金属化学討論会,P3A-11
    • Place of Presentation
      名古屋大学(愛知)
    • Related Report
      2012 Final Research Report
  • [Presentation] Nanostructured SkeletonCatalyst: Suzuki-coupling and Heck Reaction with Nanoporous Pd-catalyst as a Non-supported Catalyst2011

    • Author(s)
      Shinya Tanaka
    • Organizer
      OMCOS 16, P-435
    • Place of Presentation
      Shanghai International Convention Center (China)
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノポーラスPdを触媒とする鈴木カップリング反応の開発2011

    • Author(s)
      田中信也
    • Organizer
      日本化学会第91春季年会,3C9-30
    • Place of Presentation
      神奈川大学(神奈川)
    • Related Report
      2012 Final Research Report
  • [Presentation] Nanostructured Skeleton Catalyst: Suzuki-coupling and Heck Reaction with Nanoporous Pd-catalyst as a Non-supported Catalyst2011

    • Author(s)
      Shinya Tanaka, Tetsuro Kaneko, Naoki Asao, Yoshinori Yamamoto, Mingwei Chen, Wei Zhang, Akihisa Inoue
    • Organizer
      OMCOS 16
    • Place of Presentation
      Shanghai International Convention Center (China)
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノ多孔質骨格触媒:ナノポーラスPdを非担持型金属触媒とする鈴木カップリングおよびHeck反応2011

    • Author(s)
      田中信也・金子哲朗・浅尾直樹・山本嘉則・陳明偉・張偉・井上明久
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノポーラスPdを固体金属触媒とするカップリング反応の開発2011

    • Author(s)
      田中信也,浅尾直樹,山本嘉則,陳明偉,張偉,井上明久
    • Organizer
      第22回万有仙台シンポジウム
    • Place of Presentation
      仙台国際センター(宮城県)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/~yamamoto/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/asao_labo/

    • Related Report
      2012 Final Research Report
  • [Remarks] Yamamoto Research Group, Tohoku University

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/~yamamoto/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 東北大学 原子分子材料科学高等研究機構 浅尾 研究室

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/asao_labo/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/~yamamoto/index.html

    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/asao_labo/

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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