| Project/Area Number |
23750098
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
TANAKA Shinya 東北大学, 大学院・工学研究科, 助教 (80570142)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | ナノポーラス金属 / 固体金属触媒 / 脱合金 / パラジウム / カップリング反応 / 金 / 酸素酸化 / 化学選択性 / 金属ガラス / 合金 |
|---|
| Research Abstract |
In this work, Suzuki-coupling and Heck reaction catalyzed by nanoporous Pd (PdNPore) which was fabricated by dealloying of the metallic glass alloy consists of Ni-Pd-P system were developed. This material can be used repeatedly without support, stabilizer, and ligand, because the morphology is the monolithic bulk metal. Furthermore, the one step synthetic method of formamides via aerobic oxidation in the presence of nanoporous Au (AuNPore) as a catalyst was developed. This reaction proceeds under ambient pressure, and methanol is preferentially-oxidized in the coexistence of alkylamine.
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