| Project/Area Number |
23750116
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
EGAMI Hiromichi 独立行政法人理化学研究所, 袖岡有機合成化学研究室, 客員研究員 (50553848)
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| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 二核錯体 / 触媒 / 鉄 / 銅 / 酸化反応 / 酸化的官能基化反応 / 触媒設計 / 遷移金属 / ナイトレン / アジド |
|---|
| Research Abstract |
A synthetic method for a new series of ligands, which were designed based on a working hypothesis, has been established as originally planned, and some metal complexes were prepared. Although an efficient catalyst for a nitrene transfer reaction using azide as a nitrene source could not be found at this moment, it was found that some complexes worked as catalysts for aerobic oxidation during this study. On the other hand, a new method for oxidative introduction of an amine functionality into olefins was established.
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