Synthesis of Polymer Membranes with Hierarchically Arrayed ChiralNanopores and Development of Supersmart Separation Ability
Project/Area Number |
23750121
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Niigata University |
Principal Investigator |
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 機能性高分子 / 多孔質膜 / ナノ空孔 / 不斉転写 / 分離膜 / ポリアセチレン / らせん高分子 / 光学活性高分子 / 脱ピナニルシリル化 / 膜 / 階層構造 |
Research Abstract |
Stereoregular one-handed helical artificial polymers similar to biopolymers such as DNA or enzymes were synthesized and could formed self-supporting membranescomposed of the regular one-handed helical polymers by casting of the polymer solution. By removing of chiral substituents hierarchically arranged along the main chain, self-supporting membranes having nano-pores imprinting of chiral information originated from the chiral substituents could be synthesized. The obtained membrane having chiral imprinted nano-pores showed a optical resolutionability which is promising to application for drug development.
|
Report
(3 results)
Research Products
(23 results)
-
-
-
-
-
-
-
[Journal Article] Chiral Teleinduction in Asymmetric Polymerization of 3, 5-Bis (hydroxymethyl)phenylacetylene Having a Chiral Group via a Very Long and Rigid Spacer at 4-Position2012
Author(s)
Abe, Yunosuke; Aoki, Toshiki; Jia, Hongge; Hadano, Shingo; Namikoshi, Takeshi; Kakihana, Yuriko; Liu, Lijia; Zang, Yu; Teraguchi, Masahiro; Kaneko Takashi
-
Journal Title
Chemistry Letters
Volume: 41(3)
Issue: 3
Pages: 244-246
DOI
NAID
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-