Development of Asymmetric Polymer Catalysts Based on Controlled Helical Structure
| Project/Area Number |
23750123
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
IIDA Hiroki 名古屋大学, 工学(系)研究科(研究院), 講師 (30464150)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 機能性高分子 / キラリティ / 高分子不斉触媒 / 不斉識別 / らせん構造 / 光学活性 / 高分子 / 超分子 / キラル / ポリフェニルアセチレン |
|---|
| Research Abstract |
In this project, we have developed optically active helical polymers containing organocatalytic units as the pendant or main chain, and investigated their asymmetric organocatalysis and chiral recognition ability with the anticipation that the one-handed helical conformation would enhance the enantioselectivity and chiral recognition ability as compared to those of the corresponding random polymers and monomers. We have successfully synthesized a series of optically active helical polymers consisting of naturally-occurring riboflavin (vitamin B2) and cinchona alkaloid derivatives that function as asymmetric catalysts, chiral stationary phases for HPLC, and chiral sensory materials.
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Report
(4 results)
Research Products
(83 results)
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[Patent(Industrial Property Rights)] 光学異性体用分離剤2013
Inventor(s)
八島栄次、飯田拡基、タン チェンリン、内藤裕樹
Industrial Property Rights Holder
ダイセル化学工業、名古屋大学
Industrial Property Rights Type
特許
Industrial Property Number
2012-108689
Filing Date
2013-05-10
Related Report
Overseas
-
[Patent(Industrial Property Rights)] 光学異性体用分離剤2012
Inventor(s)
八島栄次・飯田拡基・タン チェンリン・内藤裕樹
Industrial Property Rights Holder
八島栄次・飯田拡基・タン チェンリン・内藤裕樹
Industrial Property Rights Type
特許
Industrial Property Number
2012-108689
Filing Date
2012-05-10
Related Report
