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Development of functional crystalline materialsbased on host-guest chemistry in the crystalline state

Research Project

Project/Area Number 23750146
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

INOKUMA Yasuhide  東京大学, 大学院・工学系研究科, 助教 (80555566)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords細孔性錯体 / X線結晶構造解析 / 固相反応 / ホスト-ゲスト化学 / 単結晶
Research Abstract

A new method (crystalline sponge method) for single crystal X-ray analysis of scarce amount of compounds has been developed based on host-guest chemistry in the crystalline state. This protocol is available for the structural determination of a lot of trace samples such as natural products.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (24 results)

All 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (10 results) Remarks (2 results)

  • [Journal Article] X-ray analysis on the nanogram to microgram scale using porous complexes2013

    • Author(s)
      Y. Inokuma, S. Yoshioka, J. Ariyoshi, T. Arai, Y. Hitora, K. Takada, S. Matsunaga, K. Rissanen, M. Fujita
    • Journal Title

      Nature

      Volume: 495巻 Pages: 461-466

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] X-ray analysis on the nanogram to microgram scale using porous complexes2013

    • Author(s)
      Y. Inokuma, S. Yoshioka, J. Ariyoshi, T. Arai, Y. Hitora, et al.
    • Journal Title

      Nature

      Volume: 495 Issue: 7442 Pages: 461-466

    • DOI

      10.1038/nature11990

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Pre-installed CH3NCS2012

    • Author(s)
      Y. Inokuma, G.-H. Ning, M. FujitaAngew
    • Journal Title

      Chem. Int. Ed

      Volume: 51 Pages: 2379-2381

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Pre-installed CH3NCS2012

    • Author(s)
      Yasuhide Inokuma, Guo-Hong Ning, Makoto Fujita
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 51 Issue: 10 Pages: 2379-2381

    • DOI

      10.1002/anie.201107190

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Shedding Light on Hidden Reaction Pathways in Radical Polymerization by a Porous Coordination Network2011

    • Author(s)
      Y. Inokuma, S. Nishiguchi, K. Ikemoto, M. Fujita
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 12113-12115

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diels-Alder via Molecular Recognition in a Crystalline Molecular Flask2011

    • Author(s)
      K. Ikemoto, Y. Inokuma, M. Fujita
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 16806-16808

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bimolecular Reaction via the Successive Introduction of Two Substrates into the Crystals of Networked Molecular Cages2011

    • Author(s)
      Y. Inokuma, N. Kojima, T. Arai, M. Fujita
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 19691-19693

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Molecular Flasks2011

    • Author(s)
      Y. Inokuma, M. Kawano, M. Fujita
    • Journal Title

      Nature Chem

      Volume: 3 Pages: 349-358

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Molecular Flasks2011

    • Author(s)
      Yasuhide Inokuma, Masaki Kawano, Makoto Fujita
    • Journal Title

      Nature Chemistry

      Volume: 3 Issue: 5 Pages: 349-358

    • DOI

      10.1038/nchem.1031

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Shedding Light on Hidden Reaction Pathways in Radical Polymerization by a Porous Coordination Network2011

    • Author(s)
      Inokuma, Y.; Nishiguchi, S.; Ikemoto, K.; Fujita, M.
    • Journal Title

      Chemical Communication

      Volume: 47 Issue: 44 Pages: 12113-12115

    • DOI

      10.1039/c1cc15053g

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Diels-Alder via Molecular Recognition in a Crystalline Molecular Flask2011

    • Author(s)
      Ikemoto, K.; Inokuma, Y.; Fujita, M.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 42 Pages: 16806-16808

    • DOI

      10.1021/ja2079064

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Bimolecular Reaction via the Successive Introduction of Two Substrates into the Crystals of Networked Molecular Cages2011

    • Author(s)
      Yasuhide Inokuma, Nodoka Kojima, Tatsuhiko Arai, Makoto Fujita
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 49 Pages: 19691-19693

    • DOI

      10.1021/ja209290t

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 細孔性結晶を用いたマイクログラムスケールの天然物X線結晶構造解析2013

    • Author(s)
      猪熊泰英、有吉絢子、吉岡翔太、高田健太郎、松永茂樹、藤田誠
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県)
    • Year and Date
      2013-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 細孔性結晶を用いたマイクログラムスケールの天然物X線結晶構造解析2013

    • Author(s)
      猪熊泰英、有吉絢子、吉岡翔太、高田健太郎、松永茂樹、藤田誠
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Networked molecular cages and capsules as crystalline hosts for guest encapsulation and reactions2012

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      3rd International Conference onMetal-Organic Frameworks and OpenFramework
    • Place of Presentation
      the University of Edinburgh (スコットラン ド)
    • Year and Date
      2012-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Solution-like chemistry in crystals of networked molecular hosts2012

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      4th EuCheMS Chemistry Congress
    • Place of Presentation
      Prague Congress Centre (チェコ)
    • Year and Date
      2012-08-28
    • Related Report
      2012 Final Research Report
  • [Presentation] Solution-like chemistry in crystals of networked molecular hosts2012

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      4th EuCheMS Chemistry Congress
    • Place of Presentation
      Prague, Czech Republic
    • Related Report
      2012 Annual Research Report
  • [Presentation] Networked molecular cages and capsules as crystalline hosts for guest encapsulation and reactions2012

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      3rd International Conference on Metal-Organic Frameworks and Open Framework
    • Place of Presentation
      Edinburgh, United Kingdom
    • Related Report
      2012 Annual Research Report
  • [Presentation] Host-Guest Chemistry in Crystals of Networked Molecular Cages2011

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      11th Tateshina Conference on Organic Chemistry
    • Place of Presentation
      蓼科フォーラム(長野県)
    • Year and Date
      2011-11-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 細孔性ネットワーク錯体をホストに用いた結晶内2分子反応"錯体化学会2011

    • Author(s)
      猪熊泰英、小嶋和、寧國宏、藤田誠
    • Organizer
      第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 細孔性ネットワーク錯体をホストに用いた結晶内2分子反応

    • Author(s)
      猪熊泰英、小嶋 和、寧 國宏、藤田 誠
    • Organizer
      錯体化学会 第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Host-Guest Chemistry in Crystals of Networked Molecular Cages

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      11th Tateshina Conference on Organic Chemistry
    • Place of Presentation
      蓼科フォーラム(長野県)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/

    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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