• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Optical Separation Systems Based on theEnantioselective Solvation Property of Chiral Ionic Liquids

Research Project

Project/Area Number 23750147
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

ICHIKAWA Takahiro  東京農工大学, 大学院・工学研究院, 助教 (80598798)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsイオン液体 / 液晶 / アミノ酸イオン液体 / 双連続キュービック液晶 / 光学分割 / 膜・集合体
Research Abstract

A series of amino acid ionic liquids were prepared as chiral ionic liquids. Mixing of these amino acid ionic liquids and some amphiphilic molecules provided lyotropic liquid-crystalline materials forming various nanostructures. It was found that these materials exhibited bicontinuous cubic phases having three-dimensionally interconnected nanochannels depending on the selection of amino acid anion, design of amphiphilic molecules, and the composition of the two components. The three-dimensional nachannels are composed of amino acid ionic liquids. It was found that these channels function as efficient ion transporting pathways.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (14 results) Remarks (1 results)

  • [Journal Article] イオン液体界面研究の進歩と展開2013

    • Author(s)
      大野弘幸、一川尚広、河野雄樹
    • Journal Title

      表面科学

      Volume: 34巻 Pages: 166-172

    • NAID

      10031165209

    • URL

      http://www.sssj.org/jsssj/Vol34/34-04/index.htm

    • Related Report
      2012 Final Research Report
  • [Journal Article] Nano-biphasic ionic liquid systems composed of hydrophobic phosphonium salts and a hydrophilic ammonium salt2013

    • Author(s)
      S. Taguchi
    • Journal Title

      Chem. Commun

      Volume: 48 Issue: 43 Pages: 5271-5273

    • DOI

      10.1039/c2cc31074k

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 3D Continuous Water Nano-Sheet as a Gyroid Minimal Surface Formed by Bicontinuous Cubic Liquid-Crystalline Zwitterions2012

    • Author(s)
      T. Ichikawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 28 Pages: 11354-11357

    • DOI

      10.1021/ja304124w

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Co-Organisation of Ionic Liquids with Amphiphilic Diethanolamines : Construction of 3D Continuous Ionic Nanochannels through the Induction of Liquid-Crystalline Bicontinuous Cubic Phases2012

    • Author(s)
      T.Ichikawa, M.Yoshio, S.Taguchi, J.Kagimoto, H.Ohno, T.Kato
    • Journal Title

      Chemical Science

      Volume: 3 Issue: 6 Pages: 2001-2008

    • DOI

      10.1039/c2sc00981a

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Induction of Thermotropic Bicontinuous Cubic Phases in Liquid-Crystalline ammonium and Phosphonium Salts2012

    • Author(s)
      T. Ichikawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 5 Pages: 2634-2643

    • DOI

      10.1021/ja209010m

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Self-Organized Liquid-Crystalline Nanostructured Membranes for Water Treatment: Selective Permeation of Ions2012

    • Author(s)
      Masahiro Henmi, Koji Nakatsuji, Takahiro Ichikawa, Hiroki Tomioka, Takeshi Sakamoto, Masafumi Yoshio, and Takashi Kato
    • Journal Title

      Advanced Materials

      Volume: in press Issue: 17 Pages: 2238-2241

    • DOI

      10.1002/adma.201200108

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] JAISTInternational Symposium on IonicsMaterials2013

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      Bicontinuous CubicLiquid-Crystalline Assemblies Formed through Self-Organization of IonicLiquids
    • Place of Presentation
      石川県、北陸先端科学技術大学院大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Bicontinuous Cubic Liquid-Crystalline Assemblies Formed through Self-Organization of Ionic Liquids2013

    • Author(s)
      T. Ichikawa, T.Kato, H. Ohno
    • Organizer
      JAIST Symposium on Ionics Materials 2013
    • Place of Presentation
      JAIST, Ishikawa
    • Related Report
      2012 Annual Research Report
  • [Presentation] 2012年イオン液体討論会2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      Zwitterionの自己組織化を利用した三次元プロトン伝導性界面の構築
    • Place of Presentation
      沖縄県、沖縄県男女共同参画センター「てぃるる」
    • Related Report
      2012 Final Research Report
  • [Presentation] 2012年液晶討論会2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      双連続キュービック液晶を用いた三次元プロトン伝導性界面の構築
    • Place of Presentation
      千葉県、千葉大学
    • Related Report
      2012 Final Research Report
  • [Presentation] ILCC20122012

    • Author(s)
      一川尚広、吉尾正史、田口怜美、鍵本純子、大野弘幸、加藤隆史
    • Organizer
      Construction of 3D Continuous IonicNanochannels Through the Induction of Bicontinuous Cubic Liquid-Crystalline Phases
    • Place of Presentation
      ドイツ、Landeshauptstadt Mainz
    • Related Report
      2012 Final Research Report
  • [Presentation] 双連続キュービック液晶を用いた三次元プロトン伝導性界面の構築2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      2012年日本液晶学会討論会
    • Place of Presentation
      千葉大学 西千葉キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] Zwitterionの自己組織化を利用した三次元プロトン伝導性界面の構築2012

    • Author(s)
      一川尚広・加藤隆史・大野弘幸
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」
    • Related Report
      2012 Annual Research Report
  • [Presentation] Construction of 3D Continuous Ionic Nanochannels Through the Induction of Bicontinuous Cubic Liquid-Crystalline Phases2012

    • Author(s)
      T. Ichikawa, M. Yoshio, S. Taguchi, J. Kagimoto, H. Ohno, T. Kato
    • Organizer
      24th International Liquid Crystal Conference
    • Place of Presentation
      Mainz, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] 液晶化学シンポジウム2011

    • Author(s)
      一川尚広、上田紗織、鍵本純子、加藤隆史、大野弘幸
    • Organizer
      Zwitterionの自己組織化による異方的プロトン伝導材料の構築
    • Place of Presentation
      東京大学山上会館
    • Year and Date
      2011-06-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 2011年液晶討論会2011

    • Author(s)
      一川尚広、上田紗織、鍵本純子、加藤隆史、大野弘幸
    • Organizer
      ホスホニウム塩型Zwitterionを用いた異方的プロトン伝導材料の構築
    • Place of Presentation
      東京都、東京都市大学世田谷キャンパス
    • Related Report
      2012 Final Research Report
  • [Presentation] FAPS2011

    • Author(s)
      一川尚広、吉尾正史、濱崎淳志、鍵本純子、大野弘幸、加藤隆史
    • Organizer
      Development of Nanostructured Ion-Conductive Polymer Films Having 3D Interconnected Ion Nano-Channels
    • Place of Presentation
      中国、China National Convention Center
    • Related Report
      2012 Final Research Report
  • [Presentation] Zwitterionの自己組織化による異方的プロトン伝導材料の構築2011

    • Author(s)
      一川尚広・上田紗織・鍵本純子・加藤隆史・大野弘幸
    • Organizer
      液晶化学シンポジウム
    • Place of Presentation
      東京都 東京大学山上会館
    • Related Report
      2011 Research-status Report
  • [Presentation] ホスホニウム塩型Zwitterionを用いた異方的プロトン伝導材料の構築2011

    • Author(s)
      一川尚広・上田紗織・鍵本純子・加藤隆史・大野弘幸
    • Organizer
      2011年日本液晶討論会
    • Place of Presentation
      東京都市大学 世田谷キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] Development of Nanostructured Ion-Conductive Polymer Films Having 3D Interconnected Ion Nano-Channels2011

    • Author(s)
      Takahiro ICHIKAWA, Masafumi YOSHIO, Atsushi HAMASAKI, Junko KAGIMOTO, Hiroyuki OHNO, and Takashi KATO
    • Organizer
      The 2nd FAPS Polymer Congress
    • Place of Presentation
      中国 China National Convention Center (CNCC)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~ohno/

    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi