Spatiotemporal control of arrangements of acidic and basic functionalities in porous coordination polymers

• Project/Area Number: 23750157
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Functional materials chemistry
• Research Institution: Kyoto University
• Principal Investigator: SATO Hiroshi 京都大学, 物質-細胞統合システム拠点, 特定拠点助教 (20598586)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: 多孔性物質 / 光反応 / 細孔 / ナイトレン / 分子吸着 / 多孔性材料 / 触媒

Research Abstract

This research project aimed at the development of new materials for on-demand surface activation and modificationos of porous materials. We successfully introduced photochemically active sites and observed the photochemical reactions through various direct methods such as single crystal X-ray strutural analyses.

Research Products

• [Journal Article] Photochemical Cycloaddition on the Pore Surface of a Porous Coordination Polymer Impacts on the Sorption Behavior (2012)
  • Author(s): 佐藤弘志、松田亮太郎、Mohammad Hedayetullah Mir、北川進
  • Journal Title: Chemical Communications Volume: 48 Issue: 64 Pages: 7919-7921
  • DOI: 10.1039/c2cc31083j
  • Peer Reviewed
• [Journal Article] Highly Rigid and Stable Porous Cu(I) Metal-Organic Framework with Reversible Single-Crystal-to-Single-Crystal Structural Transformation (2012)
  • Author(s): Tapas Kumar Maji、Sudip Mohapatra、北川進、松田亮太郎、佐藤弘志
  • Journal Title: CrystEngComm Volume: 14 Issue: 12 Pages: 4153-4153
  • DOI: 10.1039/c2ce06701c
  • Peer Reviewed
• [Journal Article] Effect of functional groups in MIL-101 on water sorption behavior (2012)
  • Author(s): 秋山穣慈、松田亮太郎、佐藤弘志、北川進
  • Journal Title: Microporous Mesoporous Materials Volume: - Pages: 89-93
  • DOI: 10.1016/j.micromeso.2012.01.015
  • Peer Reviewed
• [Journal Article] Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups (2011)
  • Author(s): 秋山穣慈、松田亮太郎、佐藤弘志、北川進
  • Journal Title: Advanced Materials Volume: 23 Pages: 3294-3297
  • Peer Reviewed
• [Journal Article] Reporting Structural Transformation of Soft Porous Crystals for Detection of CO_2 (2011)
  • Author(s): Nobuhiro Yanai, Koji Kitayama, Yuh Hijikata, Hiroshi Sato, Ryotaro Matsuda, Yoshiki Kubota, Masaki Takata, Motohiro Mizuno, Takashi Uemura, Susumu Kitagawa
  • Journal Title: Nature Mater. Volume: 10 Issue: 10 Pages: 787-793
  • DOI: 10.1038/nmat3104
  • Peer Reviewed
• [Journal Article] Relationship between Channel and Sorption Properties in Coordination Polymers with Interdigitated Structures (2011)
  • Author(s): 土方優、堀毛悟史、杉本雅行、佐藤弘志、松田亮太郎、北川進
  • Journal Title: Chemistry-A European Journal Volume: 17 Issue: 18 Pages: 5138-5144
  • DOI: 10.1002/chem.201003734
  • Peer Reviewed
• [Presentation] (2013)
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 滋賀
• [Presentation] Stepwise and Hysteretic Sorption Behavior of Porous Coordination Polymers with Soft Secondary Building Units (2012)
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: MOF2012
  • Place of Presentation: エジンバラ、イギリス
• [Presentation] Photochemical Modifications of Porous Coordination Polymers to Control Sorption Behavior (2012)
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: ZMPC2012
  • Place of Presentation: 広島
• [Presentation] Stepwise Sorption Behavior of Porous Coordination Polymers with Soft Secondary Building Units (2012)
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: PBAST6
  • Place of Presentation: 台北、台湾
• [Presentation] (2012)
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山
• [Presentation] (2012)
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 神奈川
• [Presentation] Photochemical Modifications of Porous Coordination Polymers to Control Sorption Behavior (2012)
  • Author(s): 佐藤弘志
  • Organizer: ZMPC 2012: International Symposium on Zeolites and Microporous Crystals
  • Place of Presentation: 広島
• [Presentation] Stepwise Sorption Behavior of Porous Coordination Polymers with Soft Secondary Building Units (2012)
  • Author(s): 佐藤弘志
  • Organizer: The 6th Pacific Basin Conference on Adsorption Science and Technology (PBAST-6)
  • Place of Presentation: Taipei, Taiwan
• [Presentation] Stepwise and Hysteretic Sorption Behavior of Porous Coordination Polymers with Soft Secondary Building Units (2012)
  • Author(s): 佐藤弘志
  • Organizer: 3rd International Conference on Metal-Organic Frameworks and Open Framework Compounds
  • Place of Presentation: Edinburgh, UK
• [Presentation] Accessible nitrenes decorate the micropore surface of a porous coordination Polymer (2011)
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: MDF International Workshop: Open-shell Organic Molecules -Synthesis and Electronic Structure Freedom-
  • Place of Presentation: 大阪
• [Presentation] Photo-responsive Pores of Porous Coordination Polymers (2011)
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: IUCr2011
  • Place of Presentation: マドリード、スペイン
• [Presentation] (2011)
  • Organizer: 第26回日本吸着学会研究発表会
  • Place of Presentation: 筑波
• [Presentation] (2011)
  • Organizer: 第25回日本吸着学会研究発表会
  • Place of Presentation: 沖縄
• [Presentation] (2011)
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山
• [Presentation] Photo-responsive Pores of Porous Coordination Polymers
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: IUCr2011
  • Place of Presentation: Palacio Municipal de Congresos de Madrid（スペイン）
• [Presentation] Photochemical Spatial Transformation of Porous Coordination Polymers
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: 錯体化学会第６１回討論会
  • Place of Presentation: 岡山理科大学（岡山県）
• [Presentation] Accessible Nitrenes Decorate the Surface of a Porous Coordination Polymer
  • Author(s): 佐藤弘志
  • Organizer: MDF Workshop-Synthesis and Electronic Structure Freedom
  • Place of Presentation: 梅田スカイビル（大阪府）
• [Presentation] アロステリック効果を示す多孔性配位高分子への分子吸着
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: 第２５回日本吸着学会研究発表会
  • Place of Presentation: 沖縄産業支援センター（沖縄県）
• [Presentation] トポケミカル光反応による多孔性配位高分子の空間変換
  • Author(s): 佐藤弘志、松田亮太郎、北川進
  • Organizer: 日本化学会第９２春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス（神奈川県）