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Design and creation of shape-controlled alloy nanocatalysts with high functionality

Research Project

Project/Area Number 23750160
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionKyoto University

Principal Investigator

KOBAYASHI Hirokazu  京都大学, 大学院・理学研究科, 准教授 (30512694)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords金属ナノ粒子 / 水素吸蔵 / 形状制御
Research Abstract

Shape-controlled octahedral and cubic Pd nanocrystals have been synthesized by a chemical reduction method. From TEM measurements, the mean diameters of the octahedraland cubic Pd nanocrystals were c.a. 10 nm respectivety. The hydrogen-storage properties have been investigated by Powder X-ray diffraction, PC isotherm and solid state NMR mesurments. It was found that that the hydrogen absorption/desorption response depends on crystal face on Pd surface. In addition, hydrogen-storage properties of Pd/Pt alloy nanocrystals has been investigated.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (35 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (19 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (5 results) (of which Overseas: 2 results)

  • [Journal Article] Kitagawa Changeover of the Thermodynamic Behavior for Hydrogen Storage in Rh with Increasing Nanoparticle Size2013

    • Author(s)
      K. Kusada, H. Kobayashi, R. Ikeda, H. Morita, H
    • Journal Title

      Chem. Lett

      Volume: 42 Pages: 55-56

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Changeover of the Thermodynamic Behavior for Hydrogen Storage in Rh with Increasing Nanoparticle Size2013

    • Author(s)
      K. Kusada, H. Kobayashi, R. Ikeda, H. Morita, H. Kitagawa
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 1 Pages: 55-56

    • DOI

      10.1246/cl.2013.55

    • NAID

      10031143798

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Finding Hydrogen-Storage Capability in Iridium Induced by the Nanosize Effect2012

    • Author(s)
      H. Kobayashi, M. Yamauchi, H. Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 6893-6895

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Matsumura Nanosize-Induced Drastic Drop in Equilibrium Hydrogen Pressure for Hydride Formation and Structural Stabilization in Pd-Rh Solid-Solution Alloys2012

    • Author(s)
      H. Kobayashi, H. Morita, M. Yamauchi, R. Ikeda, H. Kitagawa, Y. Kubota, K. Kato, M. Takata, S. Toh, S
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 12390-12393

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Modular Design of Domain Assembly in Porous Coordination Polymer Crystals via Reactivity-Directed Crystallization Process2012

    • Author(s)
      T, Fukushima, S, Horike, H, Kobayashi, M, Tsujimoto, S, Isoda, L M, Foo, Y, Kubota, M, Takata, S, Kitagawa
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 13341-13347

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanosize-Induced Drastic Drop in Equilibrium Hydrogen Pressure for Hydride Formation and Structural Stabilization in Pd-Rh Solid-Solution Alloys2012

    • Author(s)
      H. Kobayashi, H. Morita, M. Yamauchi, R. Ikeda, H. Kitagawa, Y. Kubota, K. Kato, M. Takata, S. Toh, S. Matsumura
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 30 Pages: 12390-12393

    • DOI

      10.1021/ja305031y

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanosize-Induced Hydrogen Storage and Capacity Control in aNon-Hydride-Forming Element: Rhodium2011

    • Author(s)
      H. Kobayashi, H. Morita, M. Yamauchi, R. Ikeda, H. Kitagawa, Y. Kubota, K. Kato, M. Takata
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 11034-11037

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanosize-Induced Hydrogen Storage and Capacity Control in a Non-Hydride Forming Element : Rhodium2011

    • Author(s)
      H.Kobayashi, H.Morita, M.Yamauchi, R.Ikeda, H.Kitagawa, Y.Kubota, K.Kato, M.Takata
    • Journal Title

      J.Am Chem.Soc

      Volume: 133 Issue: 29 Pages: 11034-11037

    • DOI

      10.1021/ja2027772

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Pd ナノ結晶/多孔性配位高分子コア・シェル型ナノ複合物質の水素吸蔵特性2013

    • Author(s)
      小林浩和、北川宏
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Pd-Pt 系コア・シェルナノ構造が水素吸蔵特性に及ぼす影響2013

    • Author(s)
      小林浩和、北川宏
    • Organizer
      日本化学会第93 春季年会(2013)
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Nanostructured Materials for Hydrogen Storage2012

    • Author(s)
      Hirokazu Kobayashi and Hiroshi Kitagawa
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2012 (MH2012)
    • Place of Presentation
      Kyoto
    • Year and Date
      2012-10-23
    • Related Report
      2012 Final Research Report
  • [Presentation] Pd ナノ結晶/多孔性配位高分子ナノ複合物質の合成とガス吸着特性2012

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      錯体化学会第62回討論会(国内学会/ポスター)
    • Place of Presentation
      富山大学
    • Year and Date
      2012-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノ金属と水素2012

    • Author(s)
      小林浩和
    • Organizer
      第10回 水素量子アトミクス 研究会 プロ グラム
    • Place of Presentation
      KEK 物構研
    • Year and Date
      2012-08-20
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属ナノ結晶/多孔性配位高分子コア・シェル型ナノ複合物質の合成とガス吸着特性2012

    • Author(s)
      小林浩和、北川宏
    • Organizer
      日本化学会第92 春季年会(2012)
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Nanostructured Materials for Hydrogen Storage2012

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      The 16th International Workshop
    • Place of Presentation
      九州大学
    • Year and Date
      2012-01-23
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属ナノ結晶/多孔性配位高分子コア・シェル型ナノ複合物質の合成とガス吸着特性2012

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      日本化学会
    • Place of Presentation
      慶応大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Nanostructured Materials for Hydrogen Storage2012

    • Author(s)
      Hirokazu Kobayashi
    • Organizer
      The 16th International Workshop(招待講演)
    • Place of Presentation
      九州大学
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノ金属の水素吸蔵2011

    • Author(s)
      小林 浩和
    • Organizer
      磁性分光研究会
    • Place of Presentation
      京都大学
    • Year and Date
      2011-12-03
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属ナノ結晶 / 多孔性配位高分子コア・シェル型ナノ複合物質の作製と物性2011

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      分子科学会
    • Place of Presentation
      北海道、札幌
    • Year and Date
      2011-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] 水素吸蔵ナノ粒子2011

    • Author(s)
      小林 浩和
    • Organizer
      第59回マテリアルズ・テーラリング研究会
    • Place of Presentation
      長野
    • Year and Date
      2011-07-29
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 金属ナノ結晶/多孔性配位高分子コア・シェル型ナノ複合物質の作製と物性2011

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      分子科学会
    • Place of Presentation
      北海道、札幌
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノ金属の水素吸蔵2011

    • Author(s)
      小林 浩和
    • Organizer
      磁性分光研究会(招待講演)
    • Place of Presentation
      京都大学
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノ金属と水素

    • Author(s)
      小林浩和
    • Organizer
      第10回 水素量子アトミクス研究会
    • Place of Presentation
      KEK 物構研
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pdナノ結晶/多孔性配位高分子ナノ複合物質の合成とガス吸着特性

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Nanostructured Materials for Hydrogen Storage

    • Author(s)
      Hirokazu Kobayashi and Hiroshi Kitagawa
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2012
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pd-Pt系コア・シェルナノ構造が水素吸蔵特性に及ぼす影響

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Pdナノ結晶/多孔性配位高分子コア・シェル型ナノ複合物質の水素吸蔵特性

    • Author(s)
      小林浩和、北川 宏
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Annual Research Report
  • [Book] 水素吸蔵2012

    • Author(s)
      小林 浩和、北川 宏
    • Related Report
      2012 Final Research Report
  • [Book] CSJ カレントレビュー 09 金属および半導体ナノ粒子の科学 part II2012

    • Author(s)
      小林 浩和
    • Publisher
      化学同人
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/ossc/index.html

    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 金属ナノ粒子複合体およびその製造方法2012

    • Inventor(s)
      北川 宏、山田 鉄兵、小林 浩和、向吉 恵
    • Industrial Property Rights Holder
      北川 宏、山田 鉄兵、小林 浩和、向吉 恵
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-206494
    • Filing Date
      2012-09-20
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属ナノ粒子のPCP複合体とその製造方法2012

    • Inventor(s)
      北川 宏、小林 浩和
    • Industrial Property Rights Holder
      北川 宏、小林 浩和
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-08-03
    • Related Report
      2012 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 金属ナノ粒子上のPCPナノ膜とその作製方法2011

    • Inventor(s)
      小林浩和、北川宏
    • Industrial Property Rights Holder
      小林浩和、北川宏
    • Industrial Property Number
      2011-171542
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 金属ナノ粒子複合体およびその製造方法

    • Inventor(s)
      北川 宏、山田 鉄兵、小林 浩和、向吉 恵
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 金属ナノ粒子の PCP 複合体とその製造方法

    • Inventor(s)
      北川 宏、小林 浩和
    • Related Report
      2012 Final Research Report
    • Overseas

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Published: 2011-08-05   Modified: 2019-07-29  

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