Development of the innovative sensor device based on the surface induced phase transition of coordination polymer

• Project/Area Number: 23750162
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Functional materials chemistry
• Research Institution: Osaka University
• Principal Investigator: TANAKA Daisuke 大阪大学, 理学研究科, 助教 (60589399)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: 分子磁性体 / デバイス化 / 相転移 / 金属錯体 / ナノ粒子 / スピンクロスオーバー / 薄膜

Research Abstract

In this research, the innovative sensor device based on the surface induced phase transition of coordination polymer has been triedto be developed. The thin film of the coordination polymer with high phase transition temperature was prepared and their electrical property was explored. We have succeeded in the development of a thin film device whose phase transition behavior can be detected by electrical signal.

Research Products

• [Journal Article] Computational Investigation of a Photo-switchable Single-Molecule Magnet Based on a Porphyrin Terbium Double-Decker Complex (2012)
  • Author(s): T. Inose, D. Tanaka, T. Ogawa
  • Journal Title: Heterocycles Volume: 86 Pages: 1549-1554
• [Journal Article] Proton-induced Switching of the Single Molecule Magnetic Properties of a Porphyrin Based TbIII Double-decker Complex (2012)
  • Author(s): D. Tanaka, T. Inose, H. Tanaka, S. Lee, N. Ishikawa, and T. Ogawa
  • Journal Title: Chem. Commun. Volume: 48 Pages: 7796-7796
• [Journal Article] Proton-induced Switching of the Single Molecule Magnetic Properties of a Porphyrin Based TbIIIDouble-decker Complex (2012)
  • Author(s): DaisukeTanaka, Tomoko Inose, Hirofumi Tanaka, Naoto Ishikawa, Takuji Ogawa
  • Journal Title: Chem. Commun Volume: 48 Issue: 63 Pages: 7796-7798
  • DOI: 10.1039/c2cc00086e
  • Peer Reviewed
• [Journal Article] Influence of nanoparticle size to the electrical properties of naphthalenediimide on single-walled carbon nanotube wiring (2012)
  • Author(s): Hirofumi Tanaka, Liu Hong, Minoru Fukumori, Ryota Negishi, Yoshihiro Kobayashi, Daisuke Tanaka and Takuji Ogawa
  • Journal Title: Nanotechnology Volume: in press
  • Peer Reviewed
• [Presentation] ポルフィリン単分子磁石の磁性スイッチング挙動 (2013)
  • Author(s): 田中大輔
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 滋賀
• [Presentation] プロトンによるポルフィリンダブルデッカー型単分子磁石の磁性スイッチング (2012)
  • Author(s): 田中大輔、猪瀬朋子、太田雄介、田中啓文、阪上祥平、石川直人、小川琢治
  • Organizer: 本化学会第92春季年会
  • Year and Date: 2012-03-27
• [Presentation] ポルフィリンダブルデッカー型錯体超分子集合構造体のプロトンによる単分子磁性スイッチング (2012)
  • Author(s): 田中大輔
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
• [Presentation] ダブルデッカー型ポルフィリン単分子磁石のプロトン応答性 (2012)
  • Author(s): 田中大輔
  • Organizer: ナノ学会第10回大会
  • Place of Presentation: 大阪
• [Presentation] ポルフィリン単分子磁石のプロトン応答性と単分子膜構造 (2012)
  • Author(s): 田中大輔
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
• [Presentation] Proton-induced Switching of the Single Molecule Magnetic Properties of a Porphyrin Based TbIII Double-decker Complex (2012)
  • Author(s): 田中大輔
  • Organizer: The 13th International Conference on Molecule-based Magnets
  • Place of Presentation: Orland USA
• [Presentation] プロトンによるポルフィリンダブルデッカー型単分子磁石の磁性スイッチング (2012)
  • Author(s): 田中大輔、猪瀬朋子、太田雄介、田中啓文、阪上祥平、石川直人、小川琢治
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶應義塾大学
• [Presentation] スピンクロスオーバー配位高分子薄膜の作製と特性評価 (2011)
  • Author(s): 田中大輔、田中啓文、美田佳三、小川琢治
  • Organizer: 錯体化学会 第61回討論会
  • Year and Date: 2011-09-18
• [Presentation] スピンクロスオーバー配位高分子のナノ構造体構築 (2011)
  • Author(s): 田中大輔、田中啓文、美田佳三、小川琢治
  • Organizer: ナノ学会第9回大会
  • Place of Presentation: 北海道大学
• [Remarks]
  • URL: http://www.chem.sci.osaka-u.ac.jp/lab/ogawa/index.html