| Project/Area Number |
23750167
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Tokyo Metropolitan University |
|---|
Principal Investigator |
NISHIYABU Ryuhei 首都大学東京, 都市環境科学研究科, 助教 (00432865)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Keywords | 超分子 / ホウ素化合物 / 不均一触媒 / 金ナノ粒子 / ポリビニルアルコール / ボロン酸 / ゲル / ケモセンサー / 触媒担体 / 刺激応答性 / 触媒 / 水素化還元 / 低環境負荷 / 分子集合体 |
|---|
| Research Abstract |
Boron-containing microparticles and hydrogels were prepared by boronate esterification of boronic acids with multi-hydroxy compounds and their functionalization was performed by taking advantage of the chemical property of boron. The boron-containing microparticles served as support materials for gold nanoparticle catalysts and the hybrids afforded aromatic amines, useful reactive intermediates forindustrial products, from aromatic nitro compounds. The boronate hydrogels served as scaffolds of sensor materials enabling fluorescent detection of heavy metal ion in water.
|
