| Project/Area Number |
23750174
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Environmental chemistry
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
KOIKE Takashi 東京工業大学, 資源化学研究所, 助教 (30451991)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
|---|
| Keywords | 高機能触媒 / 光触媒 / 可視光反応 / 太陽光利用 / ラジカル反応 / 酸化還元反応 / フォトレドックス触媒 / 太陽光活用 / 一電子移動 / 太陽光 / キラル触媒 / クロスカップリング / 不斉光触媒反応 |
|---|
| Research Abstract |
Development of clean and green synthetic processes has attracted great attention from the viewpoint of energy crisis and environmental issues. Photoredox catalysis with well-defined [Ru(bpy)3 ]2+ has become a useful method for redox reactions in synthetic chemistry, because they can undergo visible-light-induced single electron transfer (SET). We have developed new and green photoredox-catalyzed reactions. In addition, new insight on the design of molecular photocatalyst was obtained. We reported on our results as 10 in papers for academic meetings, 8 in scientific treatises, and 1 in patents. One of our results was introduced in the foreign website (“Advances in Engineering”) for the engineering community.
|
