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Innovation and electronic characterization of well-ordered hetero-interfaces on the organic single crystal surfaces

Research Project

Project/Area Number 23750209
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials/Devices
Research InstitutionChiba University

Principal Investigator

NAKAYAMA Yasuo  千葉大学, 先進科学センター, 特任講師 (30451751)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords有機電子材料 / 素子 / 有機エレクトロニクス / 有機半導体 / 単結晶 / 価電子バンド構造 / pnヘテロ界面 / 角度分解光電子分光法 / 反射高速度電子回折法 / ルブレン / 有機単結晶 / 反射高速度電子線回折 / 有機電界効果トランジスタ / 有機薄膜太陽電池 / シンクロトロン放射光
Research Abstract

Hetero-interfaces between an organic semiconducting material and an electrode metal, gate insulator, or another organic semiconductor are one of the most crucial factors dominating the performance of the practical organic electronic devices. In the present study, the electronic structures of such organic hetero-interfaces were elucidated on well-ordered interfaces fabricated onto the organic single crystal surfaces by means of angle-resolved photoelectron spectroscopy. On the rubrene single crystals covered with an overlayer of a normal alkane molecule as a model interface of the channel region a high-mobility organic field effect transistor, un-modified valence band dispersion width (i.e. band effective mass of conducting holes) was revealed. Hetero-interfaces of organic semiconductors with other organic materials or electronically quantized metal nano-structures were also systematically investigated.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (43 results)

All 2013 2012 2011

All Journal Article (13 results) (of which Peer Reviewed: 11 results) Presentation (25 results) (of which Invited: 3 results) Book (5 results)

  • [Journal Article] Valence band structure of rubrene single crystals in contact with an organic gate dielectric2013

    • Author(s)
      Yasuo Nakayama, Jens Niederhausen, Shin'ichi Machida, Yuki Uragami, Hiroumi Kinjo, Antje Vollmer, Jurgen P. Rabe, Norbert Koch, Hisao Ishii
    • Journal Title

      Organic Electronics

      Volume: 14(7) Pages: 1825-1832

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Valence band structure of rubrene single crystals at the contact with an organic gate dielectric2013

    • Author(s)
      Yasuo Nakayama, Jens Niederhausen, Shin’ichi Machida, Yuki Uragami, Hiroumi Kinjo, Antje Vollmer, Jürgen P. Rabe, Norbert Koch, Hisao Ishii
    • Journal Title

      Organic Electronics

      Volume: in press Issue: 7 Pages: 1825-1832

    • DOI

      10.1016/j.orgel.2013.04.019

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 汎用的な材料の電子構造評価手法としての光電子収量分光法2013

    • Author(s)
      中山泰生,佐藤友哉,金城拓海,宮内拓也,江澤拓,大澤佑介,山下剛,町田真一,野口裕,コスワッタゲ ラシカ,石井久夫 (中山泰生)
    • Journal Title

      信学技報

      Volume: OME2012-103 Pages: 55-60

    • Related Report
      2012 Annual Research Report
  • [Journal Article] The interfacial properties at organic/metal interface probed by the quantum-well states2012

    • Author(s)
      Meng-Kai Lin, Yasuo Nakayama,Chin-Yung Wang, Jer-Chia Hsu, Shin-ichi Machida, Tun-Wen Pi, Hisao Ishii, S.-J. Tang
    • Journal Title

      Physical Review B

      Volume: 86(15)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Full picture of valence band structure ofrubrene single crystals probed by angle-resolved andexcitation-energy-dependent photoelectron spectroscopy2012

    • Author(s)
      Yasuo Nakayama, Yuki Uragami,Shin'ichi Machida, Kaveenga Rasika Koswattage, Daisuke Yoshimura, Hiroyuki Setoyama, Toshihiro Okajima, Kazuhiko Mase
    • Journal Title

      Hisao Ishii Applied Physics Express

      Volume: 5(11)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structures at organic hetero- junctions of N,N'-bis(1-naphthyl)-N,N'- diphenyl-1,1'-biphenyl-4,4'-diamin (NPB)-based organic light emitting diodes2012

    • Author(s)
      Yasuo Nakayama, Shin'ichi Machida, Yukimasa Miyazaki, Tatsuhiko Nishi, Yutaka Noguchi
    • Journal Title

      Hisao Ishii Organic Electronics

      Volume: 13(12) Pages: 2850-2855

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface electronic structure of zinc-phthalocyanine on the silver thin-film quantum-well2012

    • Author(s)
      Yasuo Nakayama, Meng-Kai Lin,Chin-Yong Wang, Tun-Wen Pi, HisaoIshii, S.-J. Tang
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 10 Pages: 149-152

    • NAID

      130004438802

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Interfacial properties at the organic/metal interface probed using quantum-well states2012

    • Author(s)
      Meng-Kai Lin, Yasuo Nakayama, Chin-Yung Wang, Jer-Chia Hsu, Chih-Hao Pan, Shin-ichi Machida, Tun-Wen Pi, Hisao Ishii, S.-J. Tang
    • Journal Title

      Physical Review B

      Volume: 86(15) Issue: 15

    • DOI

      10.1103/physrevb.86.155453

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Full Picture of Valence Band Structure of Rubrene Single Crystals Probed by Angle-Resolved and Excitation-Energy-Dependent Photoelectron Spectroscopy2012

    • Author(s)
      Yasuo Nakayama, Yuki Uragami, Shin'ichi Machida, Kaveenga Rasika Koswattage, Daisuke Yoshimura, Hiroyuki Setoyama, Toshihiro Okajima, Kazuhiko Mase, Hisao Ishii
    • Journal Title

      Applied Physics Express

      Volume: 5(11) Issue: 11 Pages: 111601-111601

    • DOI

      10.1143/apex.5.111601

    • NAID

      10031126435

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structures at organic heterojunctions of N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamin (NPB)-based organic light emitting diodes2012

    • Author(s)
      Yasuo Nakayama, Shin'ichi Machida, Yukimasa Miyazaki, Tatsuhiko Nishi, Yutaka Noguchi, Hisao Ishii
    • Journal Title

      Organic Electronics

      Volume: 13(12) Issue: 12 Pages: 2850-2855

    • DOI

      10.1016/j.orgel.2012.08.033

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-Of-Flight Technique to Examine Carrier Blocking Nature in Organic Light Emitting Diode2012

    • Author(s)
      Md. Mijanur Rahman, Naoki Ogawa, Yukimasa Miyazaki, Yasuo Nakayama, Yutaka Noguchi, Hisao Ishii
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 10 Issue: 0 Pages: 315-320

    • DOI

      10.1380/ejssnt.2012.315

    • NAID

      130004438817

    • ISSN
      1348-0391
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ルブレン単結晶の異方的な価電子バンド分散の光電子分光法による実測2012

    • Author(s)
      中山泰生, 町田真一, 浦上裕希, Koswattage Rasika Kaveenga, 吉村大介, 瀬戸山寛之, 岡島敏浩, 間瀬一彦, 石井久夫 (中山泰生)
    • Journal Title

      Photon Factory Activity Report Part B

      Volume: 29 Pages: 223-224

    • Related Report
      2012 Annual Research Report
  • [Journal Article] レーザ光同時照射によって可能になった有機半導体単結晶の価電子バンド構造研究2011

    • Author(s)
      中山泰生,町田真一,Steffen Duhm, Qian Xin, 解良聡,石井久夫,上野信雄
    • Journal Title

      レーザ加工学会誌

      Volume: 18 Pages: 202-206

    • NAID

      40019179374

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Photoemission investigation inside the organic semiconductors: two-dimensional valence band structures, buried interfaces, and low-density of gap states2013

    • Author(s)
      Yasuo Nakayama, Shin'ichi Machida, Yuki Uragami, Hiroumi Kinjo, T. Luan Nguyen, Masayuki Yamamoto, Yusuke Ozawa, Kazuhiko Mase, Yutaka Noguchi, K. Rasika Koswattage, Hisao Ishii
    • Organizer
      The 2013 EMN Spring Meeting
    • Place of Presentation
      Orlando, USA
    • Year and Date
      2013-10-04
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Electronic structures of the pentacenesingle crystal and its hetero-interface2013

    • Author(s)
      Yasuo Nakayama, Yuki Uragami, Masayuki Yamamoto, Shin'ichi Machida, Kazuhiko Mase, Kaveenga Rasika Koswattage, and Hisao Ishii
    • Organizer
      Seventh international conference onmolecular electronics and bioelectronics (M&BE7)
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2013-05-18
    • Related Report
      2012 Final Research Report
  • [Presentation] 光電子計測による有機半導体の電子構造分析~モデル系から現実のデバイスへ向けて」2013

    • Author(s)
      中山泰生
    • Organizer
      放射光セミナー
    • Place of Presentation
      東京大学物性研究所
    • Year and Date
      2013-05-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Photoelectron Yield Spectroscopy and Low Energy Photoemission to Investigate Two-Dimensional Valence Band Structures, Gap States, and Buried Interfaces2013

    • Author(s)
      Hisao Ishii, Yasuo Nakayama
    • Organizer
      2013 MRS Spring Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-04-03
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Electronic structures of the pentacene single crystal and its hetero-interface2013

    • Author(s)
      Yasuo Nakayama, Yuki Uragami, Masayuki Yamamoto, Shin’ichi Machida, Kazuhiko Mase, Kaveenga Rasika Koswattage, Hisao Ishii (Yasuo Nakayama)
    • Organizer
      Seventh international conference on molecular electronics and bioelectronics
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] 誘電体分子の表面吸着に伴うAg超薄膜の量子化エネルギー変化2013

    • Author(s)
      中山泰生, Meng-Kai Lin, Chih-Hao Pan,Tun-Wen Pi,S.-J. Tang,石井 久夫 (中山泰生)
    • Organizer
      第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川県厚木市
    • Related Report
      2012 Annual Research Report
  • [Presentation] 汎用的な材料の電子構造評価手法としての光電子収量分光法2013

    • Author(s)
      中山泰生,佐藤友哉,金城拓海,宮内拓也,江澤拓,大澤佑介,山下剛,町田真一,野口裕,コスワッタゲ ラシカ,石井久夫 (中山泰生)
    • Organizer
      電子情報通信学会有機エレクトロニクス研究会
    • Place of Presentation
      佐賀県鳥栖市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Electronic investigation inside crystalline organic semiconductors: two-dimensional valence band structures, gap states, and buried interfaces2012

    • Author(s)
      Yasuo Nakayama, Shin'ichi Machida, Jens Niederhausen, Yuki Uragami, Hiroumi Kinjo, K. Rasika Koswattage, Kazuhiko Mase, Antje Vollmer, Jugen P.Rabe, Norbert Koch, Hisao Ishii
    • Organizer
      International Symposium on Organic Transistors and Functional Interfaces (OFET2012)
    • Place of Presentation
      Princeton, USA
    • Year and Date
      2012-10-28
    • Related Report
      2012 Final Research Report
  • [Presentation] 「シンクロトロン放射光を用いた有機半導体単結晶の価電子バンド構造評価の試み」2012

    • Author(s)
      中山泰生
    • Organizer
      UVSOR研究会「UVSOR有機固体専用ラインの今後の展開」
    • Place of Presentation
      分子科学研究所
    • Year and Date
      2012-09-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Photoemission Observation of Hetero-interfaces Formed onto the Rubrene Single Crystal as the Model Interfaces of an Organic Field Effect Transistor2012

    • Author(s)
      Yasuo Nakayama, Shin'ichi Machida, Jens Niederhausen, Hiroumi Kinjo, Yuli Uragami, Antje Vollmer, Norbert Koch, Hisao Ishii
    • Organizer
      The 2012 International Conference onFlexible and Printed Electronics (ICFPE2012)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2012-09-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Metals and Insulating Molecules on the Rubrene Single Crystal Surface: Model Interfaces of an Organic Field Effect Transistor2012

    • Author(s)
      Yasuo Nakayama, Jens Niederhausen, Shin'ichi Machida, Hiroumi Kinjo, Yuki Uragami, Antje Vollmer, Norbert Koch, Hisao Ishii
    • Organizer
      5th International Symposium on Flexible Organic Electronics (ISFOE12)
    • Place of Presentation
      Thessaloniki, Greece
    • Year and Date
      2012-07-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Electronic investigation inside crystalline organic semiconductors: two-dimensional valence band structures, gap states, and buried interfaces2012

    • Author(s)
      Yasuo Nakayama, Shin’ichi Machida, Jens Niederhausen, Yuki Uragami, Hiroumi Kinjo, K. Rasika Koswattage, Kazuhiko Mase, Antje Vollmer, J. P. Rabe, Norbert Koch, Hisao Ishii (Yasuo Nakayama)
    • Organizer
      International Symposium on Organic Transistors and Functional Interfaces
    • Place of Presentation
      Princeton, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Photoemission Observation of Hetero-interfaces Formed onto the Rubrene Single Crystal as the Model Interfaces of an Organic Field Effect Transistor2012

    • Author(s)
      Yasuo Nakayama, Shin’ichi Machida, Jens Niederhausen, Hiroumi Kinjo, Yuli Uragami, Antje Vollmer, Norbert Koch, Hisao Ishii (Yasuo Nakayama)
    • Organizer
      The 2012 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] シンクロトロン放射光を用いた有機半導体単結晶の価電子バンド構造評価の試み2012

    • Author(s)
      中山泰生
    • Organizer
      UVSOR 研究会「UVSOR 有機固体専用ラインの今後の展開」
    • Place of Presentation
      愛知県岡崎市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Metals and Insulating Molecules on the Rubrene Single Crystal Surface: Model Interfaces of an Organic Field Effect Transistor2012

    • Author(s)
      Yasuo Nakayama, Jens Niederhausen, Shin’ichi Machida, Hiroumi Kinjo, Yuki Uragami, Antje Vollmer, Norbert Koch, Hisao Ishii (Yasuo Nakayama)
    • Organizer
      5th International Symposium on Flexible Organic Electronics
    • Place of Presentation
      Thessaloniki, Greece
    • Related Report
      2012 Annual Research Report
  • [Presentation] ルブレン単結晶およびその表面上に形成したヘテロ界面の価電子バンド構造の実測2012

    • Author(s)
      中山泰生,町田真一,Jens Niederhausen,浦上裕希,金城拓海,K. Rasika Koswattage, 間瀬 一彦,Antje Vollmer, Norbert Koch,石井久夫 (中山泰生)
    • Organizer
      第21回有機結晶シンポジウム
    • Place of Presentation
      神奈川県横浜市
    • Related Report
      2012 Annual Research Report
  • [Presentation] ルブレン単結晶上の金属-有機界面:成長様式と電子構造2012

    • Author(s)
      中山泰生,Jens Niederhausen,町田真一,金城拓海,浦上裕希,Antje Vollmer,Norbert Koch,石井久夫 (中山泰生)
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛県松山市
    • Related Report
      2012 Annual Research Report
  • [Presentation] 金属超薄膜量子井戸構造と有機半導体分子との界面相互作用2012

    • Author(s)
      中山泰生,Meng-Kai Lin, Chin-Yong Wang, Chin-Hung Chen, Che-Chia Hsu, 町田真一,Tun-Wen Pi, S.-J. Tang, 石井久夫
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Electronic Structures of Novel Metal-on-Organic and Organic-on-Metal Interfaces2011

    • Author(s)
      Yasuo Nakayama, Shin-ichi Machida, Jens Niederhausen, Hiroumi Kinjo, Chin-Hung Chen, Che-Chia Hsu, Meng-Kai Lin, Chin-Yong Wang, Antje Vollmer, Tun-Wen Pi, S.-J. Tang, Norbert Koch, Hisao Ishii
    • Organizer
      The 6th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications (ASOMEA6)
    • Place of Presentation
      Ishikawa, Japan
    • Year and Date
      2011-11-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機半導体分子と金属超薄膜量子井戸構造との相互作用2011

    • Author(s)
      中山泰生, Che-Chia Hsu, Chin-Hung Chen, Meng-Kai Lin, Chin-Yong Wang, 町田真一,Tun-Wen Pi, S.-J. Tang, 石井久夫
    • Organizer
      第31回表面科学学術講演会
    • Place of Presentation
      東京都江戸川区
    • Related Report
      2011 Research-status Report
  • [Presentation] Novel Interfaces between Organic Semiconducting Molecules and Metal Thin Film Quantum Well States Studied by Angle-Resolved Photoelectron Spectroscopy2011

    • Author(s)
      Yasuo Nakayama, Chin-Hung Chen, Che-Chia Hsu, Meng-Kai Lin, Chin-Yong Wang, Shin-ichi Machida, Tun-Wen Pi, Hisao Ishii, S.-J. Tang
    • Organizer
      6th International Symposium on Surface Science and Nanotechnology (ISSS-6)
    • Place of Presentation
      東京都江戸川区
    • Related Report
      2011 Research-status Report
  • [Presentation] Electronic Structures of Novel Metal-on-Organic and Organic-on-Metal Interfaces2011

    • Author(s)
      Yasuo Nakayama, S. Machida, J. Niederhausen, H. Kinjo, C.-H. Chen, C.-C. Hsu, M.-K. Lin, C.-Y. Wang, A. Vollmer, T.-W. Pi, S.-J. Tang, N. Koch, H. Ishii
    • Organizer
      The 6th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications (ASOMEA6)
    • Place of Presentation
      石川県加賀市
    • Related Report
      2011 Research-status Report
  • [Presentation] NPBと各種電子輸送材料との界面ホール輸送障壁高さの光電子分光法による実測2011

    • Author(s)
      中山泰生,町田真一,宮崎行正,西龍彦,野口裕,石井久夫
    • Organizer
      有機EL討論会 第13回例会
    • Place of Presentation
      大阪大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Electronic Band Structures of model interfaces on the Rubrene Single crystal2011

    • Author(s)
      Yasuo Nakayama, Shin-ichi Machida, Jens Niederhausen, Hiroumi Kinjo, Antje Vollmer, Norbert Koch, Hisao Ishii
    • Organizer
      The 6th International Workshop on Electronic Structure and Processes at Molecular-based Interfaces (ESPMI VI)
    • Place of Presentation
      カールスルーエ(ドイツ)
    • Related Report
      2011 Research-status Report
  • [Presentation] 金属超薄膜量子井戸構造上に作製した有機分子層の角度分解光電子分光法による電子構造評価2011

    • Author(s)
      中山泰生,Che-Chia Hsu, Chin-Hung Chen, 町田真一,Tun-Wen Pi, S.-J. Tang, 石井久夫
    • Organizer
      2011年秋季 第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Related Report
      2011 Research-status Report
  • [Book] 「光電子分光」『薄膜の評価ハンドブック』第I部「基本的評価技術」第3章「組成・結合状態の分析」第6節「有機薄膜の形状・構造・組成評価」第3項「有機薄膜の組成・結合状態の分析」(3)2013

    • Author(s)
      中山泰生(分筆担当)(金原粲,吉田貞史監修;中川茂樹,波多野睦子,山田寿一,吉川正信編)
    • Publisher
      テクノシステム
    • Related Report
      2012 Final Research Report
  • [Book] 薄膜の評価技術ハンドブック (第I部 第3章 第6節 第3項 (3) 「光電子分光」)2013

    • Author(s)
      中山泰生 (分筆担当;金原 粲 監修)
    • Total Pages
      620
    • Publisher
      テクノシステム
    • Related Report
      2012 Annual Research Report
  • [Book] 「有機半導体結晶の光電子分光」『有機デバイスのための塗布技術』第3章第5節2012

    • Author(s)
      中山泰生(分筆担当)(竹谷純一編)
    • Publisher
      CMC出版
    • Related Report
      2012 Final Research Report
  • [Book] 「光電子分光」『大学院講義物理化学第2版』第3巻第7章第10節2012

    • Author(s)
      中山泰生 (分筆担当)(阿波賀邦夫,小谷正博,横山利彦編)
    • Publisher
      東京化学同人
    • Related Report
      2012 Final Research Report
  • [Book] 有機デバイスのための塗布技術 (第3章第5節「有機半導体結晶の光電子分光」)2012

    • Author(s)
      中山泰生 (分筆担当; 竹谷純一監修)
    • Total Pages
      238
    • Publisher
      CMC出版
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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