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Surface structures analysis and function control for lithium battery reaction

Research Project

Project/Area Number 23750237
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIRAYAMA Masaaki  東京工業大学, 大学院・総合理工学研究科, 講師 (30531165)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsイオン交換体 / 伝導体 / 二次電池 / 無機工業化学 / ナノ材料 / MBE,エピタキシャル / ハイブリッド車 / エネルギー全般
Research Abstract

Interfacial reactions of lithium batteries have been determined by in situ X-ray surface scattering measurements using epitaxial thin-films electrodes. The interracial structures determine the power density and the stability of lithium-excess layered material electrodes. Surface modification by Li3 PO4 solid electrolyte improved the stability of the electrode structure upon battery operations. Mechanical and technical development of surface structures is of considerable importance for improving the power characteristics and cyclability of new-generation batteries.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (34 results)

All 2013 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (22 results) (of which Invited: 3 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Multiple Electron Reaction of Li<sub>2</sub>RuO<sub>3</sub> Electrode for Lithium Batteries2013

    • Author(s)
      Sou Taminato, Masaaki Hirayama, Kunimitsu Yamamoto, Yueming Zheng and Ryoji Kanno
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 60 Issue: 1 Pages: 24-28

    • DOI

      10.2497/jjspm.60.24

    • NAID

      10031148169

    • ISSN
      0532-8799, 1880-9014
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and electrochemical properties of LiMn2O4/SrRuO3 multi-layer epitaxial thin film electrodes2012

    • Author(s)
      Kota Suzuki, Kyungsu Kim, Sou Taminato, Masaaki Hirayama, Ryoji Kanno
    • Journal Title

      Journal of Power Sources

      Volume: 226 Pages: 340-345

    • DOI

      10.1016/j.jpowsour.2012.11.008

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-capacity phase formation by surface modification of Li_3PO_4 on nanosized Li_2RuO_3 electrode for lithium batteries2012

    • Author(s)
      Y.Zheng, S.Taminato, Y.Xu, K.Suzuki, K.Kim, M.Hirayama, R.Kanno
    • Journal Title

      J.Power Sources

      Volume: 208 Pages: 447-451

    • DOI

      10.1016/j.jpowsour.2012.02.044

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Oxygen Evolution and Reduction Reactions on La<sub>0.8</sub>Sr<sub>0.2</sub>CoO<sub>3</sub> (001), (110), and (111) Surfaces in an Alkaline Solution2012

    • Author(s)
      Mamoru Komo, Asuna Hagiwara, Sou Taminato, Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Electrochemistry

      Volume: 80 Issue: 10 Pages: 834-838

    • DOI

      10.5796/electrochemistry.80.834

    • NAID

      130002147512

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Functional evaluation of lithium battery materials based on the control of anisotropy2012

    • Author(s)
      Masaaki Hirayama and Ryoji Kanno
    • Journal Title

      Bulletin of the Ceramic Society of Japan

      Volume: 47 Pages: 270-274

    • NAID

      10031155533

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Fabrication and lithium intercalation properties of epitaxial Li_2RuO_3 thin films2012

    • Author(s)
      Y.Zheng, S.Taminato, K.Suzuki, M.Hirayama, R.Kanno
    • Journal Title

      Thin Solid Films

      Volume: (In Press) Issue: 15 Pages: 4889-4893

    • DOI

      10.1016/j.tsf.2012.03.029

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and electrochemical properties of nanosized LiFeO2 particles with a layered rocksalt structure for lithium batteries2011

    • Author(s)
      Masaaki Hirayama, Hiroki Tomita, Kei Kubota, Hidekazu Ido, Ryoji Kanno
    • Journal Title

      Materials Eesearch Bulletin

      Volume: 47 Issue: 1 Pages: 79-84

    • DOI

      10.1016/j.materresbull.2011.09.024

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 中性子反射率法によるリチウム電池電極/電解質界面構造変化の直接観察2013

    • Author(s)
      平山雅章
    • Organizer
      中性子産業利用推進協議会薄膜・界面研究会
    • Year and Date
      2013-09-03
    • Related Report
      2012 Final Research Report
  • [Presentation] 中性子反射率法を用いたLi Ti O 負極表面の皮膜形成機構解析2013

    • Author(s)
      平山雅章, Kim Kyungsu, 鈴木耕太, 田港聡, 菅野了次, 山田悟史, 米村雅雄
    • Organizer
      電気化学会第80回大会
    • Year and Date
      2013-03-29
    • Related Report
      2012 Final Research Report
  • [Presentation] リチウム電池電極電解質界面における構造と電池特性2013

    • Author(s)
      平山雅章
    • Organizer
      化合物新磁性材料研究会
    • Year and Date
      2013-03-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 中性子反射率法によるLi4 Ti5 O12 電極/電解質界面の構造解析2012

    • Author(s)
      平山雅章, 鈴木耕太, Kim KyungSu, 田港聡, 菅野了次, 山田悟史, 米村雅雄
    • Organizer
      第53回電池討論会
    • Year and Date
      2012-11-15
    • Related Report
      2012 Final Research Report
  • [Presentation] In Situ Neutron Reflectometry Analysis ofLi4 Ti5 O12 /Electrolyte Interface UsingTwo-Dimensional Model Electrode2012

    • Author(s)
      M. Hirayama, K. Suzuki, K. Kim, S. Taminato, R. Kanno, N. Yamada, M. Yonemura
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Enhanced Electrochemical Properties of Li4 Ti5 O12 Epitaxial Thin Film Electrode with Surface Modification2012

    • Author(s)
      K. Kim, K. Suzuki, S. Taminato, K. Tamura, J. Mizuki, J. Son, M. Hirayama, R. Kanno
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Interfacial Reaction on Li3 PO4 /Li2 RuO3Thin-Film Electrode2012

    • Author(s)
      S. Taminato, K. Suzuki, K.Kim, J. Son, K. Tamura, J. Mizuki, M. Hirayama, R. Kanno
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Year and Date
      2012-10-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Studies on Reactions and Structures at Electrode/Electrolyte Interface Using Epitaxial Model Electrodes2012

    • Author(s)
      R. Kanno, M.Hirayama, K. Tamura
    • Organizer
      Pacific Rim Meeting onElectrochemiacl and Solid-StateScience(PRiME2012)
    • Year and Date
      2012-10-08
    • Related Report
      2012 Final Research Report
  • [Presentation] Reactions and structure changes in electrode/electrolyte interface of lithium battery2011

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama,Kazuhisa Tamura
    • Organizer
      Lithium Batteries Discussion 2011
    • Place of Presentation
      Arcachon(France)
    • Related Report
      2011 Research-status Report
  • [Presentation] STRUCTURAL ANALYSIS OF SURFACE MODIFIED Li4Ti5O12ELECTRODE2011

    • Author(s)
      KyungSu Kim,Hidekazu Ido, Kouta Suzuki, Sou Taminato, Mamoru Komo, Hiroaki Minamishima, Kazuhisa Tamura, Jun’ichiro Mizuki, Jin-young Son, Masaaki Hirayama, Ryoji Kanno
    • Organizer
      the 5th INTERNATIONAL CONFERENCE ON POLYMER BATTERIES AND FUEL CELLS (PBFC-5)
    • Place of Presentation
      Chicago(USA)
    • Related Report
      2011 Research-status Report
  • [Presentation] Li2RuO3モデル電極における界面反応と電気化学特性2011

    • Author(s)
      田港聡,平山雅章,Yueming Zheng, 鈴木耕太,Kyungsu Kim,粉生守,南嶋宏映,菅野了次,孫珍永,田村和久,水木純一郎
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      朱鷺メッセ(新潟県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Li3PO4/Li4Ti5O12電極の表面構造解析2011

    • Author(s)
      金敬洙,井戸秀和,鈴木耕太,田港聡,粉生守,南嶋宏映,田村和久,水木純一郎,孫珍永,平山雅章,菅野了次
    • Organizer
      2011年電気化学秋季大会
    • Place of Presentation
      朱鷺メッセ(新潟県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Surface structure of intercalation electrodes2011

    • Author(s)
      Masaaki Hirayama, Kouta Suzuki, KyungSu Kim, Sou Taminato, Mamoru Komo, Jin-Young Son, Kazuhisa Tamura, and Ryoji Kanno,.
    • Organizer
      The 62nd Annual Meeting of the International Society of Electrochemistry,(招待講演)
    • Place of Presentation
      Nigata (Japan)
    • Related Report
      2011 Research-status Report
  • [Presentation] Interfacial Reactions and Lithium Intercalation Mechanism in Li2RuO32011

    • Author(s)
      Sou Taminato, Masaaki Hirayama, Kota Suzuki, KyungSu Kim, Mamoru Komo, Hiroaki Minamishima, Ryoji Kanno, Kazuhisa Tamura, Jun'ichiro Mizuki
    • Organizer
      the 62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Nigata (Japan)
    • Related Report
      2011 Research-status Report
  • [Presentation] 表面修飾によるリチウム電池電極表面構造変化と電気化学特性2011

    • Author(s)
      平山雅章,鈴木耕太,Kim KyungSu,田港 聡,菅野了次,井戸秀和,田村和久
    • Organizer
      第52回電池討論会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] Li2RuO3薄膜電極の界面電子構造とインターカレーション反応機構2011

    • Author(s)
      田港聡,平山雅章,鈴木耕太,Kim Kyungsu,井戸秀和,粉生守,南嶋宏映,菅野了次,孫珍永,田村和久,水木純一郎
    • Organizer
      第37回固体イオニクス討論会
    • Place of Presentation
      鳥取市(鳥取県
    • Related Report
      2011 Research-status Report
  • [Presentation] 中性子反射率法を用いたLi4Ti5O1212負極表面の皮膜形成機構解析

    • Author(s)
      平山雅章, Kim Kyungsu, 鈴木耕太, 田港聡, 菅野了次, 山田悟史, 米村雅雄
    • Organizer
      電気化学会第80回大会
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] 平山雅章

    • Author(s)
      リチウム電池電極電解質界面における構造と電池特性
    • Organizer
      化合物新磁性材料研究会
    • Place of Presentation
      つくば
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 平山雅章, 鈴木耕太, Kim KyungSu, 田港 聡, 菅野了次, 山田悟史, 米村雅雄

    • Author(s)
      中性子反射率法によるLi4Ti5O12電極/電解質界面の構造解析
    • Organizer
      第53回電池討論会
    • Place of Presentation
      博多
    • Related Report
      2012 Annual Research Report
  • [Presentation] 平山雅章

    • Author(s)
      中性子反射率法によるリチウム電池電極/電解質界面構造変化の直接観察
    • Organizer
      中性子産業利用推進協議会 薄膜・界面研究会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] M. Hirayama, K. Suzuki, K. Kim, S. Taminato, R. Kanno, N. Yamada, M. Yonemura

    • Author(s)
      In Situ Neutron Reflectometry Analysis of Li4Ti5O12/Electrolyte Interface Using Two-Dimensional Model Electrode
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Place of Presentation
      Hawaii
    • Related Report
      2012 Annual Research Report
  • [Presentation] R. Kanno, M. Hirayama, K. Tamura

    • Author(s)
      Studies on Reactions and Structures at Electrode/Electrolyte Interface Using Epitaxial Model Electrodes
    • Organizer
      Pacific Rim Meeting on Electrochemiacl and Solid-State Science (PRiME2012)
    • Place of Presentation
      Hawaii
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] 高性能リチウムイオン電池開発最前線(共著)2013

    • Publisher
      エヌ・ティー・エス
    • Related Report
      2012 Final Research Report
  • [Book] 高性能リチウムイオン電池開発最前線(分担)2013

    • Author(s)
      平山雅章,菅野了次
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 菅野・平山研究室

    • URL

      http://www.kanno.echem.titech.ac.jp/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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