Project/Area Number |
23750246
|
Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Inorganic industrial materials
|
Research Institution | Tokai University |
Principal Investigator |
ITO Takeru 東海大学, 理学部, 講師 (50376935)
|
Research Collaborator |
OZEKI Tomoji 東京工業大学, 理工学研究科, 准教授 (60214136)
NARUKE Haruo 東京工業大学, 資源化学研究所, 准教授 (40237623)
|
Project Period (FY) |
2011 – 2013
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
Keywords | ハイブリッド材料 / ポリ酸 / 層状結晶 / 界面活性剤 / 伝導性 |
Research Abstract |
Inorganic-organic hybrid crystals containing polyoxometalate inorganic cluster anion and cationic surfactant were successfully synthesized by a simple cation-exchange solution process. These hybrid crystals, which are rare series of materials, consisted of alternate stacking manner of polyoxometalate inorganic layers and surfactant organic layers. In addition, polyoxometalate-surfactant hybrid crystals containing metal ions or protons were obtained. These hybrid crystals exhibited anhydrous conductivity at intermediate temperature range over 373 K, and are promising candidates for ion-conductive solid electrolytes.
|