Formation of layered organization of particle with ability of fluorescent-emission using a new polymer nanospheres
Project/Area Number |
23750251
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Polymer/Textile materials
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Research Institution | Saitama University |
Principal Investigator |
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Project Period (FY) |
2011 – 2012
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Project Status |
Completed (Fiscal Year 2012)
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Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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Keywords | ポリマーナノスフィア積層粒子層状組織体 / 超薄分子組織膜 / 芳香族ポリアミド / 単粒子膜 / N-ビニルカルバゾール / 三元櫛型共重合体 / 蛍光発光能 / 構造色 / ナノコロイド結晶 / 三元櫛形共重合体 / 層状組織体 / 蛍光発光増強 / π-π相互作用によるスタック / フォトニック結晶 |
Research Abstract |
We constructed a multiparticle layered organization of aromatic polyamides with rigid main chains and flexible side chains by the Langmuir-Blodgett (LB) technique, which resulted in a highly regular arrangement along the c-axis. The particle arrangement was estimated by performing out-of-plane X-ray diffraction (XRD) analysis and atomic force microscopic (AFM) observation. The results suggest that a double-particle layered structure (Y-type) is formed by the LB technique, forming amphiphilic particles at the air/water interface. Copolymers with highly hydrophobic carbazole contents and both hydrogenated and fluorinated side-chains also formed a single-particle layer at the air/water interface and exhibited multiparticle layers by a LB technique. Therefore, it is possible to control the formation of single- and double-particle layered structure using these techniques. Further, it was found that multiparticle layered organization of polymer nanospheres and polymer nanosheets could be formed simultaneously with the same component material.
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Report
(3 results)
Research Products
(157 results)
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[Journal Article] レポート平成24年度繊維学会年次大会2012
Author(s)
幾田信生,藤森厚裕,木村邦生,戸木田雅利,松本英俊,宇佐美久尚,道信剛志,武野明義,渡辺敏行,松居正樹,平田雄一,久田研次,伊藤浩志,島村佳伸,櫻井伸一,川瀬徳三,仲西正,平井智康,上甲恭平,林徳子,中澤靖元,岩田忠久,鬘谷要,平井郁子,佐藤哲也,森島美佳,宝田亘,高崎緑
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Journal Title
Sen-i Gakkaishi
Volume: 68(8)
Pages: 247-253
Related Report
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[Journal Article] レポート 平成24年度 繊維学会年次大会2012
Author(s)
幾田信生, 藤森厚裕, 木村邦生, 戸木田雅利, 松本英俊, 宇佐美久尚, 道信剛志, 武野明義, 渡辺敏行, 松居正樹, 他18名
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Journal Title
Sen-i Gakkaishi
Volume: 68
Pages: 247-253
Related Report
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