Fabrication of Novel Chiral Sensor Consisting of π?conjugated HelicalPolymer

• Project/Area Number: 23750261
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Polymer/Textile materials
• Research Institution: Asahikawa National College of Technology
• Principal Investigator: SAKAI Ryosuke 旭川工業高等専門学校, 物質化学工学科, 准教授 (90507196)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: π共役系ポリマー / キラル / 比色分析 / 超分子化学 / ホスト・ゲスト相互作用 / ポリアセチレン

Research Abstract

Development of novel chiral sensor consisting of π-conjugated polymer was investigated in this research in order to provide an innovative methodology for simple and quick detection of chirality. We achieved to fabricate various π-conjugated polymers that can show brilliant colorimetric response dependent on the chirality. The sensitivity and selectivity in the chiral recognition ability was clarified to be tunable with the molecular design of the employed conjugated polymer.

Research Products

• [Journal Article] Influence of stereoregularity and linkage groups on chiral recognition of poly(phenylacetylene) derivatives bearing L-leucine ethyl ester pendants as chiralstationary phases for HPLC (2013)
  • Author(s): C. Zhang, F. Liu, Y. Li, X. Shen, X. Xu, R. Sakai, T. Satoh, T. Kakuchi, Y. Okamoto
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 51 Issue: 10 Pages: 2271-2278
  • DOI: 10.1002/pola.26611
  • Peer Reviewed
• [Journal Article] Colorimetric Detection of Anions in Aqueous Solution Using Poly(phenylacetylene) with Sulfonamide Receptors Activated by Electron Withdrawing Group (2012)
  • Author(s): R. Sakai, E. B. Barasa, N. Sakai, S.-i. Sato, T.Satoh, T. Kakuchi
  • Journal Title: Macromolecules Volume: 45 Issue: 20 Pages: 8221-8227
  • DOI: 10.1021/ma301767g
  • Peer Reviewed
• [Journal Article] Precise Synthesis of Clickable Poly(n-hexyl isocyanate) (2012)
  • Author(s): Satoh, T., Ihara, R., Kawato, D.,Nishikawa, N., Suemasa, D., Kondo,Y., Fuchise, K., Sakai, R., Kakuchi,T
  • Journal Title: Macromolecules Volume: 45(9) Issue: 9 Pages: 3677-3686
  • DOI: 10.1021/ma300555v
  • Peer Reviewed
• [Journal Article] Fluorescence Turn-On Sensing of Anions Based on Disassembly Process of Urea-Functionalized Poly(phenylenebutadiynylene) Aggregates (2012)
  • Author(s): R. Sakai, A. Nagai, Y. Tago, S. Sato, Y. Nishimura, T. Arai, T. Satoh and T. Kakuchi
  • Journal Title: Macromolecules Volume: 45 Issue: 10 Pages: 4122-4127
  • DOI: 10.1021/ma300481j
  • Peer Reviewed
• [Journal Article] Synthesis of End-Funct ionalized Polyethers by Phosphazene Base-Catalyzed Ring-Opening Polymerization of 1,2-Butylene Oxide and Glycidyl Ether (2012)
  • Author(s): Hideki Misaka
  • Journal Title: Journal of Polymer Science Part A : Polymer Chemistry Volume: 50(in print) Issue: 10 Pages: 1941-1952
  • DOI: 10.1002/pola.25969
  • Peer Reviewed
• [Journal Article] Syntheses of 3-arm and 4-arm star-branched polystyrene Ru(II) complexes by the click-to-chelate approach (2011)
  • Author(s): C. Zhang, X. Shen, R. Sakai, M. Gottschaldt, U. S. Schubert, S. Hirohara, M. Tanihara, S. Yano, M. Obata, N. Xiao, T. Satoh, T. Kakuchi
  • Journal Title: J. Polym. Sci., Part A: Polym. Chem. Volume: 49 Issue: 3 Pages: 746-753
  • DOI: 10.1002/pola.24487
  • Peer Reviewed
• [Journal Article] Synthesis of a novel one-handed helical poly(phenylacetylene) bearing poly(L-lactide) side chains (2011)
  • Author(s): C. Zhang, F. Liu, Q. Geng, S. Zhang, X. Shen, R. Kakuchi, H. Misaka, T. Kakuchi, T. Satoh, R. Sakai
  • Journal Title: Eur. Polym. J. Volume: 47 Issue: 10 Pages: 1923-1930
  • DOI: 10.1016/j.eurpolymj.2011.07.003
  • Peer Reviewed
• [Journal Article] Synthesis of Novel Hyperbranched Polymer Through Cationic Ring-Opening Multibranching Polymerization of 2-Hydroxymethyloxetane (2011)
  • Author(s): Hideki Misaka
  • Journal Title: Journal of Folymer Science Part A : Polymer Chemistry Volume: 49 Issue: 11 Pages: 2353-2365
  • DOI: 10.1002/pola.24664
  • Peer Reviewed
• [Journal Article] Strict Size Specificity in Colorimetric Anion Detection Based on Poly(phenylacetylene) Receptor Bearing Second Generation Lysine Dendrons (2011)
  • Author(s): Sakai, R.; Sakai, N.; Satoh, T.; Li, W.; Zhang, A.; Kakuchi, T.
  • Journal Title: Macromolecules Volume: 44 Issue: 11 Pages: 4249-4257
  • DOI: 10.1021/ma200710r
  • Peer Reviewed
• [Journal Article] Synthesis of High Molecular Weisht and End-Functionalized Poly(styrene oxide) by living Ring-Opening Polymerization of Styrene Oxide Using the Alcohol/Phosphazene Base Initiating System (2011)
  • Author(s): Hideki Misaka
  • Journal Title: Macromolecules Volume: 44 Issue: 23 Pages: 9099-9107
  • DOI: 10.1021/ma202115w
  • Peer Reviewed
• [Presentation] スレオニン由来アミド基を有するポリ(フェニルアセチレン)によるキラルセンシング (2013)
  • Author(s): 戸子台遥光・酒井直哉・梅田哲・津田勝幸・佐藤敏文・覚知豊次・堺井亮介
  • Organizer: 第47回(2012年度)高分子学会北海道支部研究発表会
  • Place of Presentation: 札幌
  • Year and Date: 2013-10-29
• [Presentation] グアニジニウム基を有するポリジアセチレンのアニオン検出能の評価 (2013)
  • Author(s): 菊地真依子・前谷枝保・梅田哲・津田勝幸・佐藤敏文・覚知豊次・堺井亮介
  • Organizer: 第47回(2012年度)高分子学会北海道支部研究発表会
  • Place of Presentation: 札幌
  • Year and Date: 2013-10-29
• [Presentation] 共役高分子を活用した化学センサーの開発 (2013)
  • Author(s): 堺井亮介
  • Organizer: 化学系学協会北海道支部2013年冬季研究発表会
  • Place of Presentation: 札幌
• [Presentation] スレオニン由来アミド基を有するポリ(フェニルアセチレン)によるキラルセンシング (2013)
  • Author(s): 戸子台遥光・酒井直哉・梅田哲・津田勝幸・佐藤敏文・覚知豊次・堺井亮介
  • Organizer: 第 47 回 （2012年度） 高分子学会北海道支部研究発表会
  • Place of Presentation: 北海道大学
• [Presentation] グアニジニウム基を有するポリジアセチレンのアニオン検出能の評価 (2013)
  • Author(s): 菊地真依子・前谷枝保・梅田哲・津田勝幸・佐藤敏文・覚知豊次・堺井亮介
  • Organizer: 第 47 回 （2012年度） 高分子学会北海道支部研究発表会
  • Place of Presentation: 北海道大学
• [Presentation] 側鎖にキラルアミノ基を有するポリジアセチレンの合成とキラル識別能の評価 (2012)
  • Author(s): 中村亮介、堺井亮介、梅田哲、青山陽子、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第46回(2011年度)高分子学会北海道支部研究発表会
  • Place of Presentation: 札幌
  • Year and Date: 2012-10-31
• [Presentation] 4級アンモニウム基を有するポリジアセチレンのアニオン検出能の評価 (2012)
  • Author(s): 前谷枝保、中村亮介、堺井亮介、梅田哲、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第46回(2011年度)高分子学会北海道支部研究発表会
  • Place of Presentation: 札幌
  • Year and Date: 2012-10-31
• [Presentation] キラルアミノ基を導入したポリジアセチレンによるカルボン酸のキラル識別 (2012)
  • Author(s): 中村亮介、堺井亮介、梅田哲、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 日本化学会北海道支部2012年夏季研究発表会
  • Place of Presentation: 旭川
  • Year and Date: 2012-08-04
• [Presentation] 側鎖にアンモニウムカチオンを有するポリジアセチレンのアニオン検出能の評価 (2012)
  • Author(s): 前谷枝保、中村亮介、堺井亮介、梅田哲、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
• [Presentation] 側鎖にキラルアミノ基を導入したポリジアセチレンによるカルボン酸のキラル識別能の評価 (2012)
  • Author(s): 中村亮介、堺井亮介、梅田哲、青山陽子、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
• [Presentation] Synthesis of urea-functionalized poly(phenylenebutadiynylene) as a turn-on fluorescent probe for anion sensing (2012)
  • Author(s): R. Sakai, A. Nagai, Y. Tago, S. Sato, T. Satoh, T. Kakuchi
  • Organizer: 243rd ACS National Meeting & Exposition, San Diego
  • Place of Presentation: CA, USA
• [Presentation] Colorimetric anion detection byurea-functionalized poly(phenylacetylene)s bearing L-amino acids as a pendant (2012)
  • Author(s): N. Sakai, R. Sakai, T. Satoh, T. Kakuchi
  • Organizer: 243rd ACS National Meeting & Exposition, San Diego
  • Place of Presentation: CA, USA
• [Presentation] キラルアミノ基を導入したポリジアセチレンによるカルボン酸のキラル識別 (2012)
  • Author(s): 中村亮介、堺井亮介、梅田哲、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 日本化学会北海道支部2012 年夏季研究発表会
  • Place of Presentation: 旭川高専
• [Presentation] 側鎖にキラルアミノ基を導入したポリジアセチレンによるカルボン酸のキラル識別能の評価 (2012)
  • Author(s): 中村亮介、堺井亮介、梅田哲、青山陽子、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] 側鎖にアンモニウムカチオンを有するポリジアセチレンのアニオン検出能の評価 (2012)
  • Author(s): 前谷枝保、中村亮介、堺井亮介、梅田哲、津田勝幸、佐藤敏文、覚知豊次
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋工業大学
• [Presentation] Synthesis of urea-functionalized poly(phenylenebutadiynylene) as a turn-on fluorescent probe for anion sensing. (2012)
  • Author(s): R. Sakai, A. Nagai, Y. Tago, S. Sato, T. Satoh, T. Kakuchi
  • Organizer: 243rd ACS National Meeting
  • Place of Presentation: San Diego, CA
• [Presentation] Corolimetric anion detection by urea-functionalized poly(phenylacetylene) s bearing L-amino acids as a pendants. (2012)
  • Author(s): N. Sakai, R. Sakai, T. Satoh, T. Kakuchi
  • Organizer: 243rd ACS National Meeting
  • Place of Presentation: San Diego, CA
• [Presentation] 側鎖にキラルアミノ基を有するポリジアセチレンの合成とキラル識別能の評価 (2012)
  • Author(s): 中村亮介・堺井亮介・梅田哲・青山陽子・津田勝幸・佐藤敏文・覚知豊次
  • Organizer: 第46回 (2011年度) 高分子学会北海道支部研究発表会
  • Place of Presentation: 北海道大学百年記念会館
• [Presentation] 4級アンモニウム基を有するポリジアセチレンのアニオン検出能の評価 (2012)
  • Author(s): 前谷枝保・中村亮介・堺井亮介・梅田哲・津田勝幸・佐藤敏文・覚知豊次
  • Organizer: 第46回 (2011年度) 高分子学会北海道支部研究発表会
  • Place of Presentation: 北海道大学百年記念会館
• [Book] New Functional Polymers using Host-Guest Chemistry (2012)
  • Author(s): R. Sakai, T. Kakuchi
  • Publisher: Functional Polymers by Post-Polymerization Modification, ed. by Theato, P. and Klok, H. A., Wiley-VCH
• [Book] Functional Polymers by Post-Polymerization Modification (2012)
  • Author(s): R. Sakai, T. Kakuchi
  • Publisher: Wiley-VCH