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Hole doping in boron icosahedral cluster solids with unique method and development of new superconductors

Research Project

Project/Area Number 23760625
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical properties of metals
Research InstitutionTokyo University of Science

Principal Investigator

HYODO Hiroshi  東京理科大学, 基礎工学部, 助教 (30548863)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsデドープ / ボロン正20面体クラスター固体 / 電気化学 / ホールドープ / リチウム / ドーピング / 超伝導 / デインターカレーション / インターカレーション
Research Abstract

Li-dedoped beta rhombohedral boron (・-B), which has different structure with Li-doped ・-B, was synthesized by the heat treatment of Li-doped ・-B at 600 and 800 ℃. Especially, it was found that Li was successfully dedoped with keeping the removal of interstitial B for Li7・-B obtained by the heat treatment at 600 ℃ and the hole doping was indicated. It was also found that V removes by electrochemical Li doping into V doped ・-B.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (25 results)

All 2013 2012 2011

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (23 results) (of which Invited: 2 results)

  • [Journal Article] Self-compensation property of beta-rhombohedral boron doped with high Li concentration2012

    • Author(s)
      Hiroshi Hyodo, Akimitsu Nezu, Kohei Soga, Kaoru Kimura
    • Journal Title

      SOLID STATE SCIENCES

      Volume: 14巻 Issue: 11-12 Pages: 1578-1583

    • DOI

      10.1016/j.solidstatesciences.2012.01.026

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity in Li-doped α-rhombohedral boron2011

    • Author(s)
      T.Nagatochi
    • Journal Title

      Physical Review B

      Volume: 83 Issue: 18

    • DOI

      10.1103/physrevb.83.184507

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Self-compensation proper and bonding co ersion of V nd Li or Mg co-doped ・-rhombohedral boron2013

    • Author(s)
      H. Hyodo
    • Organizer
      17th International Symposium on Intercalation Compounds (ISIC17)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2013-05-16
    • Related Report
      2012 Final Research Report
  • [Presentation] V ドープ・菱面体晶ボロンへの Li ドープによる自己補償2013

    • Author(s)
      井上翔太
    • Organizer
      日本物理学会第68回年次大会, 広島大学東広島キャンパス
    • Place of Presentation
      広島
    • Year and Date
      2013-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Self-compensation property and bonding conversion of V and Li or Mg co-doped beta-rhombohedral boron2013

    • Author(s)
      Hiroshi Hyodo, Shouta Inoue, Hiroyuki Iseki, Kohei Soga and Kaoru Kimura
    • Organizer
      ISIC17 (17th International Symposium on Intercalation Compounds)
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Vドープβ菱面体晶ボロンへのLiドープによる自己補償2013

    • Author(s)
      井上翔太,兵藤宏,曽我公平,木村薫
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学(広島県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] V ドープβ菱面体晶ボロンへの Li ドープによる自己補償2012

    • Author(s)
      井上翔太
    • Organizer
      第8回日本ホウ索・ホウ化物研究会(JSBB),東京都市大学世田谷キャンパス
    • Place of Presentation
      東京
    • Year and Date
      2012-12-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Self-compensation, Bonding-distribution and Thermoelectric Properties of B-based and Al-based Icosahedral and Decagonal Cluster Solidsas Structurally Complex Materials2012

    • Author(s)
      K. imura
    • Organizer
      2012MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2012-11-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Self-compensation and bonding-conversion in B-based and Al-based icosahedral cluster solids2012

    • Author(s)
      K. Kimura
    • Organizer
      Japan-France Joint Seminar 2012: Physics and Control of Clustering Solids, Awaji Yumebutai
    • Place of Presentation
      Hyogo,Japan
    • Year and Date
      2012-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity in Li-doped α-Rhombohedral Boron2012

    • Author(s)
      H. Hyodo
    • Organizer
      Japan-France Joint Seminar 2012: Physics and Control of Clustering Solids, Awaji Yumebutai
    • Place of Presentation
      Hyogo, Japan
    • Year and Date
      2012-11-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity and Self-Compensation in Metal Doped Boron Icosahedral Cluster Solids2012

    • Author(s)
      H. Hyodo
    • Organizer
      Materials Science & Technology 2012 Conference & Exhibition (MS&T'12)
    • Place of Presentation
      Pittsburgh, USA.(招待講演)
    • Year and Date
      2012-10-08
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity in Li-doped alpha-Rhombohedral Boron2012

    • Author(s)
      H. Hyodo
    • Organizer
      2012 MRS Spring Meeting & Exhibit, Moscone West Convention Center/ Marriott Marquis
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2012-04-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity and self-compensation in metal doped Boron icosahedral cluster solids2012

    • Author(s)
      Hiroshi Hyodo, T. Nagatochi, A. Sumiyoshi, K. Soga, Y. Sato, M. Terauchi, K. Kirihara, K. Kawaguchi, Y. Shimizu, T. Sasaki, N. Koshizaki and K. Kimura
    • Organizer
      MS&T - Materials Science and Technology Conference and Exhibition 2012
    • Place of Presentation
      Pittsburgh, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Self-compensation, Bonding-distribution and Thermoelectric Properties of B-based and Al-based Icosahedral and Decagonal Cluster Solids as Structurally Complex Materials2012

    • Author(s)
      Kaoru Kimura; Miyazaki Yoshinobbu; Hiroshi Hyodo; Yoshiki Takagiwa; Junpei T. Okada; Eiji Abe; Kazuhiro Kirihara; Kohei Soga; Yoshihiko Yokoyama; Ken'ichi Kato; Masaki Takata
    • Organizer
      2012 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Vドープβ菱面体晶ボロンへのLiドープによる自己補償2012

    • Author(s)
      井上翔太、兵藤宏、曽我公平、木村薫
    • Organizer
      第8回日本ホウ索・ホウ化物研究会(JSBB)
    • Place of Presentation
      東京都市大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Superconductivity in Li-doped α-Rhombohedral Boron2012

    • Author(s)
      Hirhoshi HYODO, Takenori Nagatochi, Atsuro Sumiyoshi, Kohei Soga, Yohei Sato, Masami Terauchi and Kaoru Kimura
    • Organizer
      Japan-France Joint Seminar 2012: Physics and Control of Clustering Solids
    • Place of Presentation
      Hyogo, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Self-compensation and bonding-conversion in B-based and Al-based icosahedral cluster solids2012

    • Author(s)
      Kaoru KIMURA, Hiroshi Hyodo; Yoshiki Takagiwa, Kazuhiro Kirihara; Kohei Soga, Ken'ichi Kato; Masaki Takata
    • Organizer
      Japan-France Joint Seminar 2012: Physics and Control of Clustering Solids
    • Place of Presentation
      Hyogo, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Superconductivity in Li-doped alpha-Rhombohedral Boron,2012

    • Author(s)
      Hiroshi Hyodo, Takenori Nagatochi, Atsuro Sumiyoshi, Kohei Soga, Yohei Sato, Masami Terauchi, Kaoru Kimura
    • Organizer
      2012 MRS Spring Meeting & Exhibit
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] ボロン正 20 面体クラスター固体の自己補償 II2011

    • Author(s)
      兵藤宏
    • Organizer
      日本物理学会 2011 年ron, 秋季大会, 富山大学
    • Place of Presentation
      富山
    • Year and Date
      2011-09-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Self-Compensation and Bonding-Conversion in B-Based and Al-Based Icosahedral Cluster Solids2011

    • Author(s)
      K. Kimura
    • Organizer
      17th International Symposium on BoBorides and Related Materials (ISBB2011)
    • Place of Presentation
      Istanbul, Turkey
    • Year and Date
      2011-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity in Li-doped α-Rho bohedral Bron2011

    • Author(s)
      H. Hyodo
    • Organizer
      17thInternational Symposium on Boron,Borides and Related Materials(ISBB2011)
    • Place of Presentation
      Istanbul,Turkey
    • Year and Date
      2011-09-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity in Li-doped a-Rhombohedral Boron2011

    • Author(s)
      H. Hyodo et al.
    • Organizer
      ISBB2011
    • Place of Presentation
      Istanbul (Turkey)
    • Related Report
      2011 Research-status Report
  • [Presentation] Self-Compensation and Bonding-Conversion in ICS2011

    • Author(s)
      K. Kimura and H. Hyodo et al.
    • Organizer
      ISBB2011(招待講演)
    • Place of Presentation
      Istanbul (Turkey)
    • Related Report
      2011 Research-status Report
  • [Presentation] Doping Behavior of V and Mg Co-Doped beta-B2011

    • Author(s)
      K. Soga, H. Hyodo, H. Iseki, K. Kimura
    • Organizer
      ISBB2011
    • Place of Presentation
      Istanbul (Turkey)
    • Related Report
      2011 Research-status Report
  • [Presentation] ボロン正20面体クラスター固体の自己補償II2011

    • Author(s)
      兵藤宏,井関博之,根津暁充,細井慎,曽我公平,木村薫
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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