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Synthesis of pure sintered body of hexagonal diamond and its characterization

Research Project

Project/Area Number 23760640
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionEhime University

Principal Investigator

OHFUJI Hiroaki  愛媛大学, 地球深部ダイナミクス研究センター, 准教授 (80403864)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords六方晶ダイヤモンド / 高圧実験 / 高温高圧 / 直接変換 / 高温高圧実験 / 物性測定 / 電子顕微鏡観察
Research Abstract

We performed a series of high pressure and high temperature experiments using a large-volume press to synthesize a pure, single-phase hexagonal diamond sintered body. Our study demonstrated that single-phase hexagonal diamond, which includes neither traces of unreacted graphite starting material nor cubic diamond, can be obtained at 25 GPa and 1100-1500C through direct conversion of highly-oriented, highly-crystalline graphite. The sample consists of extremely thin layered units (a few to several tens of nm) and is as dense as cubic diamond. Since our preliminary hardness measurements provided very high indentation hardness values comparable to or exceeding that of cubic diamond, this nano-sintered body of pure hexagonal diamond would have potential application as a novel ultra-hard material.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (31 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (19 results) (of which Invited: 4 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 2 results)

  • [Journal Article] Nano-layered diamond sintered compact obtained by direct conversion from highly oriented graphite under high pressure and high temperature.2013

    • Author(s)
      F. Isobe, H. Ohfuji, H. Sumiya, T. Irifune
    • Journal Title

      ournal of Nanomaterials

      Volume: 2013 Issue: 1 Pages: 380165-380165

    • DOI

      10.1155/2013/380165

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure and stability of carbon nitride under high pressure and high temperature up to 125 GPa and 3000 K2013

    • Author(s)
      Y. Kojima, H. Ohfuji
    • Journal Title

      Diamond and Related Materials

      Volume: 39 Pages: 1-7

    • DOI

      10.1016/j.diamond.2013.07.006

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A novel technique for the synthesis of nanodiamond powder2013

    • Author(s)
      L. Fang, H. Ohfuji, T. Irifune
    • Journal Title

      Journal of Nanomaterials

      Volume: 2013 Issue: 1 Pages: 201845-201845

    • DOI

      10.1155/2013/201845

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of diamond powders from melamine under high pressure and high temperature2013

    • Author(s)
      L. Fang, X. Chen, H. Ohfuji, T. Irifune, G. Sun, B. Chen, S. Peng
    • Journal Title

      Chinese Physics C

      Volume: 37 Issue: 8 Pages: 88002-88002

    • DOI

      10.1088/1674-1137/37/8/088002

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of diamond powders from melamine under high pressure and high temperature. Chinese Physics C, in press.2013

    • Author(s)
      L. Fang, X. Chen, H. Ohfuji, T. Irifune, G. Sun, B. Chen, S. Peng
    • Journal Title

      Chinese Physics C

      Volume: NA

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of graphite crystallinity on the microtexture of nano-polycrystalline diamond obtained by direct conversion.2012

    • Author(s)
      H. Ohfuji, S. Okimoto, T. Kunimoto, F. Isobe, H. Sumiya, K. Komatsu, T. Irifune
    • Journal Title

      Physics and Chemistry of Minerals,

      Volume: 39 Issue: 7 Pages: 543-552

    • DOI

      10.1007/s00269-012-0510-3

    • Related Report
      2013 Final Research Report 2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Wear resistance of nano-polycrystalline diamond with various hexagonal diamond contents2012

    • Author(s)
      A. Kurio, Y. Tanaka, H. Sumiya, T. Irifune, T. Shinmei, H. Ohfuji, H. Kagi
    • Journal Title

      Journal of Superhard Materials

      Volume: 34 Issue: 6 Pages: 3-11

    • DOI

      10.3103/s1063457612060081

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Experimental study on the stability of graphitic C3N4 under high pressure and high temperature2011

    • Author(s)
      L. Fang, H. Ohfuji, T. Shinmei, T. Irifune
    • Journal Title

      Diamond and Related Materials

      Volume: 20 Issue: 5-6 Pages: 819-825

    • DOI

      10.1016/j.diamond.2011.03.034

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] 高温高圧下におけるグラファイト-ダイヤモンド相転移と組織化メカニズム2013

    • Author(s)
      大藤弘明
    • Organizer
      日本結晶学会
    • Place of Presentation
      熊本大学
    • Year and Date
      2013-10-13
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] ナノ多結晶ダイヤモンドの生成メカニズムと微細組織2013

    • Author(s)
      大藤弘明
    • Organizer
      日本機械学会講習会
    • Place of Presentation
      東京
    • Year and Date
      2013-06-28
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] 六方晶ダイヤモンドの単相バルク焼結体合成と組織評価2012

    • Author(s)
      大藤弘明,元木健介,磯部太志,入舩徹男,角谷均
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2012-11-07
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイト-六方晶ダイヤモンドの相転移メカニズム-グラファイトの結晶性と静水圧性の影響-2012

    • Author(s)
      大藤弘明,山下智晴
    • Organizer
      日本鉱物科学会2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      2012-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイト→六方晶ダイヤモンドの相転移メカニズムの実験的考察-グラファイトの結晶性と静水圧性の影響-2012

    • Author(s)
      大藤弘明,山下智晴
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2012-05-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Phase transition mechanism and microtexture evolution through graphite-diamond transition under high pressure and high temperature2012

    • Author(s)
      H. Ohfuji
    • Organizer
      9th International Workshop on Water Dynamics
    • Place of Presentation
      Tohoku Univ.
    • Year and Date
      2012-03-08
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Experimental study on the martensite-like phase transition mechanism of graphite to hexagonal diamond2012

    • Author(s)
      H. Ohfuji, H. Takeuchi
    • Organizer
      Joint 2012 COMPRES Annual Meeting and High-Pressure Mineral Physics Seminar-8
    • Place of Presentation
      Lake Tahoe, USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Phase transition mechanism and microtexture evolution through graphite-diamond transition under high pressure and high temperature2012

    • Author(s)
      H. Ohfuji
    • Organizer
      9th International Workshop on Water Dynamics(招待講演)
    • Place of Presentation
      東北大学
    • Related Report
      2011 Research-status Report
  • [Presentation] グラファイトからの六方晶ダイヤモンド直接変換合成と相転移メカニズム2011

    • Author(s)
      大藤弘明,竹内洋貴
    • Organizer
      第52回高圧討論会
    • Place of Presentation
      沖縄キリスト教学院(沖縄)
    • Year and Date
      2011-11-10
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイトからの六方晶ダイヤモンド直接変換合成と相転移メカニズム2011

    • Author(s)
      大藤弘明,竹内洋貴
    • Organizer
      日本鉱物科学会2011年年会
    • Place of Presentation
      茨城大学
    • Year and Date
      2011-09-11
    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Presentation] グラファイトからの六方晶ダイヤモンド直接変換と相転移メカニズム2011

    • Author(s)
      大藤弘明,竹内洋貴
    • Organizer
      日本地球惑星科学連合2011年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2011-05-25
    • Related Report
      2013 Final Research Report
  • [Presentation] 高温高圧下直接変換によって合成されたアモルファスダイヤモンド2011

    • Author(s)
      大藤弘明,片桐政人,小竹翔子,角谷均
    • Organizer
      第52回高圧討論会
    • Place of Presentation
      沖縄キリスト教学院
    • Related Report
      2011 Research-status Report
  • [Presentation] グラファイトからの六方晶ダイヤモンド直接変換合成と相転移メカニズム2011

    • Author(s)
      大藤弘明,竹内洋貴
    • Organizer
      第52回高圧討論会
    • Place of Presentation
      沖縄キリスト教学院
    • Related Report
      2011 Research-status Report
  • [Presentation] グラファイトからの六方晶ダイヤモンド直接変換合成と相転移メカニズム2011

    • Author(s)
      大藤弘明,竹内洋貴
    • Organizer
      日本地球惑星連合2011年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2011 Research-status Report
  • [Presentation] 高温高圧下におけるダイヤモンドナノ粒子の直接焼結

    • Author(s)
      大藤弘明,宇田博亮,磯部太志,入舩徹男,角谷均
    • Organizer
      第54回高圧討論会
    • Place of Presentation
      新潟
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高温高圧下におけるグラファイト-ダイヤモンド相転移と組織化メカニズム

    • Author(s)
      大藤弘明
    • Organizer
      日本結晶学会2013年度年会
    • Place of Presentation
      熊本大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] グラファイト→六方晶ダイヤモンドの相転移メカニズムの実験的考察-グラファイトの結晶性と静水圧性の影響-

    • Author(s)
      大藤弘明,山下智晴
    • Organizer
      日本地球惑星科学連合2012年大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2012 Research-status Report
  • [Presentation] グラファイト-六方晶ダイヤモンドの相転移メカニズム-グラファイトの結晶性と静水圧性の影響-

    • Author(s)
      大藤弘明,山下智晴
    • Organizer
      日本鉱物科学会2012年年会
    • Place of Presentation
      京都大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 六方晶ダイヤモンドの単相バルク焼結体合成と組織評価

    • Author(s)
      大藤弘明,元木健介,磯部太志,入舩徹男,角谷均
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 六方晶ダイヤモンドの単相バルク焼結体の製造方法2013

    • Inventor(s)
      大藤弘明,入舩徹男
    • Industrial Property Rights Holder
      大藤弘明,入舩徹男
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-02-06
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 六方晶ダイヤモンド単相バルク焼結体およびその製造方法2013

    • Inventor(s)
      大藤弘明,入舩徹男
    • Industrial Property Rights Holder
      大藤弘明,入舩徹男
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-02-06
    • Related Report
      2012 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 六方晶ダイヤモンドの単相バルク焼結体の製造方法2012

    • Inventor(s)
      大藤弘明,入舩徹男
    • Industrial Property Rights Holder
      大藤弘明,入舩徹男
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-180427
    • Filing Date
      2012-08-16
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 六方晶ダイヤモンド単相バルク焼結体およびその製造方法2012

    • Inventor(s)
      大藤弘明,入舩徹男
    • Industrial Property Rights Holder
      大藤弘明,入舩徹男
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-180427
    • Filing Date
      2012-08-16
    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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