| Project/Area Number |
23760704
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Material processing/treatments
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| Research Institution | Tokyo National College of Technology |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
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| Keywords | 多層コアシェル触媒 / ダイレクトアンモニア燃料電池 / 燃料電池 / アンモニア酸化 / 触媒・化学プロセス / 新エネルギー |
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| Research Abstract |
Multi-walled carbon nanotube (MWCNT) supported multi-layered shell core noble metal particles has been developed by an ethanol reduction method. The successful combination of metals were Pt outer shell / Ir inner shell / Pd core and Pt outer shell / Ir inner shell / Rh core. It is demonstrated that the overpotential of Pt/Ir/Rh/MWCNT by the ethanol reduction method was lower than that of Pt and Pt/Ir/MWCNT, suggesting that the electronic state of a shell metal was influenced by the core metal to change the catalytic activity toward ammonia oxidation in the case of two layer shells. Thus, it is suggested that multilayer shells enable to adjust the adsorption energy of Nads which is a poisoning specie of ammonia oxidation.
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