Tunable catalysis by using high-density mixed monolayer
Project/Area Number |
23760735
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Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Multi-year Fund |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | Hokkaido University |
Principal Investigator |
HARA Kenji 北海道大学, 触媒化学研究センター, 准教授 (10333593)
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 単分子層 / 金表面 / 触媒反応場 / 選択性 / 協奏機能 / 触媒調製化学 / 金属錯体 / イソシアニド / 鉄 / ニッケル / 水素化 / 触媒 / ロジウム / 銅 / 金 / 表面 |
Research Abstract |
This research was proposed to establish a novel versatile preparation method to provideunique and demanded catalytic environment by utilizing two-dimensional high-densitymolecular assembly on surface. Densely-packed mixed monolayer of catalytically activeunit and performance-determining unit was set to be key components to realize thetargeted purpose. The present research accomplished achievement in preparing severalcatalyst systems which afford usually difficult selectivity, or high catalyst turnover numberand recyclability.
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Report
(3 results)
Research Products
(49 results)