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Development of hydrodeoxygenation catalysts for conversion of biomass lignin

Research Project

Project/Area Number 23760737
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

NAKAGAWA Yoshinao  東北大学, 工学研究科, 助教 (10436545)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords資源 / エネルギー利用技術 / 水素化 / シクロヘキサノール / 水素化分解
Research Abstract

Hydrodeoxygenation of biomass-lignin-derived compounds has been investigated using guaiacol as a model substrate. Both multi-step process and single-step process were developed. The multi-step process involves steps using Rh catalyst, Ru catalyst, and Ir-ReOx catalyst. Cyclohexanol was obtained in good yield. The single-step process uses Ru catalyst and base co-catalyst, giving high yield of cyclohexanol.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (15 results)

All 2013 2012

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] One-Pot Conversion of Sugar and Sugar Polyols to n-Alkanes without C-C Dissociation over the Ir-ReOx/SiO2 Catalyst Combined with H-ZSM-52013

    • Author(s)
      Kaiyou Chen
    • Journal Title

      ChemSusChem

      Volume: 6 Issue: 4 Pages: 613-621

    • DOI

      10.1002/cssc.201200940

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Performance, structure and mechanism of Pd–Ag alloy catalyst for selective oxidation of glycerol to dihydroxyacetone2013

    • Author(s)
      Shota Hirasawa
    • Journal Title

      Journal of Catalysis

      Volume: 300 Pages: 205-216

    • DOI

      10.1016/j.jcat.2013.01.014

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Production of Biobutanediols by the Hydrogenolysis of Erythritol2012

    • Author(s)
      Y. Amada, H. Watanabe, Y. Hirai, Y. Kajikawa, Y. Nakagawa and K. Tomishige
    • Journal Title

      ChemSusChem

      Volume: 5 Issue: 10 Pages: 1991-1999

    • DOI

      10.1002/cssc.201200121

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Total Hydrogenation of Furfural over a Silica-Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor2012

    • Author(s)
      Yoshinao Nakagawa
    • Journal Title

      ChemCatChem

      Volume: 4 Issue: 11 Pages: 1791-1797

    • DOI

      10.1002/cctc.201200218

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] C–O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts2012

    • Author(s)
      Kaiyou Chen
    • Journal Title

      Journal of Catalysis

      Volume: 294 Pages: 171-183

    • DOI

      10.1016/j.jcat.2012.07.015

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solid acid co-catalyst for the hydrogenolysis of glycerol to 1,3-propanediol over Ir-ReO_x/SiO_22012

    • Author(s)
      Y. Nakagawa, X. Ning, Y. Amada, K. Tomishige
    • Journal Title

      Appl. Catal. A

      Volume: 433-434 Pages: 123-134

    • DOI

      10.1016/j.apcata.2012.05.009

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective oxidation of glycerol to dihydroxyacetone over Pd-Ag catalyst2012

    • Author(s)
      Shota Hirasawa, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      Catalysis Science and Technology

      Volume: 2巻 Issue: 6 Pages: 1150-1152

    • DOI

      10.1039/c2cy20062g

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 担持Ru触媒を用いたグアイコールの水素化分解によるシクロヘキサノール選択的合成2013

    • Author(s)
      石川桃子・田村正純・中川善直・冨重圭一
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      大阪
    • Year and Date
      2013-02-25
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] ReOx修飾Ir触媒を用いた環状エーテル類の水素化分解反応2012

    • Author(s)
      田村正純・陳凱幼・中川善直・冨重圭一
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Year and Date
      2012-10-11
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Pd-Ag/Cを用いたグリセリンの酸化反応によるジヒドロキシアセトンの生成2012

    • Author(s)
      平澤祥太・中川善直・冨重圭一
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-29
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] ReOx修飾Ir触媒を用いたテトラヒドロフルフリルアルコールの水素化分解反応による1,5-ペンタンジオールの合成2012

    • Author(s)
      陳凱幼・中川善直・冨重圭一
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-29
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] テトラヒドロフルフリルアルコールの水素化分解による1,5-ペンタンジオールの合成におけるレニウム修飾イリジウム触媒の反応特性2012

    • Author(s)
      森一真・陳凱幼・中川善直・冨重圭一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] Ir-ReO_x/SiO_2触媒のグリセリン水素化分解反応機構とエリスリトールへの応用2012

    • Author(s)
      天田靖史・寧玄鶴・梶川泰照・中川善直・冨重圭一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] Ir-ReOx/SiO2触媒のグリセリン水素化分解反応機構とエリスリトールへの応用2012

    • Author(s)
      天田 靖史・寧 玄鶴・梶川 泰照・中川 善直・冨重 圭一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 1,4-アンヒドロエリスリトールの水素化分解物の製造方法2012

    • Inventor(s)
      冨重 圭一、中川 善直、梶川 泰照、平井 雄一郎
    • Industrial Property Rights Holder
      冨重 圭一、中川 善直、梶川 泰照、平井 雄一郎
    • Industrial Property Number
      2012-047993
    • Filing Date
      2012
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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