Study on Design of Multi-functionalized Heterogeneous Catalysts by Use of Layered Hydroxy Double Salt

• Project/Area Number: 23760738
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Catalyst/Resource chemical process
• Research Institution: Chiba University
• Principal Investigator: HARA Takayoshi 千葉大学, 大学院・工学研究科, 助教 (60437358)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: 触媒調製化学 / グリーンケミストリー / 触媒・化学プロセス / ナノ材料 / 二酸化炭素排出削減 / 層状複塩基性塩

Research Abstract

We have developed the multi-functionalized Ni-Zn hydroxyl double salt as a heterogeneous catalystfor CO_2 fixation reaction into epoxides. The isolated Zn^<2+> cation located on Ni(OH)_2 brucite sheet canact as a Lewis acid site to activate epoxide molecule. Intercalation of ethoxide anion as a Lewis baseinto NiZn interlayer was also carried out. The obtained EtO^-/NiZn can promote the above reactioneffectively under 1 atm of CO_2. It can be said that the EtO^-/NiZn has two functions such as Lewis acidityand Lewis basicity on its matrix.

Research Products

• [Journal Article] (2013)
  • Author(s): I. B. Adilina, T. Hara, N. Ichikuni, N. Kumada,S. Shimazu
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 86 Pages: 146-152
• [Journal Article] Recyclable Pd-Incorporated Perovskite-Titanate Catalysts Synthesized in Molten Salts for the Liquid-Phase Oxidation of Alcohols with Molecular Oxygen (2013)
  • Author(s): Indri Badria Adilina, Takayoshi Hara, Nobuyuki Ichikuni, Nobuhiro Kumada, and Shogo Shimazu
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 86 Issue: 1 Pages: 146-152
  • DOI: 10.1246/bcsj.20120215
  • NAID: 130004153129
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed
• [Journal Article] Effect of local structure of Mo oxide on selective photo-oxidation of propane to acetone (2013)
  • Author(s): Nobuyuki Ichikuni, Yuma Nakao, Kazuya Ishizuki, Takayoshi Hara and Shogo Shimazu
  • Journal Title: Catalysis Letters Volume: 143 Issue: 2 Pages: 154-158
  • DOI: 10.1007/s10562-012-0948-4
  • Peer Reviewed
• [Journal Article] (2012)
  • Author(s): Rodiansono, S. Khairi, T. Hara, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Sci. Technol. Volume: 2 Pages: 2139-2145
• [Journal Article] (2012)
  • Author(s): Rodiansono, T. Hara, N. Ichikuni, S. Shimazu
  • Journal Title: Chem. Lett. Volume: 41 Pages: 769-771
• [Journal Article] (2012)
  • Author(s): I. B. Adilina, T. Hara, N. Ichikuni, S. Shimazu
  • Journal Title: J.Mol. Catal. A: Chem.
• [Journal Article] (2012)
  • Author(s): T. Hara, Y. Takami, N. Ichikuni, S. Shimazu
  • Journal Title: Chem. Lett. Volume: 41 Pages: 488-490
• [Journal Article] (2012)
  • Author(s): Hara, M. Hatakeyama, A. Kim, N. Ichikuni, S.Shimazu
  • Journal Title: Green Chem. Volume: 13 Pages: 771-777
• [Journal Article] Size Control of Ni Nanocluster by the Carbon Chain Length of Secondary Alkoxide (2012)
  • Author(s): Hirotake Kitagawa, Nobuyuki Ichikuni, Songhai Xie, Tatsuya Tsukuda, Takayoshi Hara, Shogo Shimazu
  • Journal Title: e-Journal of Surface Science and Nanotechnology Volume: 10 Issue: 0 Pages: 648-650
  • DOI: 10.1380/ejssnt.2012.648
  • NAID: 130004933775
  • ISSN: 1348-0391
  • Peer Reviewed
• [Journal Article] Highly efficient and selective hydrogenation of unsaturated carbonyl compounds using Ni-Sn alloy catalysts (2012)
  • Author(s): Rodiansono, Takayoshi Hara, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Catalysis Science & Technology Volume: 2 Issue: 10 Pages: 2139-2145
  • DOI: 10.1039/c2cy20216f
  • Peer Reviewed
• [Journal Article] A Novel Preparation Method of Ni-Sn Alloy Catalysts Supported on Aluminium Hydroxide: Application to Chemoselective Hydrogenation of Unsaturated Carbonyl Compounds (2012)
  • Author(s): Rodiansono, Takayoshi Hara, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Chemistry Letters Volume: 41 Issue: 8 Pages: 769-771
  • DOI: 10.1246/cl.2012.769
  • NAID: 130004426635
  • Peer Reviewed
• [Journal Article] Preparation and catalysis of supported NiO nanocluster for oxidative coupling of thiophenol (2012)
  • Author(s): Ichikuni, Nobuyuki
  • Journal Title: Transactions of the Materials Research Society of Japan Volume: 37 Pages: 177-180
  • Peer Reviewed
• [Journal Article] Oxidative cleavage of isoeugenol to vanillin under molecular oxygen catalysed by cobalt porphyrin intercalated into lithium taeniolite clay (2012)
  • Author(s): Indri Badria Adilina, Takayoshi Hara, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Journal of Molecular Catalysis A: Chemistry Volume: 361-362 Pages: 72-79
  • DOI: 10.1016/j.molcata.2012.05.005
  • Peer Reviewed
• [Journal Article] CaO-Catalyzed Aerobic Oxidation of α-Hydroxy Ketones: Application for One-pot Synthesis of Quinoxaline Derivatives (2012)
  • Author(s): Takayoshi Hara, Yukihiro Takami, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Chemistry Letters Volume: 41 Issue: 5 Pages: 488-490
  • DOI: 10.1246/cl.2012.488
  • NAID: 130004426565
  • Peer Reviewed
• [Journal Article] Multinuclear Solid-State NMR Study of Allophane (2012)
  • Author(s): Moriaki Hatakeyama, Takayoshi Hara, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 85 Issue: 3 Pages: 372-375
  • DOI: 10.1246/bcsj.20110293
  • NAID: 130004153034
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed
• [Journal Article] Preparation of Clay-Supported Sn Catalysts and Application to Baeyer-Villiger Oxidation (2012)
  • Author(s): Takayoshi Hara, Moriaki Hatakeyama, Arum Kim, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Green Chemistry Volume: 14 Issue: 3 Pages: 771-777
  • DOI: 10.1039/c2gc16437j
  • Peer Reviewed
• [Journal Article] CaO-Catalyzed Aerobic Oxidation of α-Hydroxy Ketones: Application for One-pot Synthesis of Quinoxaline Derivatives (2012)
  • Author(s): T. Hara, Y. Takami, N. Ichikuni, and S. Shimazu
  • Journal Title: Chemistry Letters Volume: ー
  • Peer Reviewed
• [Journal Article] Preparation and Catalysis of Supported NiO Nanocluster for Oxidative Coupling of Thiophenol (2012)
  • Author(s): N. Ichikuni, O. Tsuchida, J. Naganuma, T. Hara, H. Tsunoyama, T. Tsukuda, and S. Shimazu
  • Journal Title: Transactions of the Materials Research Society of Japan Volume: ー
  • NAID: 130003399077
  • Peer Reviewed
• [Journal Article] (2011)
  • Author(s): T. Hara, J. Sawada, Y. Nakamura, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Sci. Technol. Volume: 1 Pages: 1376-1382
• [Journal Article] (2011)
  • Author(s): K. Motokura, N. Hashimoto, T. Hara, T.Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda
  • Journal Title: Green Chem. Volume: 13 Pages: 2416-2422
• [Journal Article] (2011)
  • Author(s): D. Tsukamoto, M. Ikeda, Y. Shiraishi, T. Hara, 77N. Ichikuni, S. Tanaka, T. Hirai
  • Journal Title: Chem. Eur. J. Volume: 17 Pages: 9816-9824
• [Journal Article] (2011)
  • Author(s): Y. Takahashi, N. Hashimoto, T. Hara, S.Shimazu, T. Mitsudome, T. Mizugaki, K. Jitsukawa,K. Kaneda
  • Journal Title: Chem. Lett. Volume: 40 Pages: 405-407
• [Journal Article] (2011)
  • Author(s): Y. Ogaki, Y. Shinozuka, T. Hara, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Today Volume: 164 Pages: 415-418
• [Journal Article] Characterization of heat-treated synthetic imogolite by 27Al MAS and 27Al MQMAS solid state NMR (2011)
  • Author(s): Moriaki Hatakeyama, Takayoshi Hara, Nobuyuki Ichikuni, and Shogo Shimazu
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 84 Issue: 6 Pages: 656-659
  • DOI: 10.1246/bcsj.20100291
  • NAID: 130004152928
  • Peer Reviewed
• [Journal Article] An anionic D-valine-palladium(II) complex supported on a hydroxy double salt with a Bronsted basic phosphate anion: application for a heterogeneous catalyst toward aerobic alcohol oxidation (2011)
  • Author(s): T. Hara, J. Sawada, Y. Nakamura, N. Ichikuni, and S. Shimazu
  • Journal Title: Catalysis Science & Technology Volume: 1(8) Issue: 8 Pages: 1376-1382
  • DOI: 10.1039/c1cy00223f
  • Peer Reviewed
• [Journal Article] Rhodium-Grafted Hydrotalcite Catalyst for Heterogeneous 1,4-Addition Reaction of Organoboron Reagents to Electron Deficient Olefins (2011)
  • Author(s): Ken Motokura , Norifumi Hashimoto ,Takayoshi Hara, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda
  • Journal Title: Green Chem. Volume: 13巻 Issue: 9 Pages: 2416-2422
  • DOI: 10.1039/c1gc15146k
  • Peer Reviewed
• [Journal Article] Highly Efficient Pd/SiO2-Dimethyl Sulfoxide Catalyst System for Selective Semihydrogenation of Alkynes (2011)
  • Author(s): Yusuke Takahashi, Norifumi Hashimoto,Takayoshi Hara, Shogo Shimazu, TakatoMitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda
  • Journal Title: Chem. Lett Volume: 40巻 Issue: 4 Pages: 405-407
  • DOI: 10.1246/cl.2011.405
  • NAID: 130004426186
  • Peer Reviewed
• [Journal Article] Selective Photocatalytic Oxidation of Alcohols to Aldehydes in Water by TiO_2 Partially Coated with WO_3 (2011)
  • Author(s): Daijiro Tsukamoto, et al
  • Journal Title: Chemistry-A European Journal Volume: 17 Issue: 35 Pages: 9816-9824
  • DOI: 10.1002/chem.201100166
  • Peer Reviewed
• [Journal Article] Hemicellulose decomposition and saccharides production from various plant biomass by sulfonated allophane catalyst (2011)
  • Author(s): Y. Ogaki, Y. Shinozuka, T. Hara, N. Ichikuni, and S. Shimazu
  • Journal Title: Catalysis Today Volume: 164(1) Issue: 1 Pages: 415-418
  • DOI: 10.1016/j.cattod.2010.11.002
  • Peer Reviewed
• [Presentation] Rh水酸化物アニオン導入型層状Ni-Zn複塩基性塩触媒による炭素-炭素結合形成反応 (2013)
  • Author(s): 原孝佳・藤田希未・一國伸之・島津省吾
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津
• [Presentation] 二級アルコキシドを用いた担持Niナノクラスターのサイズ制御およびWGSRへの応用 (2013)
  • Author(s): 北川裕丈・一國伸之・原孝佳・島津省吾
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大学びわこくさつキャンパス
• [Presentation] メソ細孔アルミナに担持されたモリブデン酸化物の構造とプロパン光酸化反応選択性 (2013)
  • Author(s): 石附和弥・一國伸之・原孝佳・島津省吾
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大学びわこくさつキャンパス
• [Presentation] Rh水酸化物アニオン導入型層状Ni-Zn複塩基性塩触媒による炭素-炭素結合形成反応 (2013)
  • Author(s): 原孝佳・藤田希未・一國伸之・島津省吾
  • Organizer: 日本化学会第93回春季年会
  • Place of Presentation: 立命館大学びわこくさつキャンパス
• [Presentation] スルホン化粘土化合物触媒を用いたフルクトースからの5-ヒドロキシメチルフルフラールの合成 (2012)
  • Author(s): 石崎慧・原孝佳・一國伸之・島津省吾
  • Organizer: 第28回日本イオン交換研究発表会
  • Place of Presentation: 東京工業大学大岡山キャンパス
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒によるCO_2のエポキシドへの環化付加反応 (2011)
  • Author(s): 原孝佳・中村宜央・一國伸之・島津省吾
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北見
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒を用いたCO_2とエポキシドからの環状カーボネート合成 (2011)
  • Author(s): 原孝佳・中村宜央・一國伸之・島津省吾
  • Organizer: 第27回日本イオン交換研究発表会・第30回溶媒抽出討論会連合年会
  • Place of Presentation: 宮崎
• [Presentation] 反応空間を制御した層状Ni-Zn複塩基性塩触媒による1,3-ジニトロ化合物のワンポット合成 (2011)
  • Author(s): 木澤大二郎・原孝佳・一國伸之・島津省吾
  • Organizer: 第27回日本イオン交換研究発表会・第30回溶媒抽出討論会連合年会
  • Place of Presentation: 宮崎
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒によるCO2のエポキシドへの環化付加反応 (2011)
  • Author(s): 原孝佳・中村 宜央・一國 伸之・島津 省吾
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北見工業大学
• [Presentation] 酸化カルシウムを固体触媒としたa-ヒドロキシケトン類の酸化反応 (2011)
  • Author(s): 高見行洋・原孝佳・一國 伸之・島津 省吾
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北見工業大学
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒を用いたCO2とエポキシドからの環状カーボネート合成 (2011)
  • Author(s): 原孝佳・中村宜央・一國伸之・島津省吾
  • Organizer: 2011年日本イオン交換学会･日本溶媒抽出学会連合年会
  • Place of Presentation: シーガイアコンベンションセンター
• [Presentation] 反応空間を制御した層状Ni-Zn複塩基性塩触媒による1,3-ジニトロ化合物のワンポット合成 (2011)
  • Author(s): 木澤大二郎・原孝佳・一國伸之・島津省吾
  • Organizer: 2011年日本イオン交換学会･日本溶媒抽出学会連合年会
  • Place of Presentation: シーガイアコンベンションセンター