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Development of novel zeolite catalyst with highly catalytic activity in direct synthesis of light olefins through conversion of methanol

Research Project

Project/Area Number 23760740
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionThe University of Kitakyushu (2012)
Tokyo Institute of Technology (2011)

Principal Investigator

IMAI Hiroyuki  北九州市立大学, 国際環境工学部, 講師 (70514610)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsゼオライト / オレフィン製造 / 酸触媒反応 / メタノール転換反応 / 物性制御 / 触媒プロセス / 水熱合成 / アルコール転換反応 / 粒子形態制御 / 酸性質制御 / 小細孔 / 反応機構
Research Abstract

In this study, the development of novel zeolite catalyst for the efficient production of light olefins, which are widely utilized as a raw material of chemicals in the industrial field, from methanol has been studied. The physicochemicalsuch as the particle size and acid strength and catalytic properties of zeolite catalysts with a topology were successfully controlled by varying the structure of organic compounds and the concentration of the starting gel for the zeolite synthesis. In addition, new method for the zeolite synthesis was successfully developed without any organic compounds at shorter synthesis duration compared the conventional methods. In the conversion of methanol to light olefins, nanosized zeolites synthesized employing the novel method above exhibited a longer catalyst life compared with the zeolite with the same structure synthesized by conventional methods.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2012 2011 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (20 results)

  • [Journal Article] Direct Production of Propene from Methoxy Speciesand Dimethyl Ether over H-ZSM-52012

    • Author(s)
      Hiroshi Yamazaki, Hisashi Shima, Hiroyuki Imai, Toshiyuki Yokoi, TakashiTatsumi, Junko N. Kondo
    • Journal Title

      THEJOURNAL OF PHYSICAL CHEMISTRY C

      Volume: 116 Issue: 45 Pages: 24091-24097

    • DOI

      10.1021/jp307290z

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] Production ofhydrocarbons in conversion of methanolover CHA-type zeolite2012

    • Author(s)
      Hiroyuki Imai, Toshiyuki Yokoi, JunkoN. Kondo, Takashi Tastumi
    • Organizer
      the 15thInternational Congress on Catalysts 2012
    • Place of Presentation
      ミュンヘン(ドイツ)
    • Year and Date
      2012-07-03
    • Related Report
      2012 Final Research Report
  • [Presentation] CHA型ゼオライトにおける Si及びAl源の影響2012

    • Author(s)
      林田望、今井裕之、横井俊之、野村淳子、辰巳敬
    • Organizer
      第92回春季年会
    • Place of Presentation
      慶應大学,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] CHA型ゼオライト上でのMTO反応に おける酸性質の影響2012

    • Author(s)
      洞口恵次・今井裕之・横井俊之・野村淳子・辰巳 敬
    • Organizer
      第92回春季年会
    • Place of Presentation
      慶應大学,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] メタノール転換反応におけるCHA型ゼオライトの粒子サイズの影響2012

    • Author(s)
      今井裕之・洞口恵次・横井俊之・野村淳子・辰巳 敬
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京工業大学,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] パルス法を用いた CHA 型ゼオライト上でのメタノール転換反応における反応過程の検討2011

    • Author(s)
      今井裕之,山崎弘史,横井俊之,野村淳子,辰巳敬
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北海道
    • Year and Date
      2011-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of RTH-type zeolites with various types of organic compounds and their catalytic properties as an acid catalyst2011

    • Author(s)
      Hiroyuki Imai, Ming Liu, MasatoYoshioka, Toshiyuki Yokoi, Junko N. Nomura, Takashi Tatsumi
    • Organizer
      5th International FEZA Conference
    • Place of Presentation
      バレンシア(スペイン)
    • Year and Date
      2011-07-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Reaction mechanism of transformation of methanol to olefins over 8-membered ring zeolite2011

    • Author(s)
      Hiroyuki Imai, Hiroshi Yamazaki, ChaoMan-Chien, Toshiyuki Yokoi, Junko N. Kondo, Takashi Tatsumi
    • Organizer
      The 13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      2011-05-25
    • Related Report
      2012 Final Research Report
  • [Presentation] CHA 型ゼオライトによるメタノール転換反応における水蒸気共存効果2011

    • Author(s)
      今井裕之, 横井俊之, 野 村淳子, 辰巳敬
    • Organizer
      第60回石油学会研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2011-05-17
    • Related Report
      2012 Final Research Report
  • [Presentation] CHA型ゼオライトによるメタノール転換反応における水蒸気共存効果2011

    • Author(s)
      今井裕之、横井俊之、野村淳子、辰巳敬
    • Organizer
      第60回石油学会研究発表会
    • Place of Presentation
      タワーホール船堀,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] Reaction Mechanism of Transformation of Methanol to Olefins over 8-membered ring Zeolite2011

    • Author(s)
      Hiroyuki Imai, Hiroshi Yamazaki, Chao Man-Chien, Toshiyuki Yokoi, Junko N. Kondo, Takashi Tatsumi
    • Organizer
      The 13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      済州島,韓国
    • Related Report
      2011 Research-status Report
  • [Presentation] Synthesis of RTH-type zeolites with various types of organic compounds and their catalytic properties as an acid catalyst2011

    • Author(s)
      Hiroyuki Imai, Ming Liu, Masato Yoshioka, Toshiyuki Yokoi, Junko N. Kondo, Takashi Tatsumi
    • Organizer
      5th International FEZA Conference
    • Place of Presentation
      バレンシア,スペイン
    • Related Report
      2011 Research-status Report
  • [Presentation] パルス法を用いたCHA型ゼオライト上でのメタノール転換反応における反応過程の検討2011

    • Author(s)
      今井裕之、山崎弘史、横井俊之、野村淳子、辰巳敬
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学,北海道
    • Related Report
      2011 Research-status Report
  • [Presentation] CHA型ゼオライトの合成に及ぼす有機構造規定剤の影響2011

    • Author(s)
      林田望、今井裕之、横井俊之、野村淳子、辰巳敬
    • Organizer
      第1回CSJ化学フェスタ
    • Place of Presentation
      早稲田大学,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] メタノール転換反応におけるCHA型ゼオライトの結晶サイズの影響2011

    • Author(s)
      洞口恵次・今井裕之・横井俊之・野村淳子・辰巳 敬
    • Organizer
      第1回CSJ化学フェスタ
    • Place of Presentation
      早稲田大学,東京
    • Related Report
      2011 Research-status Report
  • [Presentation] MTO反応での低級オレフィン生成に関する速度論的検討

    • Author(s)
      山崎弘史、今井裕之、横井俊之、辰巳敬、野村淳子
    • Organizer
      石油学会第61回研究発表会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2012 Annual Research Report
  • [Presentation] CON型アルミノシリケートの合成と触媒特性

    • Author(s)
      吉岡真人、今井裕之、横井俊之、辰巳敬
    • Organizer
      石油学会第61回研究発表会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2012 Annual Research Report
  • [Presentation] Production of hydrocarbons in conversion of methanol over CHA-type zeolite

    • Author(s)
      Hiroyuki Imai, Toshiyuki Yokoi, Junko N. Kondo, Takashi Tatsumi
    • Organizer
      the 15th International Congress on Catalysts 2012
    • Place of Presentation
      ミュンヘン、ドイツ
    • Related Report
      2012 Annual Research Report
  • [Presentation] ゼオライト固体酸触媒上でのエチレンからの低級オレフィン合成

    • Author(s)
      洞口恵次、横井俊之、今井裕之、野村淳子、辰巳敬
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 基質の種類によるゼオライト上のメトキシ種の反応機構の違い

    • Author(s)
      山崎弘史、今井裕之、横井俊之、辰巳敬、野村淳子
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] メタノール転換反応におけるMWW型ゼオライトの酸性質の影響

    • Author(s)
      今井裕之、荒川美咲、黎 暁紅
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田キャッスルホテル
    • Related Report
      2012 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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