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Development of sunlight-driven devise for catalytic transformation using metal complexes fixed on solid surfaces

Research Project

Project/Area Number 23760743
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionOsaka University

Principal Investigator

MORI Kohsuke  大阪大学, 大学院・工学研究科, 准教授 (90423087)

Co-Investigator(Kenkyū-buntansha) YAMASHITA Hiromi  大阪大学, 大学院・工学研究科, 教授 (40200688)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords金属錯体 / メソポーラシシリカ / ゼオライト / 光触媒 / メソポーラスシリカ
Research Abstract

The design of promising photocatalysts being applied to the synthesis of specialty chemicals under visible light irradiation is a crucial challenging task. In this study, the development of new generation photocatalyst with novel functionalities was performed by the exploitation of sunlight-driven photocatalyticdevises and selective molecular transformations.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (48 results)

All 2013 2012 2011 Other

All Journal Article (27 results) (of which Peer Reviewed: 2 results) Presentation (20 results) (of which Invited: 5 results) Remarks (1 results)

  • [Journal Article] What Are the Active Species in the Photoinduced H2 Production with Terpyridyl Pt(II) Complexes? An Investigation by in Situ XAFS2013

    • Author(s)
      M. Martis, K. Mori, K. Kato, G. Sankar, H. Yamashita
    • Journal Title

      ChemPhysChem

      Volume: 14 Pages: 1122-1125

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] 可視光を有効利用する光触媒-プラズモンがもたらす新しい光エネルギー変換-2013

    • Author(s)
      森 浩亮、山下弘巳
    • Journal Title

      化学

      Volume: 68 Pages: 70-71

    • Related Report
      2012 Final Research Report
  • [Journal Article] ナノ細孔空間を利用したシングルサイト光触媒の設計と応用2013

    • Author(s)
      亀川孝、森 浩亮、山下弘巳
    • Journal Title

      Electrochemistry

      Volume: 81 Pages: 98-102

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Intercalation of Pt(II) Terpyridine Complexes into Layered K_4Nb_6O_17and Visible-light Driven Photocatalytic Production of H_22012

    • Author(s)
      K. Mori, S. Ogawa, M. Martis, H. Yamashita
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 116 Pages: 18873-18877

    • Related Report
      2012 Final Research Report
  • [Journal Article] Hybrid Mesoporous Silica Materials Functionalized by Pt(II) Complexes: Correlation between Spatial Distribution of Active Center, Photoluminescence Emission, and Photocatalytic Activity2012

    • Author(s)
      K. Mori, K. Watanabe, Y. Terai, Y. Fujiwara, H. Yamashita
    • Journal Title

      Chemistry - A European Journal

      Volume: 18 Pages: 11371-11378

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Reduction of CO_2 with H_2O on Various Titanium Oxide Photocatalysts2012

    • Author(s)
      K. Mori, H. Yamashita, M. Anpo
    • Journal Title

      RSC Advances

      Volume: 2 Pages: 3165-3172

    • Related Report
      2012 Final Research Report
  • [Journal Article] Photoluminescence Emission and Photoinduced Hydrogen Production Driven by Pt(II) Pyridyl Complexes Anchored onto Mesoporous Silica2012

    • Author(s)
      K. Mori, K. Watanabe, K. Fuku, H. Yamashita
    • Journal Title

      Chemistry - A European Journal

      Volume: 18 Pages: 415-418

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
  • [Journal Article] ナノ多孔体に固定化した金属錯体の光触媒特性2012

    • Author(s)
      森 浩亮、山下弘巳
    • Journal Title

      光化学

      Volume: 43 Pages: 127-133

    • NAID

      10031134266

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] 無機マトリクスに固定化した金属錯体光触媒2012

    • Author(s)
      森 浩亮、山下弘巳
    • Journal Title

      触媒

      Volume: 54 Pages: 327-332

    • NAID

      10030934299

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Intercalation of Pt(II) Terpyridine Complexes into Layered K_4Nb_6O_17 and Visible-light Driven Photocatalytic Production of H_22012

    • Author(s)
      K. Mori, S. Ogawa, M. Martis, H. Yamashita
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 116 Issue: 35 Pages: 18873-18877

    • DOI

      10.1021/jp3059799

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic reduction of CO2 with H2O on Various Titanium Oxide Photocatalysts2012

    • Author(s)
      K. Mori, H. Yamashita, M. Anpo
    • Journal Title

      RSC Advances

      Volume: 2 Issue: 8 Pages: 3165-3172

    • DOI

      10.1039/c2ra01332k

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] TiO2 Photocatalyst Supported on Highly Hydrophobic FAU Zeolite for Degradation of Organic Compounds in Water and Air: Structural, Sorptive and Photocatalytic Studies2012

    • Author(s)
      Y. Kuwahara, J. Aoyama, K. Miyakubo, T. Eguchi, T. Kamegawa, K. Mori, H. Yamashita
    • Journal Title

      Journal of Catalysis

      Volume: 285 Pages: 223-234

    • Related Report
      2011 Research-status Report
  • [Journal Article] Synthesis of Pd Nanoparticles on Heteropolyacid-supported Silica by Photo-assisted Deposition Method: an Active Catalyst for Direct Synthesis of Hydrogen Peroxide2012

    • Author(s)
      K. Mori, K. Furubayashi, S. Okada, H. Yamashita
    • Journal Title

      RSC Advances

      Volume: 2 Pages: 1047-1054

    • Related Report
      2011 Research-status Report
  • [Journal Article] Low-temperature Synthesis of Highly Hydrophilic Ti-containing Mesoporous Silica Thin Films on Polymer Substrates by Photocatalytic Removal of Structure Directing Agents2011

    • Author(s)
      Y. Horiuchi, H. Ura, T. Kamegawa, K. Mori, and H. Yamashita
    • Journal Title

      Journal of Materials Chemistry

      Volume: 21 Pages: 236-241

    • Related Report
      2011 Research-status Report
  • [Journal Article] Design of Colloidal and Supported Metal Nanoparticles: Their Synthesis, Characterization, and Catalytic Application2011

    • Author(s)
      K. Mori and H. Yamashita
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 54 Pages: 1-14

    • NAID

      10027974586

    • Related Report
      2011 Research-status Report
  • [Journal Article] Anchoring of Pt(II) Pyridyl Complex to Mesoporous Silica Materials: Enhanced Photoluminescence Emission at Room Temperature and Photooxidation Activity using Molecular Oxygen2011

    • Author(s)
      K. Mori, K. Watanabe, M. Kawashima, M. Che, and H. Yamashita
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 115 Pages: 1044-1050

    • Related Report
      2011 Research-status Report
  • [Journal Article] Design of Superhydrophobic Surfaces by Synthesis of Carbon Nanotubes over Co-Mo Nanocatalysts Deposited under Microwave Irradiation on Ti-containing Mesoporous Silica Thin Films2011

    • Author(s)
      Y. Horiuchi, Y. Shimizu, T. Kamegawa, K. Mori, and H. Yamashita
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 13 Pages: 6309-6309

    • Related Report
      2011 Research-status Report
  • [Journal Article] Synthesis of Pd-supported Nanosized Mesoporous Silica as a Spherical Nanocatalyst for Suzuki-Miyaura Coupling Reaction2011

    • Author(s)
      S. Okada, T. Urata, T. Kamegawa, K. Mori, and H. Yamashita
    • Journal Title

      Chemistry Letters

      Volume: 40 Pages: 609-611

    • NAID

      10028243933

    • Related Report
      2011 Research-status Report
  • [Journal Article] An Efficient Method for the Creation of Superhydrophobic Surface: Ethylene Polymerization over Self-assembled Colloidal Silica Nanoparticles Incorporating Single-site Cr-oxide Catalysts2011

    • Author(s)
      Y. Horiuchi, K. Fujiwara, T. Kamegawa, K. Mori, and H. Yamashita
    • Journal Title

      Journal of Materials Chemistry

      Volume: 21 Pages: 8543-8546

    • Related Report
      2011 Research-status Report
  • [Journal Article] Preparation of Hydrophobically Modified Single-site Ti-containing Mesoporous Silica (TiSBA-15) and Their Enhanced Catalytic Performances2011

    • Author(s)
      T. Kamegawa, N. Suzuki, K. Tsuji, J. Sonoda, Y. Kuwahara, K. Mori, H. Yamashita
    • Journal Title

      Catalysis Today

      Volume: 175 Pages: 393-397

    • Related Report
      2011 Research-status Report
  • [Journal Article] Active Site Design in a Core-shell Nanostructured Catalyst for One-pot Oxidation Reaction2011

    • Author(s)
      S. Okada, K. Mori, T. Kamegawa, H. Yamashita
    • Journal Title

      Chemistry - A European Journal

      Volume: 17 Pages: 9047-9051

    • Related Report
      2011 Research-status Report
  • [Journal Article] Highly-Efficient Thermal Decomposition of Volatile Organic Compound by Pt/CeO2/ZSM-52011

    • Author(s)
      K. Fuku, M. Goto, T. Kamegawa, K. Mori, H. Yamashita
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 9 Pages: 979-981

    • NAID

      130004152970

    • Related Report
      2011 Research-status Report
  • [Journal Article] Size Controlled Deposition of Ag Nanoparticles on Alumina by the Assist of Photo-induced Chromic Reaction and Study of Their Catalysis2011

    • Author(s)
      K. Mori, A. Kumami, H. Yamashita
    • Journal Title

      Physical Chemistry & Chemical Physics

      Volume: 13 Pages: 15821-15824

    • Related Report
      2011 Research-status Report
  • [Journal Article] Controlled Synthesis and Surface Hydrophilic Properties of Ti-Containing Mesoporous Silica Thin Films Using Various Structure-Directing Agents2011

    • Author(s)
      Y. Horiuchi, H. Ura, T. Kamegawa, K. Mori, H. Yamashita
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 115 Pages: 15410-15415

    • Related Report
      2011 Research-status Report
  • [Journal Article] Enhancement in Adsorption Property and Catalytic Activity of Enzymes Immobilized on Phosphorus and Calcium Modified MCM-412011

    • Author(s)
      Y. Kuwahara, T. Yamanishi, T. Kamegawa, K. Mori, H. Yamashita
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 115 Pages: 10335-10345

    • Related Report
      2011 Research-status Report
  • [Journal Article] Enhanced Catalytic Activity on Titanosilicate Molecular Sieves Controlled by Cation-π Interactions2011

    • Author(s)
      Y. Kuwahara, K. Nishizawa, T. Kamegawa, K. Mori, H. Yamashita
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Pages: 12462-12465

    • Related Report
      2011 Research-status Report
  • [Journal Article] Photo-Induced Aerobic Oxidation Driven by Phosphorescence Ir(III) Complex Anchored to Mesoporous Silica2011

    • Author(s)
      K. Mori, M. Tottori, K. Watanabe, M. Che, H. Yamashita
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 115 Pages: 21358-21362

    • Related Report
      2011 Research-status Report
  • [Presentation] 表面固定化 Pt 錯体の発光および触媒活性制御2013

    • Author(s)
      森浩亮、渡辺健太郎、山下弘巳
    • Organizer
      第111回触媒討論会
    • Year and Date
      2013-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 層状化合物への Ir および Rh 錯体の階層的固定化と光触媒的水素生成反応2013

    • Author(s)
      森浩亮、青山準也、山下弘巳
    • Organizer
      日本化学会第93回春季年会
    • Year and Date
      2013-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 光応答性金属錯体を基盤とした光触媒の創製2013

    • Author(s)
      森浩亮
    • Organizer
      第12回表面設計化学セミナー
    • Place of Presentation
      近畿大学
    • Year and Date
      2013-02-15
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Visible-light-induced Photocatalysis based on Phosphorescence Metal Complexes Fixed on the Inorganic Matrices2012

    • Author(s)
      K. Mori
    • Organizer
      8^<th> Handai Nanoscience and Nanotechnology International Symposium (HNNIS-8)
    • Year and Date
      2012-12-12
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属錯体を基盤とした有機-無機複合光触媒の創製2012

    • Author(s)
      森浩亮
    • Organizer
      第7回SPring-8 グリーンエネルギー研究会-光がかかわるグリーンエネルギー-
    • Place of Presentation
      大阪府立大
    • Year and Date
      2012-11-15
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノ細孔空間を利用した新しい触媒化学2012

    • Author(s)
      森浩亮
    • Organizer
      平成 24 年度触媒学会ナノ構造触媒研究会講演会「ナノ構造触媒講演会 2012(京都)」
    • Place of Presentation
      京都テルサ
    • Year and Date
      2012-11-09
    • Related Report
      2012 Final Research Report
  • [Presentation] メソポーラスシリカ固定化 Pt 錯体における発光特性と光触媒活性の相関2012

    • Author(s)
      森浩亮、渡邉健太郎、山下弘巳
    • Organizer
      2012 年光化学討論会
    • Year and Date
      2012-09-12
    • Related Report
      2012 Final Research Report
  • [Presentation] ナノ細孔空間を利用した機能集積型触媒の開発2012

    • Author(s)
      森浩亮
    • Organizer
      第23回 N2RC 拠点セミナー「ミクロ・メソ細孔を反応場とする触媒プロセスの新展開」
    • Place of Presentation
      大阪府立大
    • Year and Date
      2012-07-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 多機能集積型触媒による反応プロセスの高効率化2012

    • Author(s)
      森浩亮
    • Organizer
      近畿化学協会、触媒表面部会、平成 24 年度第1回キャタリストクラブ例会
    • Year and Date
      2012-05-14
    • Related Report
      2012 Final Research Report
  • [Presentation] 多機能集積型触媒の開発:金属ナノ粒子から光触媒まで2011

    • Author(s)
      森浩亮
    • Organizer
      触媒学会フレッシュマンゼミナール
    • Place of Presentation
      早稲田大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 触媒化学の基礎と応用:金属触媒から光触媒まで2011

    • Author(s)
      森浩亮
    • Organizer
      平成23年度JPIJSコロキウム「若手の集い」
    • Place of Presentation
      大阪
    • Related Report
      2011 Research-status Report
  • [Presentation] Design of Visible-light Driven Photocatalysts based on Phosphorescence Metal Complexes2011

    • Author(s)
      Kohsuke Mori
    • Organizer
      International Meeting on Novel Catalyst Design and Surface Science (Post Symposium of C&FC2011)
    • Place of Presentation
      兵庫
    • Related Report
      2011 Research-status Report
  • [Presentation] Visible-light-induced Photocatalysis based on Phosphorescence Metal Complexes Fixed on the Inorganic Matrices

    • Author(s)
      Kohsuke Mori
    • Organizer
      8th Handai Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Osaka University
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 金属錯体を基盤とした有機-無機複合光触媒の創製

    • Author(s)
      森浩亮
    • Organizer
      第7回SPring-8グリーンエネルギー研究会-光がかかわるグリーンエネルギー-
    • Place of Presentation
      大阪府立大
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ナノ細孔空間を利用した新しい触媒化学

    • Author(s)
      森浩亮
    • Organizer
      平成24年度触媒学会ナノ構造触媒研究会講演会「ナノ構造触媒講演会2012(京都)」
    • Place of Presentation
      京都テルサ
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ナノ細孔空間を利用した機能集積型触媒の開発

    • Author(s)
      森浩亮
    • Organizer
      第23回N2RC拠点セミナー「ミクロ・メソ細孔を反応場とする触媒プロセスの新展開」
    • Place of Presentation
      大阪府立大
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 多機能集積型触媒による反応プロセスの高効率化

    • Author(s)
      森浩亮
    • Organizer
      近畿化学協会、触媒表面部会、平成24年度第1回キャタリストクラブ例会
    • Place of Presentation
      大阪大学中之島
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] メソポーラスシリカ固定化Pt 錯体における発光特性と光触媒活性の相関

    • Author(s)
      森浩亮、渡邉健太郎、山下弘巳
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 層状化合物へのIrおよびRh錯体の階層的固定化と光触媒的水素生成反応

    • Author(s)
      森浩亮、青山準也、山下弘巳
    • Organizer
      日本化学会第93回春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 表面固定化Pt錯体の発光および触媒活性制御

    • Author(s)
      森浩亮、渡辺健太郎、山下弘巳
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.dma.jim.osaka-u.ac.jp/view?l=ja&u=4266

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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