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A novel technique for gas hydrate study using terahertz spectroscopy

Research Project

Project/Area Number 23760846
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionNagoya University

Principal Investigator

TAKEYA Kei  名古屋大学, 工学研究科, 助教 (70515874)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords自然エネルギーの利用 / テラヘルツ波 / メタンハイドレート / 誘電率 / 非平衡 / テラヘルツ技術 / ガスハイドレート / 光学定数 / エネルギー学 / 非平衡状態
Research Abstract

The optical and dielectric properties of gas hydrates at THz frequencies are expected to provide meaningful information. The present study reports a THz-TDS study of gas hydrates over a wide temperature range (10-250 K) at atmospheric pressure. The real and imaginary dielectric constants ε' and ε'' of SF6 hydrate have been measured in the frequency range 0.3-1.2 THz and in the temperature range 10.3-240 K using THz-TDS with a gas cooling cryostat. The constant ε' increases with frequency, and its mathematical analysis of the increase in ε', shows a local maximum at a few THz. The polarizability ε obtained from ε' shows a linear increase against the square of temperature. The constant ε'', which is mainly influenced by infrared phonon absorption, increases with frequency and temperature over the entire range considered in this study. We discuss the frequency and temperature dependence of ε'' using a mathematical model and obtain parameters to describe the fitted curves of ε''. We check our results using a mathematical model for ice.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (31 results)

All 2013 2012 2011

All Journal Article (10 results) (of which Peer Reviewed: 8 results) Presentation (21 results) (of which Invited: 1 results)

  • [Journal Article] Broadband terahertz wave generation from a MgO:LiNbO_3 ridge waveguide pumped by a 1.5 μm femtosecond fiber laser2013

    • Author(s)
      Shuzhen Fan, Hajime Takeuchi, Toshihiko Ouchi, Kei Takeya, Kodo Kawase
    • Journal Title

      Optics Letters

      Volume: vol.38, issue 10 Pages: 1654-1656

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Wide Spectrum Terahertz-Wave Generation From Nonlinear Waveguides2013

    • Author(s)
      Kei Takeya, Koji Suizu, Hironobu Sai, Toshihiko Ouchi, Kodo Kawase
    • Journal Title

      IEEE Journal of Selected Topics in Quantum Electronics

      Volume: 19巻 1 号 Pages: 8500212-8500212

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of gas hydrates through observation of radical species (in Japanese)2013

    • Author(s)
      Atsushi Tani, Takeshi Sugahara, Motoi Oshima, Kei Takeya, Kazunari Ohgaki
    • Journal Title

      Low Temperature Science

      Volume: 71巻 Pages: 187-192

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of gas hydrates through observation of radical species2013

    • Author(s)
      Atsushi Tani, Takeshi Sugahara, Motoi Oshima, Kei Takeya, Kazunari Ohgaki
    • Journal Title

      Low Temperature Science

      Volume: 71 Pages: 187-192

    • NAID

      120005228449

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] THz Generation Using Cherenkov Phase Matching2012

    • Author(s)
      Kei Takeya, Koji Suizu, Kodo Kawase
    • Journal Title

      Terahertz Science and Technology

      Volume: 5巻 2号 Pages: 78-86

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] ntermolecular Hydrogen Transfer in Isobutane Hydrate2012

    • Author(s)
      Naohiro Kobayashi, Takashi Minami, Atsushi Tani, Mikio Nakagoshi, Takeshi Sugahara, Kei Takeya, Kazunari Ohgaki
    • Journal Title

      Energies

      Volume: 5巻 6号 Pages: 1705-1712

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Hydrogen Transfer in Isobutane Hydrate2012

    • Author(s)
      Naohiro Kobayashi, Takashi Minami, Atsushi Tani, Mikio Nakagoshi, Takeshi Sugahara, Kei Takeya, Kazunari Ohgaki
    • Journal Title

      Energies

      Volume: 5 Issue: 6 Pages: 1705-1712

    • DOI

      10.3390/en5061705

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Terahertz Spectroscopy of Gas Hydrates2011

    • Author(s)
      Kei Takeya, Iwao Kawayama, Hironaru Murakami, Kazunari Ohgaki, Masayoshi Tonouchi
    • Journal Title

      Physics and Chemistry of Ice 2010

      Volume: 1 Pages: 167-171

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dielectric Study on Gas Hydrates Using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      Kei Takeya, Iwao Kawayama, Hironaru Murakami, Masayoshi Tonouchi, Kazunari Ohgaki
    • Journal Title

      Proceedings of the 7th International Conference on Gas Hydrates (ICGH 2011)

      Volume: 1 Pages: 140-140

    • Related Report
      2011 Research-status Report
  • [Journal Article] Dielectric Study on Structure-II Gas Hydrates using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      K. Takeya, K. Kawase, I. Kawayama, H. Murakami, K. Ohgaki, M. Tonouchi
    • Journal Title

      The Joint Conference for International Symposium on Terahertz Nanoscience (TeraNano 2011) & Workshop of International Terahertz Research Network (GDR-I THz 2011)

      Volume: 1 Pages: 208-208

    • Related Report
      2011 Research-status Report
  • [Presentation] テラヘルツ波の高効率発生と応用可能性 (招待講演)2013

    • Author(s)
      川瀬晃道, 竹家啓, 林伸一郎
    • Organizer
      第4回京都、SMI 産学公連携セミナー「テラヘルツ波が開くメゾ空間の計測分析技術」
    • Place of Presentation
      京都大学東京オフィス, 品川
    • Year and Date
      2013-02-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Terahertz time domain spectroscopy of hydrogen bonded materials2013

    • Author(s)
      Kei Takeya, Takashi Fukui, Kodo Kawase,Masayoshi Tonouchi
    • Organizer
      International workshop on Optical Terahertz Science and Technology (OTST 2013)
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Cherenkov phase-matched terahertz wave generation from nonlinear waveguides2013

    • Author(s)
      Shuzhen Fan, Hajime Takeuchi, Kousuke Kajiki, Toshihiko Ouchi, Kei Takeya, Kodo Kawase
    • Organizer
      International workshop on Optical Terahertz Science and Technology (OTST 2013)
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] LiNbO_3リッジ導波路を用いたフェムト秒レーザー励起高出力テラヘルツ波発生2013

    • Author(s)
      竹内創,加治木康介,尾内敏彦,Fan Shuzhen,竹家啓,川瀬晃道
    • Organizer
      2013 年 春季 第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Final Research Report
  • [Presentation] DAST 結晶を用いたフェムト秒レーザ励起による高出力テラヘルツ波発生2013

    • Author(s)
      村手宏輔, 杉山宗, トリパティ サロジ, 竹家啓, 川瀬晃道
    • Organizer
      2013 年 春季 第60回応用物理学会学術講演会2013 年 春季 第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Study of beam polarization rotation affected by parabolic mirrors in THz spectroscopic setup2013

    • Author(s)
      Yu Guan, Shu-zhen Fan, Kei Takeya, Kodo Kawase
    • Organizer
      応用物理学会テラヘルツ電磁波技術研究主催・研究討論会「テラヘルツセンシング及びシミュレーション技術の進展」
    • Place of Presentation
      機械振興会館, 東京
    • Related Report
      2012 Final Research Report
  • [Presentation] Novel high power THz sources and applications (Invited)2013

    • Author(s)
      K. Kawase, S. Hayashi, K. Takeya
    • Organizer
      The 4th THz-Bio Workshop, O-16
    • Place of Presentation
      Seoul National University, Seoul, Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] Nonlinear optical THz-wave sources and applications (Invited)2013

    • Author(s)
      K. Kawase, S. Hayashi, K. Takeya
    • Organizer
      International Conference on Frontiers in Materials Science, Chemistry & Physis, Molecular Materials Meeting (M3)
    • Place of Presentation
      Biopolis, Singapore
    • Related Report
      2012 Final Research Report
  • [Presentation] テラヘル図 3. THF ハイドレートの吸収ピークの温度依存性 ツ波の性質・発生・応用 (招待講演)2012

    • Author(s)
      川瀬晃道, 竹家啓, 林伸一郎
    • Organizer
      超高信頼性無線通信システム研究会特別講演会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-12-03
    • Related Report
      2012 Final Research Report
  • [Presentation] DAST 結晶を用いたフェムト秒レーザー励起による高出力テラヘルツ波発 生2012

    • Author(s)
      杉山宗,内田裕久,竹家啓,川瀬晃道
    • Organizer
      2012 年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区 松山大学文京キャンパス, 松山
    • Related Report
      2012 Final Research Report
  • [Presentation] LiNbO_3 リッジ導波路からのモノパルステラヘルツ波発生2012

    • Author(s)
      竹内創,加治木康介,尾内敏彦, Shuzhen Fan,竹家啓,川瀬晃道
    • Organizer
      2012 年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区 松山大学文京キャンパス, 松山
    • Related Report
      2012 Final Research Report
  • [Presentation] Nonlinear optical THz-wave sources and applications (Invited)2012

    • Author(s)
      K. Kawase, S. Hayashi, K. Takeya
    • Organizer
      SPIE Optics + Photonics, Terahertz Emitters, Receivers, and Applications III (Conference OP218)
    • Place of Presentation
      San Diego Convention Center, San Diego, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Nonlinear optical THz sources and real-life applications2012

    • Author(s)
      K. Kawase, S. Hayashi, K. Takeya
    • Organizer
      The 7th Asia-Pacific Microwave Photonics Conference (APMP 2012)
    • Place of Presentation
      Coop-Inn Kyoto, Kyoto, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Nonlinear optical THz generations and applications (Invited)2012

    • Author(s)
      K. Kawase, K. Takeya, S. Hayashi
    • Organizer
      The 4th International Workshop on Far-Infrared Technologies 2012 (IW-FIRT 2012)
    • Place of Presentation
      Fukui University
    • Related Report
      2012 Final Research Report
  • [Presentation] Nonlinear optical THz sources and real-life applications2012

    • Author(s)
      K. Kawase, S. Hayashi, K. Takeya
    • Organizer
      The 7th Asia-Pacific Microwave Photonics Conference
    • Place of Presentation
      Coop-Inn Kyoto, Kyoto, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Dielectric Study on Structure-II Gas Hydrates using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      K. Takeya, K. Kawase, I. Kawayama, H. Murakami, K. Ohgaki, M. Tonouchi
    • Organizer
      The Joint Conference for International Symposium on Terahertz Nanoscience (TeraNano 2011) & Workshop of International Terahertz Research Network (GDR-I THz 2011)
    • Place of Presentation
      Osaka University Nakanoshima Center, Osaka, Japan
    • Year and Date
      2011-11-24
    • Related Report
      2011 Research-status Report
  • [Presentation] テラヘルツ時間領域分光法によるガスハイドレートの観測2011

    • Author(s)
      竹家啓
    • Organizer
      テラヘルツ秋の学校2011 in 安曇野
    • Place of Presentation
      ホテルアンビエント安曇野、長野
    • Year and Date
      2011-11-07
    • Related Report
      2011 Research-status Report
  • [Presentation] Dielectric Study on Gas Hydrates Using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      Kei Takeya, Iwao Kawayama, Hironaru Murakami, Masayoshi Tonouchi, Kazunari Ohgaki
    • Organizer
      7th International Conference on Gas Hydrates (ICGH 2011)
    • Place of Presentation
      Edinburgh, Scotland, United Kingdom
    • Year and Date
      2011-07-17
    • Related Report
      2011 Research-status Report
  • [Presentation] Dielectric Study on Structure-II Gas Hydrates using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      K. Takeya, K. Kawase, I. Kawayama, H. Murakami, K. Ohgaki, M. Tonouchi
    • Organizer
      The Joint Conference for International Symposium on Terahertz Nanoscience (TeraNano 2011) & Workshop of International Terahertz Research Network (GDR-I THz 2011) 24P-33
    • Place of Presentation
      Osaka University Nakanoshima Center, Osaka, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] テラヘルツ時間領域分光法によるガスハイドレートの観測2011

    • Author(s)
      竹家啓
    • Organizer
      テラヘルツ秋の学校 2011
    • Place of Presentation
      安曇野 ホテルアンビエント安曇野、長野
    • Related Report
      2012 Final Research Report
  • [Presentation] Dielectric Study on Gas Hydrates Using Terahertz Time Domain Spectroscopy2011

    • Author(s)
      Kei Takeya, Iwao Kawayama, Hironaru Murakami, Masayoshi Tonouchi, Kazunari Ohgaki
    • Organizer
      7th International Conference on Gas Hydrates (ICGH 2011) Edinburgh
    • Place of Presentation
      Scotland, United Kingdom
    • Related Report
      2012 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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