• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Functionality-control on Enzyme and Solid by Chiral HelicenethiolDerivatives.

Research Project

Project/Area Number 23790003
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Chemical pharmacy
Research InstitutionTohoku University

Principal Investigator

SHIGENO Masanori  東北大学, 大学院・薬学研究科, 助教 (30571921)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsイオウ / ヘリセン / 二重ラセン / 固体表面 / キラリティー / 熱的ヒステリシス / 二重らせん
Research Abstract

I found that electronic devices possessing gold electrodes modified by chiral helicenedithiol showed Shottoky-diode characteristics after an application of high voltages, and that the polarity of the diode characteristics could be reversed by the polarity of the applied high voltages. I also found that tetramer of optically active sulfonamidohelicene oligomers showed the structural change between a helix dimer and a radom coil during heating and cooling, and that the molecular thermal hysteresis was revealed during those structural changes. Organic gel/liquid two-layer systems were constructed by two-liquid/ultrasonication/diffusion-controlled gelation using a chiral aminohydroxyhelicene derivative

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (33 results)

All 2013 2012 2011 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (25 results) Remarks (1 results)

  • [Journal Article] Molecular Thermal Hysteresis in Helix-Dimer Formation of Sulfo namidohelicene Oligomers in Solution.2013

    • Author(s)
      重野 真徳、串田 陽、山口 雅彦
    • Journal Title

      Chemistry A European Journal

      Volume: VOL.19 Issue: 31 Pages: 10226-10234

    • DOI

      10.1002/chem.201204556

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiple States of Dimeric Aggregates Formed by (Amido-ethynyl)helicene Bidomain Compound and (Amido-ethynyl-amido)helicene Tridomain Compound2012

    • Author(s)
      Wataru Ichinose, Masanori Shigeno, Masahiko Yamaguchi
    • Journal Title

      Chemistry - A European Journal

      Volume: 18 Issue: 40 Pages: 12644-12654

    • DOI

      10.1002/chem.201201929

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Component Fibers/Gels and Vesicles Formed from Hetero-Double-Helices of Pseudoenantiomeric Ethynylhelicene Oligomers with Branched Side Cheins2012

    • Author(s)
      N. Saito, M. Shigeno, M. Yamaguchi
    • Journal Title

      Chem. Eur. J.,

      Volume: 18 Issue: 29 Pages: 8994-9004

    • DOI

      10.1002/chem.201200280

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Organic Gel-Loquid Two-Layar Systems using Diffusion-Controlled Gelation with a Helicene Derivative2012

    • Author(s)
      M. Shigeno, M. Yamaguchi
    • Journal Title

      Chem. Commun.,

      Volume: 48 Issue: 49 Pages: 6139-6141

    • DOI

      10.1039/c2cc31977b

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Side Chain Effect on the Doubke Helix Formation of Ethynylhelicene Oligomers2011

    • Author(s)
      N.Saito, R.Terakawa, M.Shigeno, R.Amemiya, M.Yamaguchi
    • Journal Title

      The Journal of Organic Chenmistry

      Volume: 76 Issue: 12 Pages: 4841-4858

    • DOI

      10.1021/jo200658q

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes2011

    • Author(s)
      Takanori Matsuda, Yoshiyuki Yamaguchi, Masanori Shigeno, Shinya Sato, Masahiro Murakami
    • Journal Title

      Chemical Communications

      Volume: 30 Issue: 30 Pages: 8697-8699

    • DOI

      10.1039/c1cc12457a

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and duplex formation of the reverse amidohelicene tetramer2011

    • Author(s)
      Wataru Ichinose
    • Journal Title

      Tetrahedron

      Volume: 67 Issue: 30 Pages: 5477-5486

    • DOI

      10.1016/j.tet.2011.05.059

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 電極表面修飾単分子層の構造変化に伴う電荷注入障壁の可逆的変調の機構2013

    • Author(s)
      野内亮・重野真徳・山田直・谷本敬明・三苫伸彦・谷垣勝己・山口雅彦
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島
    • Year and Date
      2013-03-26
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 光学活性ヘリセンジチオールを用いた電荷注入障壁の可逆的スイッチング2013

    • Author(s)
      野内亮・重野真徳・山田直・谷垣勝己・山口雅彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-22
    • Related Report
      2012 Final Research Report
  • [Presentation] スルホンアミドヘリセンオリゴマーの二重ラセン/ランダムコイル構造変化における熱的ヒステリシス2013

    • Author(s)
      重野真徳・串田陽・山口雅彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 光学活性オキシカルボニルヘリセンオリゴマーの合成2013

    • Author(s)
      重野真徳、伊藤達也、山口雅彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] アミノメチレンヘリセンオリゴマー二量体会合体によるゲル形成と酸・塩基によるゾル-ゲル転移2013

    • Author(s)
      重野真徳、佐藤雅彦、串田陽、一ノ瀬亘、山口雅彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] 光学活性ヘリセンジチオールを用いた電荷注入障壁の可逆的スイッチ2013

    • Author(s)
      野内亮、重野真徳、山田直、谷垣勝己、山口雅彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] Molecular Thermal Hysteresis in the Helix-dimer/random-coil Structural Change of Sulfonamidohelicene Oligomers in Solution2012

    • Author(s)
      重野真徳・串田陽・山口雅彦
    • Organizer
      IFOC-7
    • Place of Presentation
      東京
    • Year and Date
      2012-11-18
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 光学活性スルホンアミドヘリセンオリゴマーの合成と二量体会合形成2012

    • Author(s)
      重野真徳・串田陽・山口雅彦
    • Organizer
      第102回有機合成シンポジウム2012年[秋]
    • Place of Presentation
      東京
    • Year and Date
      2012-11-08
    • Related Report
      2012 Final Research Report
  • [Presentation] 光学活性アミノ-ヒドロキシメチルヘリセン誘導体を用いる二溶媒系ゲル形成2012

    • Author(s)
      重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 擬鏡像異性体アミノメチルヘリセンオリゴマーのヘテロ会合2012

    • Author(s)
      重野真徳・串田陽・佐藤雅彦・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 擬鏡像エチニルヘリセンオリゴマーによるヘテロ二重ラセン形成と高次集合体形成2012

    • Author(s)
      斎藤望、重野真徳、山口雅彦
    • Organizer
      第101回有機合成シンポジウム2012年【春】
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 光学活性スルホンアミドヘリセンオリゴマーの合成と二量体会合形成2012

    • Author(s)
      重野真徳、串田陽、山口雅彦
    • Organizer
      第102回有機合成シンポジウム2012年【秋】
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] アミド-エチニルジドメインヘリセンオリゴマーを用いる二成分ゲル形成2012

    • Author(s)
      一ノ瀬亘・伊藤潤・重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] アミド-エチニル-アミド-トリドメインヘリセンオリゴマー立体異性体の合成と会合2012

    • Author(s)
      一ノ瀬亘・伊藤潤・重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] ヘリセン担持キラルシリカナノ粒子の合成と不斉認識2012

    • Author(s)
      一ノ瀬亘・宮川雅道・重野真徳・安増建・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] エチニルヘリセンオリゴマー擬鏡像異性体の二成分系ベシクル形成と構造制御2012

    • Author(s)
      齋藤望・重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] ヘリセン部を有する光学活性ヘキサデヒドロトリベンゾ[12]アヌレンの合成と会合2012

    • Author(s)
      齋藤望・寺川亮・重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] アミノメチルヘリセンオリゴマーの合成とラセン二量体形成2012

    • Author(s)
      重野真徳・佐藤雅彦・串田陽・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 擬鏡像異性体アミノメチルヘリセンオリゴマーのヘテロ会合2012

    • Author(s)
      重野真徳・串田陽・佐藤雅彦・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 光学活性アミノ-ヒドロキシメチルヘリセン誘導体を用いる二溶媒系ゲル形成2012

    • Author(s)
      重野真徳・山口雅彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Related Report
      2011 Research-status Report
  • [Presentation] ラセン有機分子の合成・集合体形成と機能2011

    • Author(s)
      重野真徳
    • Organizer
      第26回若手研究者の仙台セミナー
    • Place of Presentation
      東北大学
    • Year and Date
      2011-12-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Enantio-Controlled Reversible Switching of Charge Injection Barriers on Helicenedithiol Modified Electrodes2011

    • Author(s)
      Masanori Shigeno
    • Organizer
      TATESHINA CONFERENCE ON ORGANIC CHEMISTRY 2011
    • Place of Presentation
      蓼科フォーラム
    • Year and Date
      2011-11-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Enantio-Controlled Reversible Switching of Charge Injection Barriers on Helicenethiol Modified Electrodes2011

    • Author(s)
      Masanori Shigeno, Masahiko Yamaguchi
    • Organizer
      TATESHINA CONFERENCE ON ORGANIC CHEMISTRY 2011
    • Place of Presentation
      蓼科フォーラム
    • Related Report
      2011 Research-status Report
  • [Presentation] ラセン有機分子の合成・集合体形成と機能2011

    • Author(s)
      重野真徳
    • Organizer
      第26 回若手研究者の仙台セミナー
    • Place of Presentation
      東北大学
    • Related Report
      2011 Research-status Report
  • [Presentation] アミノメチレンヘリセンオリゴマーの合成,ホモラセン二量

    • Author(s)
      重野真徳、佐藤雅彦、串田陽、山口雅彦
    • Organizer
      第51回日本薬学会東北支部大会
    • Place of Presentation
      青森
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.pharm.tohoku.ac.jp/~sekkei/yakan-home.html

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi