| Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Research Abstract |
Three novel reactions using iron phthalocyanine and molecular oxygen have been developed:
(1) a new method for generation of radicals from hydrazine compounds and addition reactions of resultant radicals to alkenes
(2) synthesis of 1,4-diols from simple alkenes by redox hydration using sodium borohydride
(3) oxidation-reduction esterification using oxygen as an oxidant. In addition, mild oxynitration reactions of alkenes have been found in the courseof these studies.
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