Generation of cyclopentenyl cation using hyperleaving group: λ^<3>-bromanyl group
| Project/Area Number |
23790012
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Chemical pharmacy
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| Research Institution | The University of Tokushima |
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Principal Investigator |
MIYAMOTO Kazunori 徳島大学, 大学院・ヘルスバイオサイエンス研究部, 助教 (40403696)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 臭素 / 超原子価 / ビニルカチオン / 環状 / 脱離能 / ハイパー脱離基 / 5員環 |
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| Research Abstract |
We have succeeded in the generation and characterization of cyclopentenyl cation, which is hitherto unknown last one among the cyclic carbocation families. This methodology utilizes cyclopentenyl-λ^<3>-bromane as the progenitor for cyclopentenyl cation, because of the vastly enhanced nucleofugality of hyperleaving group: λ^<3>-bromanyl group.
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Report
(3 results)
Research Products
(43 results)
