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Hemicryptophane-based efficient sustained-release of fluoride ion and the application to composite resin

Research Project

Project/Area Number 23792302
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Dental engineering/Regenerative dentistry
Research InstitutionOsaka Dental University

Principal Investigator

MAKITA Yoshimasa  大阪歯科大学, 歯学部, 講師 (30454573)

Research Collaborator IKEDA Keisuke  大阪府立大学, 大学院工学研究科, 学生
FUJITA Tomoyuki  大阪府立大学, 大学院工学研究科, 学生
DANNO Tomofumi  大阪府立大学, 大学院工学研究科, 学生
INOUE Masashi  大阪府立大学, 大学院工学研究科, 学生
KATAYAMA Natsuki  大阪府立大学, 大学院工学研究科, 学生
OGAWA Akiya  大阪府立大学, 大学院工学研究科, 教授 (30183031)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsヘミクリプトファン
Research Abstract

Development of restoration material sustained-release fluoride ion enough to prevent caries is desired. We have synthesized hemicryptophanes which are hollow and covalent molecules. In this study, we investigated the sustained-release fluoride ions ability of hemicryptophanes. As a result, the novel hemicryptophanes bearing a soluble ability of various solvents and including three molecules in the cavity were synthesized.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (13 results)

  • [Journal Article] Enhancement of Catalytic Reactivity of Zinc(II) Complex by a Cyclotriveratrylene-capped Structure2012

    • Author(s)
      Y. Makita, K. Ikeda, K. Sugimoto, T. Fujita, T. Danno, K. Bobuatong, M. Ehara, S. Fujiwara, A. Ogawa
    • Journal Title

      J. Organomet. Chem

      Volume: 706 Pages: 26-29

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Face-to-Face Structures Formed by 3D Hydrogen-Bonded Networks of Tris(4-carboxyphenyl)cyclotriguaiacylene2012

    • Author(s)
      Y. Makita, T. Danno, T. Fujita, K. Ikeda, S. Fujiwara, A. Ogawa
    • Journal Title

      J. Chem. Crystallography

      Volume: 42 (10) Pages: 1075-1075

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective Oxidation of Alcohols Catalyzed by a Hemicryptophane-Ruthenium Complex2012

    • Author(s)
      Y. Makita, T. Fujita, T. Danno, M. Inoue, M. Ueshima, S. Fujiwara, A. Ogawa
    • Journal Title

      Supramol. Cat

      Volume: 9

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Face-to-Face Structures Formed by 3D Hydrogen-Bonded Networks of Tris(4-carboxyphenyl)cyclotriguaiacylene2012

    • Author(s)
      Yoshimasa Makita, Tomofumi Danno, Tomoyuki Fujita, Keisuke Ikeda, Shin-ichi Fujiwara, Akiya Ogawa
    • Journal Title

      Journal of Chemical Crystallography

      Volume: 42 Issue: 10 Pages: 1075-1079

    • DOI

      10.1007/s10870-012-0355-0

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective Oxidation of Alcohols Catalyzed by a Hemicryptophane-Ruthenium Complex2012

    • Author(s)
      Yoshimasa Makita, Tomoyuki Fujita, Tomofumi Danno, Masashi Inoue, Michio Ueshima, Shin-ichi Fujiwara, Akiya Ogawa
    • Journal Title

      Supramolecular Catalyst

      Volume: 1 Pages: 9-11

    • DOI

      10.2478/supcat-2012-0002

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhancement of catalytic reactivity of zinc(II) complex by a cyclotriveratrylene-capped structure2012

    • Author(s)
      Yoshimasa Makita, Keisuke Ikeda, Kazuya Sugimoto, Tomoyuki Fujita, Tomofumi Danno, Karan Bobuatong, Masahiro Ehara, Shin-ichi Fujiwara, Akiya Ogawa
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 706-707 Pages: 26-29

    • DOI

      10.1016/j.jorganchem.2012.01.006

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of a cyclotriveratrylene-capped azaphosphatrane2011

    • Author(s)
      Y. Makita, K. Furuyoshi, K. Ikeda, T. Fujita, S. Fujiwara, M. Ehara, A. Ogawa
    • Journal Title

      Tetrahedron Lett

      Volume: 52(47) Pages: 4129-4129

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of a CTV-capped Azaphosphatrane2011

    • Author(s)
      Y.Makita, K.Furuyoshi, K.Ikeda, T.Fujita, S.Fujiwara, M.Ehara, A.Ogawa
    • Journal Title

      Tetrahedron Lett.

      Volume: 52 Issue: 32 Pages: 4129-4131

    • DOI

      10.1016/j.tetlet.2011.05.127

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] ヘミクリプトファン誘導体の合成とゲスト分子包接2014

    • Author(s)
      片山夏輝, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第94回日本化学会春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] ガドリニウム複核錯体の構造と性質2013

    • Author(s)
      井上将史, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学
    • Year and Date
      2013-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] ガドリニウム複核錯体の構造と性質2013

    • Author(s)
      井上将史, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 拡張ヘミクリプトファンの構造と性質2013

    • Author(s)
      團野智史, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 拡張ヘミクリプトファンの合成と性質2012

    • Author(s)
      團野智史, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都テルサ
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] ルテニウムーヘミクリプトファン触媒によるアルコール類の選択的酸化反応2012

    • Author(s)
      藤田智之, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 亜鉛内包ヘミクリプトファンの構造と触媒特性2011

    • Author(s)
      牧田佳真, 池田敬祐, 團野智史, 藤原眞一, 小川昭弥
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2011-09-23
    • Related Report
      2013 Final Research Report
  • [Presentation] ルテニウム内包ヘミクリプトファンの合成とアルコール類の酸化への応用2011

    • Author(s)
      藤田智之, 牧田佳真, 藤原眞一, 小川昭弥
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2011-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] ヘミクリプトファン誘導体の合成とゲスト分子包接

    • Author(s)
      片山夏輝 牧田佳真 藤原眞一 小川昭弥
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ガドリニウム複核錯体の構造と性質

    • Author(s)
      井上将史 牧田佳真 藤原眞一 小川昭弥
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 亜鉛内包ヘミクリプトファ ンの構造と触媒特性

    • Author(s)
      牧田 佳真・池田 敬祐・團野 智史・藤原 眞一・小川 昭弥
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2011 Research-status Report
  • [Presentation] ルテニウム内包ヘミクリプトファンの合成とアルコール類の酸化への応用

    • Author(s)
      藤田 智之・牧田 佳真・藤原 眞一・小川 昭弥
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2011 Research-status Report
  • [Presentation] ルテニウムーヘミクリプトファン触媒によるアルコール類の選択的酸化反応

    • Author(s)
      藤田 智之・牧田 佳真・藤原 眞一・小川 昭弥
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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