Electrophilic Fluorination Using Organodication Species
| Project/Area Number |
23850005
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 有機合成化学 |
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| Research Abstract |
Treatment of the organo-dication species with a naphthalene framework with cesium fluoride afforded a fluorine-bridged cation in good yield. This protocol improved previous methodologies for preparation of similar fluorine cation species. For the future, I would like to try fluorination of organic compounds utilizing the fluorine cation thus formed, for example, via single electron transfer reactions. On the other hand, I succeeded in the preparation of another type of organo-dication species with a dihydroanthracene framework. This dication was found to serve as a strong oxidant, and effectively promoted the oxidative self-coupling of naphthols.
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Report
(3 results)
Research Products
(34 results)
