| Budget Amount *help |
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
Treatment of the organo-dication species with a naphthalene framework with cesium fluoride afforded a fluorine-bridged cation in good yield. This protocol improved previous methodologies for preparation of similar fluorine cation species. For the future, I would like to try fluorination of organic compounds utilizing the fluorine cation thus formed, for example, via single electron transfer reactions. On the other hand, I succeeded in the preparation of another type of organo-dication species with a dihydroanthracene framework. This dication was found to serve as a strong oxidant, and effectively promoted the oxidative self-coupling of naphthols.
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