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Simultaneous detection of metal cations by ion transfer voltammetry in the flow system

Research Project

Project/Area Number 23850012
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionKyushu University

Principal Investigator

ISHIMATSU Ryoichi  九州大学, 大学院・工学研究院, 助教 (90512781)

Project Period (FY) 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsイオン選択性電極 / イオン移動ボルタンメトリー / イオノフォア / 促進イオン移動ボルタンメトリー / フローインジェクション分析
Research Abstract

In this research, polyvinylchloride(PVC) membrane containing plasticizer, supporting salt, an ionophore was used as an ion-selective electrode(ISE), and we demonstrated that K^+, Li^+, Ca6<2+>, Mg6<2+> can be detected by using these electrode through ion transfer voltammetry. It is shown that the facilitated ion transfer processes across the interface between PVC and water(W) are electrochemically quasireversible, and from digital simulation, the rate constant of the facilitated ion transfers are in the range of 0. 01-0. 001 cm s^<-1>. We also confirmed that these ISE can work in a diluted serum solution.

Report

(2 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (7 results)

All 2012 2011 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Electrochemical mechanism of ion-ionophore recognition at plasticized membrane/water interfaces2011

    • Author(s)
      R. Ishimatsu, A. Izadyar, B. Kabagambe, Y. Kim, J. Kim, and S. Amemiya
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 16300-16308

    • Related Report
      2011 Final Research Report
  • [Journal Article] Electrochemical mechanism of ion-ionophore recognition at plasticized membrane/water interfaces2011

    • Author(s)
      R.Ishimatsu, et.al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 113 Issue: 40 Pages: 16300-16308

    • DOI

      10.1021/ja207297q

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] PVCと水との界面を横切る促進イオン移動ボルタンメトリー応答に基づく金属イオンのフローインジェクション分析2012

    • Author(s)
      石松亮一, ら
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松(静岡)
    • Year and Date
      2012-03-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 今任稔彦「PVCと水との界面を横切る促進イオン移動ボルタンメトリー応答に基づく金属イオンのフローインジェクション分析」電気化学会2012

    • Author(s)
      石松亮一、中野幸二
    • Organizer
      第79回大会
    • Place of Presentation
      アクトシティ浜松
    • Related Report
      2011 Final Research Report
  • [Presentation] Facilitated Ion Transfer of Metal Cations across the PVC|Water Interface : Flow Injection Analysis2011

    • Author(s)
      石松亮一, ら
    • Organizer
      第49回フローインジェクション分析講演会
    • Place of Presentation
      愛知工業大学(愛知)
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] Facilitated Ion Transfer of Metal Cations across the PVC| Water Interface : Flow Injection Analysis2011

    • Author(s)
      Ryoichi Ishimatsu, Koji Nakano, Toshihiko Imato
    • Organizer
      第49回フローインジェクション分析講習会
    • Place of Presentation
      愛知工業大学(愛知)
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.cstf.kyushu-u.ac.jp/~imatolab/index-j.html

    • Related Report
      2011 Final Research Report

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Published: 2011-09-05   Modified: 2016-04-21  

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