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Fabrication of Fe-based superconducting wires using effects ofstructural transformation and strain

Research Project

Project/Area Number 23860042
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

MIZUGUCHI Yoshikazu  首都大学東京, 大学院・理工学研究科, 助教 (50609865)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords超伝導 / 超伝導線材 / 新規超伝導物質 / 鉄系超伝導 / 鉄カルコゲナイド
Research Abstract

We have developed novel fabrication process of FeSe superconducting wires using structural transformation of the wire core. The hexagonal FeSe1.2, starting wire core, was packed into the Fe sheath. By annealing at high temperature, the core and Fe sheath reacted and the transformation from hexagonal FeSe1.2 to tetragonal FeSe superconductor. This novel PIT method allowed us to obtain FeSe superconducting wires with high-density core. Furthermore, during this project, we have discovered new BiS2-based layered superconductor Bi4O4S3 and REOBiS2 systems. To date, 11 superconductors related to the BiS2-based superconductors have been discovered all over the world.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • Research Products

    (40 results)

All 2013 2012 2011

All Journal Article (15 results) (of which Peer Reviewed: 14 results) Presentation (23 results) (of which Invited: 4 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] BiS2 - based superconductivity in F-substituted NdOBiS22013

    • Author(s)
      S. Demura
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82 Issue: 3 Pages: 33708-33708

    • DOI

      10.7566/jpsj.82.033708

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of superconductivity in LaO1-xFxBiS2 prepared by high pressure technique2013

    • Author(s)
      K. Deguchi
    • Journal Title

      EPL

      Volume: 101 Issue: 1 Pages: 17004-17004

    • DOI

      10.1209/0295-5075/101/17004

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] uperconductivity in novel BiS2-based layered superconductor LaO1-xFxBiS22012

    • Author(s)
      Y. Mizuguchi,S. Demura, K. Deguchi, Y. Takano, H. Fujihisa, Y. Gotoh, H. Izawa and O. Miura, J
    • Journal Title

      Phys. Soc. Jpn

      Volume: 81 Issue: 11 Pages: 114725-114725

    • DOI

      10.1143/jpsj.81.114725

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pressure Study of BiS_2-Based Superconductors Bi_4O_4S_3 and La(O,F)BiS_22012

    • Author(s)
      H. Kotegawa, H. Tou, 他7名
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Issue: 10 Pages: 103702-103702

    • DOI

      10.1143/jpsj.81.103702

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] BiS2-based layered superconductor Bi4O4S32012

    • Author(s)
      Yoshikazu Mizuguchi,Hiroshi Fujihisa, Yoshito Gotoh, Katsuhiro Suzuki, Hidetomo Usui, Kazuhiko Kuroki, Satoshi Demura, Yoshihiko Takano, Hiroki Izawa, Osuke Miura
    • Journal Title

      Physical Review B

      Volume: 86 Pages: 220510-220510

    • DOI

      10.1016/j.physc.2012.08.003

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of two-step structural phase transition in Fe1+dTe detected by low-temperature x-ray diffraction2012

    • Author(s)
      Y.Mizuguchi
    • Journal Title

      Solid State Commun.

      Volume: 152 Issue: 12 Pages: 1047-1051

    • DOI

      10.1016/j.ssc.2012.03.022

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of tetragonal phase in the FeSe wire fabricated by a novel chemical-transformation PIT process2012

    • Author(s)
      Hiroki Izawa, Yoshikazu Mizuguchi,Toshinori Ozaki, Yoshihiko Takano, Osuke Miura
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Issue: 1R Pages: 10101-10101

    • DOI

      10.1143/jjap.51.010101

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inducement of superconductivity in Fe(Te,S) by sulfuric acid treatment2012

    • Author(s)
      M. Nagao
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 81 Issue: 8 Pages: 85005-85005

    • DOI

      10.1143/jpsj.81.085005

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bulk superconductivity in Bi4O4S3 revealed by specific heat measurement2012

    • Author(s)
      H. Takatu
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 81 Issue: 12 Pages: 125002-125002

    • DOI

      10.1143/jpsj.81.125002

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physics and chemistry review of layered chalcogenide superconductors2012

    • Author(s)
      K Deguchi
    • Journal Title

      Sci. Technol. Adv. Mater.

      Volume: 13 Issue: 5 Pages: 54303-54303

    • DOI

      10.1088/1468-6996/13/5/054303

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Two-step phase transition in Fe_<1+d>Te detected by low-temperature x-ray diffraction2012

    • Author(s)
      Yoshikazu Mizuguchi
    • Journal Title

      Solid State Communication (accepted for publication)

      Volume: (in printing)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and magnetic properties of Fe1+dTe single crystals2012

    • Author(s)
      Yoshikazu Mizuguchi
    • Journal Title

      Physics Proceedia (accepted for publication)

      Volume: (in printing)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transport properties of the singleand 3-core Fe-Se wires fabricated by a novel chemical-transformation PIT process2011

    • Author(s)
      Y. Mizuguchi,H. Izawa, T. Ozaki, Y. Takano and O. Miura
    • Journal Title

      Supercond. Sci. Technol

      Volume: 24 Issue: 12 Pages: 125003-125003

    • DOI

      10.1088/0953-2048/24/12/125003

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Thin Crystals of FeTe1-xSx Using the Scotch-Tape Method2011

    • Author(s)
      Y. Mizuguchi, T. Watanabe, H. Okazaki, T. Yamaguchi, Y. Takano and O. Miura
    • Journal Title

      pn. J. Appl. Phys

      Volume: 50 Issue: 8R Pages: 88003-88003

    • DOI

      10.1143/jjap.50.088003

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single crystal growth and structural characterization of FeTe1-xSx2011

    • Author(s)
      Yoshikazu Mizuguchi
    • Journal Title

      IEEE, Trans.Appl.Supercond.

      Volume: 21 Issue: 3 Pages: 2866-2869

    • DOI

      10.1109/tasc.2010.2087307

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Superconductivity in the novel BiS2-based layered materials2013

    • Author(s)
      Y. Mizuguchi
    • Organizer
      invited talk in session ISRFM
    • Place of Presentation
      Miami, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconductivity in the novel BiS2-based layered materials2013

    • Author(s)
      Y. Mizuguchi
    • Organizer
      study of matter at extreme conditions
    • Place of Presentation
      Miami, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] BiS2層を有する新しい層状超伝導物質の発見とその物性2013

    • Author(s)
      水口佳一
    • Organizer
      SIS2013
    • Place of Presentation
      長野
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Fe1+dTe系における反強磁性転移と構造相転移2012

    • Author(s)
      水口佳一
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 構造相変態法によるFeSe超伝導テープの作製と特性評価2012

    • Author(s)
      井澤宏輝
    • Organizer
      応用物理学会
    • Place of Presentation
      早稲田大
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 鉄カルコゲナイド超伝導体の応用へのアプローチ2012

    • Author(s)
      水口佳一
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学ユビキタス元素戦略」第9回領域会議
    • Place of Presentation
      物質・材料研究機構
    • Year and Date
      2012-01-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Physical properties of layered chalcogenide superconductors and related magnetic materials2012

    • Author(s)
      Y. Mizuguchi
    • Organizer
      B-4-I24-004,IUMRS-2012
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of FeSe wire by a novel chemical-transformation PIT process2012

    • Author(s)
      H. Izawa, Y. Mizuguchi,T. Ozaki, Y.Takano, O. Miura
    • Organizer
      B-4-O26-016, IUMRS-2012
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] CRITICAL CURRENT DENSITIES OF FeTe1-xSex WIRES FABRICATED BY MODIFIED PIT PROCESS2012

    • Author(s)
      H. Izawa, Y. Mizuguchi,T. Ozaki, Y.Takano, O. Miura
    • Organizer
      WTP-55, ISS2012
    • Place of Presentation
      Funabori, Tokyo
    • Related Report
      2012 Final Research Report
  • [Presentation] NOVEL BiS2-BASED LAYERED SUPERCONDUCTING FAMILY2012

    • Author(s)
      Yoshikazu Mizuguchi
    • Organizer
      PC-9, ISS2012
    • Place of Presentation
      Funabori, Tokyo
    • Related Report
      2012 Final Research Report
  • [Presentation] 鉄カルコゲナイド超伝導体の応用へのアプローチ2012

    • Author(s)
      水口佳一
    • Organizer
      特定領域研究「配列ナノ空間を利用した新物質科学 ユビキタス元素戦略」第9回領域会議
    • Related Report
      2012 Final Research Report
  • [Presentation] Fe1+dTe系における反強磁性転移と構造相転移2012

    • Author(s)
      水口佳一,濱田健太朗,三浦大介,高津浩,後藤和基,門脇広明,中井祐介,真庭豊,町田理,坂田英明
    • Organizer
      日本物理学会第67回年次大会,25a-YA-1
    • Place of Presentation
      関西学院大
    • Related Report
      2012 Final Research Report
  • [Presentation] Physical properties of FeTe-based bulk and thin crystals2012

    • Author(s)
      Y. Mizuguchi
    • Organizer
      Materials and Mechanisms of superconductivity
    • Place of Presentation
      Washington DC, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Physical Properties of Layered Chalcogenide Superconductors and Related Magnetic Materials2012

    • Author(s)
      Y. Mizuguchi
    • Organizer
      IUMRS 2012
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Novel BiS2-based layered superconducting family2012

    • Author(s)
      Y. Mizuguchi
    • Organizer
      ISS2012
    • Place of Presentation
      Funabori, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] FABRICATION AND PHYSICAL PROPERTIES OF FeTe-BASED THIN CRYSTALS USING THE SCOTCH-TAPE METHOD2011

    • Author(s)
      Yoshikazu Mizuguchi
    • Organizer
      ISS-2011
    • Place of Presentation
      Funabori, Japan
    • Year and Date
      2011-10-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Superconducting properties and wire fabrication of 11- and 122-type Fe chalcogenides2011

    • Author(s)
      Yoshikazu Mizuguchi
    • Organizer
      European Conference on Applied Superconductivity
    • Place of Presentation
      Hague, Netherland
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 構造相変態によるFeSe超伝導線材の新しい作製プロセス2011

    • Author(s)
      井澤宏樹
    • Organizer
      応用物理学会第72回学術講演会
    • Place of Presentation
      山形大
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] スコッチテープ法によるFeTe系単結晶薄膜の作成と物性評価2011

    • Author(s)
      水口佳一
    • Organizer
      応用物理学会第72回学術講演会
    • Place of Presentation
      山形大
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] FABRICATION AND PHYSICAL PROPERTIES OF FeTe-BASED THIN CRYSTALS USING THE SCOTCH-TAPE METHOD2011

    • Author(s)
      Y. Mizuguchi,K. Hamada, H. Okazaki,T. Yamaguchi, Y. Takano, O. Miura
    • Organizer
      24th International symposium on superconductivity
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Superconducting properties and wire fabrication of 11- and 122-type Fe chalcogenides2011

    • Author(s)
      Y. Mizuguchi, T. Ozaki, S. Tsuda, T.Yamaguchi, Y. Takano, O. Miura,H.Takeya
    • Organizer
      EUCAS-2011
    • Place of Presentation
      Hague, Netherland
    • Related Report
      2012 Final Research Report
  • [Presentation] 構造相変態によるFeSe超伝導線材の新しい作製プロセス2011

    • Author(s)
      井澤宏輝, 水口佳一,高野義彦, 尾崎壽紀, 三浦大介
    • Organizer
      秋季第72回応用物理学会学術講演会 31a-ZT-3
    • Place of Presentation
      山形大
    • Related Report
      2012 Final Research Report
  • [Presentation] スコッチテープ法によるFeTe系単結晶薄膜の作成と物性評価2011

    • Author(s)
      水口佳一,濱田健太朗, 岡崎宏之, 山口尚秀,高野義彦, 三浦大介
    • Organizer
      秋季第72回応用物理学会学術講演会 31a-ZT-3
    • Place of Presentation
      山形大
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] BiS2系超伝導体2012

    • Inventor(s)
      水口佳一/三浦大介/高野義彦/出村郷志/後藤義人/藤久裕司
    • Industrial Property Rights Holder
      首都大学東京/物質・材料研究機構/産業総合技術研究所
    • Industrial Property Number
      2012-156182
    • Filing Date
      2012-07-12
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] BiS2系超伝導体2012

    • Inventor(s)
      水口佳一/三浦大介/藤久裕司/後藤義人/高野義彦/出村郷志
    • Industrial Property Rights Holder
      水口佳一/三浦大介/藤久裕司/後藤義人/高野義彦/出村郷志
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-156182
    • Filing Date
      2012-07-12
    • Related Report
      2012 Annual Research Report

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Published: 2011-09-05   Modified: 2019-07-29  

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