| Co-Investigator(Renkei-kenkyūsha) |
SATO Sota 東京大学, 理学系研究科, 准教授 (40401129)
MURASE Takashi 山形大学, 工学部, 准教授 (70508184)
INOKUMA Yasuhide 北海道大学, 工学研究院, 准教授 (80555566)
SAWADA Tomohisa 東京大学, 工学系研究科, 講師 (70625467)
FUJITA Daishi 東京大学, 工学系研究科, 特任研究員 (20713564)
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| Budget Amount *help |
¥386,750,000 (Direct Cost: ¥297,500,000、Indirect Cost: ¥89,250,000)
Fiscal Year 2016: ¥85,800,000 (Direct Cost: ¥66,000,000、Indirect Cost: ¥19,800,000)
Fiscal Year 2015: ¥81,900,000 (Direct Cost: ¥63,000,000、Indirect Cost: ¥18,900,000)
Fiscal Year 2014: ¥85,150,000 (Direct Cost: ¥65,500,000、Indirect Cost: ¥19,650,000)
Fiscal Year 2013: ¥77,350,000 (Direct Cost: ¥59,500,000、Indirect Cost: ¥17,850,000)
Fiscal Year 2012: ¥56,550,000 (Direct Cost: ¥43,500,000、Indirect Cost: ¥13,050,000)
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| Outline of Final Research Achievements |
This research project was intended to the integration of solution-state chemistry and solid-state chemistry through the nano-cavities of self-assembled hollow complexes. New chemistry was established by the successful integration of those two fields, which have been developed independently so far. New mechanistic insights on molecular recognition events or reactions in solution state were visualized by the single crystal X-ray analyses of the guest inclusion complexes. Furthermore, topochemical control in thermal and photochemical reactions was achieved in solution when substrates are well reorganized in the cavity before the events.
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