Development of Novel Photo- and Electro-functional Polymers by SOMO Design of Organic Radicals

• Project/Area Number: 24225003
• Research Category: Grant-in-Aid for Scientific Research (S)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: Waseda University
• Principal Investigator: Nishide Hiroyuki 早稲田大学, 理工学術院, 教授 (90120930)
• Co-Investigator(Kenkyū-buntansha): 小柳津 研一 早稲田大学, 理工学術院, 教授 (90277822) ; 錦谷 禎範 早稲田大学, 理工学術院, 教授 (50708625)
• Co-Investigator(Renkei-kenkyūsha): NISHIKITANI Yoshinori 早稲田大学, 理工学術院, 教授 (50708625)
• Project Period (FY): 2012-05-31 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥195,390,000 (Direct Cost: ¥150,300,000、Indirect Cost: ¥45,090,000); Fiscal Year 2016: ¥24,570,000 (Direct Cost: ¥18,900,000、Indirect Cost: ¥5,670,000); Fiscal Year 2015: ¥26,650,000 (Direct Cost: ¥20,500,000、Indirect Cost: ¥6,150,000); Fiscal Year 2014: ¥32,890,000 (Direct Cost: ¥25,300,000、Indirect Cost: ¥7,590,000); Fiscal Year 2013: ¥55,770,000 (Direct Cost: ¥42,900,000、Indirect Cost: ¥12,870,000); Fiscal Year 2012: ¥55,510,000 (Direct Cost: ¥42,700,000、Indirect Cost: ¥12,810,000)
• Keywords: 高分子合成 / 有機ラジカル / 機能性高分子 / 蓄電 / 光電変換 / 高分子化学 / 電荷輸送 / 電子交換 / 有機エレクトロニクス

Outline of Final Research Achievements

We have been focusing on reversible and rapid electron-transfer processes of organic robust radicals and developing “radical polymers” as a new class of functional polymers. The present research described the chemistry of materials for charge-transport and -storage exploiting redox gradient-driven electron self-exchange reactions. The research was broadened by developing highly efficient transporting systems and precisely designing transport properties. The electroactive polymers were explored by pursuing new characteristics along expanding the radical species, besides a SOMO (singly-occupied MO)-π conjugated system. The research provided a breakthrough for organic photovoltaic and rechargeable devices.

Assessment Rating

Verification Result (Rating)

A+

Research Products

• [Journal Article] Quantifying TEMPO Redox Polymer Charge Transport toward the Organic Radical Battery (2017)
  • Author(s): C. Karlsson, T. Suga, H. Nishide
  • Journal Title: ACS Applied Materials and Interfaces Volume: 9 Issue: 12 Pages: 10692-10698
  • DOI: 10.1021/acsami.7b00403
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of Dimethyl-Substituted Polyviologen and Control of Charge Transport in Electrodes for High-Resolution Electrochromic Displays (2017)
  • Author(s): K. Sato, R. Mizukami, T. Mizuma, H. Nishide, K. Oyaizu
  • Journal Title: Polymers Volume: 9 Issue: 3 Pages: 86-86
  • DOI: 10.3390/polym9030086
  • Peer Reviewed / Open Access
• [Journal Article] Charge-Discharge with Rocking-Chair-Type Li+ Migration Characteristics in a Zwitterionic Radical Copolymer Composed of TEMPO and Trifluoromethanesulfonylimide with Carbonate Electrolytes for a High-Rate Li-Ion Battery (2017)
  • Author(s): H. Tokue, T. Murata, H. Agatsuma, H. Nishide, K. Oyaizu
  • Journal Title: Macromolecules Volume: 50 Issue: 5 Pages: 1950-1958
  • DOI: 10.1021/acs.macromol.6b02404
  • Peer Reviewed / Open Access
• [Journal Article] Low‐Cost, Organic Light‐Emitting Electrochemical Cells with Mass‐Producible Nanoimprinted Substrates Made Using Roll‐to‐Roll Methods (2017)
  • Author(s): K. Sato, S. Uchida, S. Toriyama, S. Nishimura, K. Oyaizu, H. Nishide, Y. Nishikitani
  • Journal Title: Advanced Materials Technologies Volume: - Issue: 5 Pages: 1-8
  • DOI: 10.1002/admt.201600293
  • Peer Reviewed / Open Access
• [Journal Article] Redox Mediation through TEMPO-Substituted Polymer with Nanogap Electrodes for Electrochemical Amplification (2017)
  • Author(s): H. Tokue, K. Kakitani, H. Nishide, K. Oyaizu
  • Journal Title: Chemistry Letters Volume: 46 Issue: 5 Pages: 647-650
  • DOI: 10.1246/cl.170055
  • NAID: 130005655617
  • Peer Reviewed / Open Access
• [Journal Article] A Hydrogen Storable Quinaldine Polymer: Its Ni‐Electrodeposition‐assisted Hydrogenation and Subsequent Hydrogen Evolution (2017)
  • Author(s): R. Kato, T. Oya, Y. Shimazaki, K. Oyaizu, H. Nishide
  • Journal Title: Polymer International Volume: 66 Issue: 5 Pages: 647-652
  • DOI: 10.1002/pi.5327
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Electrochemical Current Rectification with Cross Reaction at a TEMPO/viologen-substituted Polymer thin-layer Heterojunction (2016)
  • Author(s): H Tokue, K Kakitani, H Nishide, K Oyaizu
  • Journal Title: RSC Advances Volume: 6 Issue: 101 Pages: 99195-99201
  • DOI: 10.1039/c6ra23124a
  • Peer Reviewed / Open Access
• [Journal Article] A Ketone/alcohol Polymer for Cycle of Electrolytic Hydrogen-fixing with Water and Releasing under Mild Conditions (2016)
  • Author(s): R. Kato, K. Yoshimasa, T. Egashira, T. Oya, K. Oyaizu, H. Nishide
  • Journal Title: Nature Communications Volume: 7 Issue: 1 Pages: 1-7
  • DOI: 10.1038/ncomms13032
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Effect of π-Conjugated Polyelectrolyte on Performance of White Polymer Light-Emitting Diodes Based on Excitons and Exciplexes Having Long Intermolecular Distances (2016)
  • Author(s): Y. Nishikitani, N. Inokuchi, H. Nishide, S. Uchida, T. Shibanuma, S. Nishimura
  • Journal Title: J. Phys. Chem. C Volume: 120 Issue: 26 Pages: 13976-13986
  • DOI: 10.1021/acs.jpcc.6b04413
  • Peer Reviewed / Open Access
• [Journal Article] Metallopolyyne Polymers with Ferrocenyl Pendant Ligands as Cathode-active Materials for Organic Battery Application (2016)
  • Author(s): Z. Meng, K. Sato, T. Sukegawa, K. Oyaizu, CL. Ho, J. Xiang, YH. Feng, YH. Lo, H. Nishide, WY. Wong
  • Journal Title: J. Org. Chem. Volume: 812 Pages: 51-55
  • DOI: 10.1016/j.jorganchem.2015.11.019
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] A Quasi-Solid State DSSC with 10.1% Efficiency through Molecular Design of the Charge-Separation and-Transport (2016)
  • Author(s): M. Suzuka, N. Hayashi, T. Sekiguchi, K. Sumioka, M. Takata, N. Hayo, H. Ikeda, K. Oyaizu, H. Nishide
  • Journal Title: Scientific Reporys Volume: 6 Issue: 1 Pages: 28022-28022
  • DOI: 10.1038/srep28022
  • Peer Reviewed / Open Access
• [Journal Article] Poly (norbornyl-NDIs) as a Potential Cathode-active Material in Rechargeable Charge Storage Devices (2016)
  • Author(s): Y. Sasada, SJ. Langford, K. Oyaizu, H. Nishide
  • Journal Title: RSC Adv. Volume: 6 Issue: 49 Pages: 42911-42916
  • DOI: 10.1039/c6ra06103f
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Enhanced Catalytic Activity of Oxovanadium Complexes in Oxidative Polymerization of Diphenyl Disulfide (2016)
  • Author(s): F. Aida, Y. Takatori, D. Kiyokawa, K. Nagamatsu, K. Oyaizu, H. Nishide
  • Journal Title: Polym. Chem. Volume: 7 Issue: 11 Pages: 2087-2091
  • DOI: 10.1039/c5py01980j
  • Peer Reviewed / Open Access
• [Journal Article] Synthesis and Charge-Discharge Properties of Organometallic Copolymers of Ferrocene and Triphenylamine as Cathode Active Materials for Organic-Battery Applications (2016)
  • Author(s): J. Xiang, K. Sato, H. Tokue, K. Oyaizu, CL. Ho, H. Nishide, WY. Wong, MD. Wei
  • Journal Title: Euro. J. Inorg, Chem. Volume: - Issue: 7 Pages: 1030-1035
  • DOI: 10.1002/ejic.201501169
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Dynamic Switching of Ionic Conductivity by Cooperative Interaction of Polyviologen and Liquid Crystals for Efficient Charge Storage (2016)
  • Author(s): K. Sato, T. Yamasaki, T. Mizuma, K. Oyaizu, H. Nishide
  • Journal Title: J. Mater. Chem. A Volume: 4 Issue: 9 Pages: 3249-3252
  • DOI: 10.1039/c6ta00320f
  • Peer Reviewed / Open Access
• [Journal Article] "Click" Incorporation of Radical/Ionic Sites into a Reactive Block Copolymer: A Facile and On-Demand Domain Functionalization Approach toward Organic Resistive Memory (2016)
  • Author(s): T. Suga, K. Aoki, T. Yashiro, H. Nishide
  • Journal Title: Macromol. Rapid Commun. Volume: 37 Issue: 1 Pages: 53-59
  • DOI: 10.1002/marc.201500492
  • Peer Reviewed / Open Access
• [Journal Article] Oxygen-enriched Electrolytes Based on Perfluorochemicals for High-capacity Lithium-oxygen Batteries (2015)
  • Author(s): Y. Nishikami, T. Konishi, R. Omoda, Y. Aihara, K. Oyaizu, H. Nishide
  • Journal Title: J. Mater. Chem. A Volume: 3 Issue: 20 Pages: 10845-10850
  • DOI: 10.1039/c5ta02219c
  • Peer Reviewed / Open Access
• [Journal Article] High-Density and Robust Charge Storage with Poly(anthraquinone-substituted norbornene) for Organic Electrode-Active Materials in Polymer–Air Secondary Batteries (2015)
  • Author(s): T. Kawai, K. Oyaizu, H. Nishide
  • Journal Title: Macromolecules Volume: 48 Issue: 8 Pages: 2429-2434
  • DOI: 10.1021/ma502396r
  • Peer Reviewed / Open Access
• [Journal Article] Synthesis of Poly(TEMPO-Substituted Glycidyl ether)by Utilizing t-BuOK/18-Crown-6 for an OrganicCathode-Active Material (2015)
  • Author(s): K. Sato, T. Sukegawa, K. Oyaizu, H. Nishide
  • Journal Title: Macromol. Symp. Volume: 351 Issue: 1 Pages: 90-96
  • DOI: 10.1002/masy.201300224
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Facile Grafting-onto-preparation of Block Copolymers of TEMPO and Glycidyl Methacrylates on an Oxide Substrate as an Electrode-active Layer (2015)
  • Author(s): K. Takahashi, K. Korolev, K. Tsuji, K. Oyaizu, H. Nishide, E. Bryuzgina, A. Navrotskiy, I. Novakova
  • Journal Title: Polymer Volume: 68 Pages: 310-314
  • DOI: 10.1016/j.polymer.2015.02.043
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Polyviologen as the Charge-storage Electrode of an Aqueous Electrolyte- and Organic-based Dye-sensitized Solar Cell (2015)
  • Author(s): M. Suzuka, S. Hara, T. Sekiguchi, K. Oyaizu, H. Nishide
  • Journal Title: Polymer Volume: 68 Pages: 353-357
  • DOI: 10.1016/j.polymer.2015.02.044
  • Peer Reviewed / Open Access
• [Journal Article] Electrochemical Formation of a Polyviologen–ZnO Composite with an Efficient Charging Capability (2015)
  • Author(s): H. Maruo, K. Oyaizu, H. Nishide
  • Journal Title: Chemistry Letters Volume: 44 Issue: 3 Pages: 393-395
  • DOI: 10.1246/cl.141125
  • NAID: 130004868393
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Open Access
• [Journal Article] White Polymer Light-Emitting Electrochemical Cells Fabricated Using Energy Donor and Acceptor Fluorescent pi-Conjugated Polymers Based on Concepts of Band-Structure Engineering (2015)
  • Author(s): Y. Nishikitani, D. Takizawa, H. Nishide, S. Uchida, S. Nishimura
  • Journal Title: J. Phys. Chem.C Volume: 119 Issue: 52 Pages: 28701-28710
  • DOI: 10.1021/acs.jpcc.5b08547
  • Peer Reviewed / Open Access
• [Journal Article] Phenothiazine-functionalized redox polymers for a new cathode-active material (2015)
  • Author(s): A. A. Golriz, T. Suga, H. Nishide, R. Berger, J. S. Gutmann
  • Journal Title: RSC Advances Volume: 5 Issue: 29 Pages: 22947-22950
  • DOI: 10.1039/c4ra17107a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Efficient charge transport of a radical polyether/SWCNT composite electrode for an organic radical battery with high charge-storage density (2015)
  • Author(s): T. Sukegawa, K. Sato, K. Oyaizu, H. Nishide
  • Journal Title: RSC Advances Volume: 5 Issue: 20 Pages: 15448-15452
  • DOI: 10.1039/c4ra15949g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Kinetic Control of Electron Transfer at Doped Zinc Oxide/Redox-active Molecule Interface for Photocurrent Rectification (2015)
  • Author(s): M. Suzuka, S, Hara, T. Sekiguchi, K. Oyaizu, H. Nishide
  • Journal Title: Chemistry Letters Volume: 44 Issue: 1 Pages: 41-43
  • DOI: 10.1246/cl.140872
  • NAID: 130004699196
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Facile charge transport and storage by a TEMPO-populated redox mediating polymer integrated with polyaniline as electrical conducting path (2014)
  • Author(s): K. Oyaizu, H. Tatsuhira, H. Nishide
  • Journal Title: Polym. J. Volume: 47 Issue: 2 Pages: 1-8
  • DOI: 10.1038/pj.2014.124
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Expanding the dimensionality of polymers populated with organic robust radicals toward flow cell application: Synthesis of TEMPO-crowded bottlebrush polymers using anionic polymerization and ROMP (2014)
  • Author(s): T. Sukegawa, I. Masuko, K. Oyaizu, H. Nishide
  • Journal Title: Macromolecules Volume: 47 Issue: 24 Pages: 8611-8617
  • DOI: 10.1021/ma501632t
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis of pendant radical- and ion-containing block copolymers via ring-opening metathesis polymerization for organic resistive memory (2014)
  • Author(s): T. Suga, M. Sakata, K. Aoki, H. Nishide
  • Journal Title: ACS Macro. Lett. Volume: 3 Issue: 8 Pages: 703-707
  • DOI: 10.1021/mz500273z
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] In-suti polymerization of thiophene derivatives using a gas phase oxidant to form a hole transporting layer in dye-sensitized solar cell (2014)
  • Author(s): Y. Sasada, F. Kato, K. Oyaizu, H. Nishide
  • Journal Title: J. Photopolym. Sci. Tech. Volume: 27 Pages: 347-350
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ionic Liquid-inspired Redox Shuttles: Properties of a Ferrocenylimidazolium Salt as an Efficient Mediator for Dye-sensitized Solar Cells (2014)
  • Author(s): K. Oyaizu H. Ikeda, N. Hayo, F. Kato, H. Nishide
  • Journal Title: Chemistry Letters Volume: 43 Issue: 7 Pages: 1134-1136
  • DOI: 10.1246/cl.140276
  • NAID: 130004868268
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Porphyrin network polymers prepared via a Click reaction and facilitated oxygen-permeation through their membranes (2014)
  • Author(s): N. Chikushi, E. Ohara, A. Hisama, H. Nishide
  • Journal Title: Macromol. Rapid. Commun. Volume: 35 Issue: 10 Pages: 976-980
  • DOI: 10.1002/marc.201400038
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Anionic polymerization of 4-methacryloyloxy-TEMPO using an MMA-capped initiator (2014)
  • Author(s): T. Sukegawa, H. Omata, I. Masuko, K. Oyaizu, H. Nishide
  • Journal Title: ACS Macro. Lett. Volume: 3 Issue: 3 Pages: 240-243
  • DOI: 10.1021/mz400644y
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Interaction of tris(2-aminoethyl)amine-based ureas and thiourea with superoxide anion and peroxide dianion through multiple hydrogen-bonding (2014)
  • Author(s): N. Chikushi, Y. Nishikami, H. Nishide
  • Journal Title: Chem. Lett. Volume: 43 Issue: 6 Pages: 760-762
  • DOI: 10.1246/cl.140038
  • NAID: 130004868155
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] TEMPO/viologen electrochemical heterojunction for diffusion controlled redox mediation: A highly rectifying bilayer-sandwiched device based on cross reaction at interface between dissimilar redox polymers (2014)
  • Author(s): H. Tokue, K. Oyaizu, T. Sukegawa, H. Nishide
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 6 Issue: 6 Pages: 4043-4049
  • DOI: 10.1021/am405527y
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Redox-active hydroxy-TEMPO radical immobilized in Nafion layer for aqueous electrolyte-based and dye-sensitized solar cell (2014)
  • Author(s): R. Kato, F. Kato, K. Oyaizu, H. Nishide
  • Journal Title: Chem. Lett. Volume: 43 Issue: 4 Pages: 480-482
  • DOI: 10.1246/cl.131120
  • NAID: 130004868074
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Self-doping Inspired Zwitterionic Pendant Design of Radical Polymers toward a Rocking-chair-type Organic Cathode-active Material (2013)
  • Author(s): I. -S. Chae, M. Koyano, K. Oyaizu, H. Nishide
  • Journal Title: J. Mater. Chem. A Volume: 1 Issue: 4 Pages: 1326-1333
  • DOI: 10.1039/c2ta00785a
  • Peer Reviewed
• [Journal Article] Polyviologen Hydrogel with High-rate Capability for Anodes toward an Aqueous Electrolyte-type and Organic-based Rechargeable Device (2013)
  • Author(s): N. Sano, W. Tomita, S. Hara, C. -H. Min, J. -S. Lee, K. Oyaizu, H. Nishide
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 5 Issue: 4 Pages: 1355-1361
  • DOI: 10.1021/am302647w
  • Peer Reviewed
• [Journal Article] Robust and Efficient Charge Storage by Uniform Grafting of TEMPO Radical Polymer around Multi-walled Carbon Nanotubes (2013)
  • Author(s): W. Choi, S. Endo, K. Oyaizu, H. Nishide, K. E. Geckeler
  • Journal Title: J. Mater. Chem. A Volume: 1 Issue: 9 Pages: 2999-3003
  • DOI: 10.1039/c3ta01588b
  • Peer Reviewed
• [Journal Article] Synthesis of Pendant Nitronyl Nitroxide Radical-containing Poly(norbornene)s as Ambipolar Electrode-active Materials (2013)
  • Author(s): T. Sukegawa, A. Kai, K. Oyaizu, H. Nishide
  • Journal Title: Macromolecules Volume: 46 Issue: 4 Pages: 1361-1367
  • DOI: 10.1021/ma302278h
  • Peer Reviewed
• [Journal Article] Redox Equilibrium of a Zwitterionic Radical Polymer in a Non-aqueous Electrolyte for Novel Li+ Host Material in a Li-ion Battery (2013)
  • Author(s): I. S. Chae, M. Koyano, T. Sukegawa, K. Oyaizu, H. Nishide
  • Journal Title: J. Mater. Chem. A Volume: 1 Issue: 34 Pages: 9608-9611
  • DOI: 10.1039/c3ta12076g
  • Peer Reviewed
• [Journal Article] Enhanced Bimolecular Exchange Reaction through Programmed Coordination of a Five-coordinate Oxovanadium Complex for Efficient Redox Mediation in Dye-sensitized Solar Cells (2013)
  • Author(s): K. Oyaizu, N. Hayo, Y. Sasada, F. Kato, H. Nishide
  • Journal Title: Dalton Trans. Volume: 42 Issue: 45 Pages: 16090-16095
  • DOI: 10.1039/c3dt51698a
  • Peer Reviewed
• [Journal Article] 空気電池: 有機負極を目指したポリマー膜の設計 (2013)
  • Author(s): 小柳津研一, 西出宏之
  • Journal Title: 膜 Volume: 38 Pages: 131-136
  • NAID: 10031177818
• [Journal Article] TEMPO-substituted Polyacrylamide for an Aqueous Electrolyte-typed and Organic-based Rechargeable Device (2012)
  • Author(s): N. Chikushi, H. Yamada, K. Oyaizu, H. Nishide
  • Journal Title: Sci. Chin. Chem. Volume: 55 Issue: 5 Pages: 822-829
  • DOI: 10.1007/s11426-012-4556-3
  • Peer Reviewed
• [Journal Article] Macromolecular Complexes Leading to High Performance Energy Devices (2012)
  • Author(s): K. Oyaizu, H. Nishide
  • Journal Title: Macromol. Symp. Volume: 317-318 Issue: 1 Pages: 248-258
  • DOI: 10.1002/masy.201200012
  • Peer Reviewed
• [Journal Article] Electrolyte Anion-assisted Charge Transportation in Poly(oxoammonium cation/nitroxyl radical) Redox Gels (2012)
  • Author(s): K. Nakahara, K. Oyaizu, H. Nishide
  • Journal Title: J. Mater. Chem. Volume: 22 Issue: 27 Pages: 13669-13673
  • DOI: 10.1039/c2jm31907a
  • Peer Reviewed
• [Journal Article] Indoline Dye-coupled Polyviologen : Its Electrochemical Property and Electropolymerization (2012)
  • Author(s): N. Sano, M. Suzuki, W. Tomita, K. Oyaizu, H. Nishide
  • Journal Title: Jpn. J. Appl. Phys Volume: 51 Issue: 10S Pages: 10NE17-10NE17
  • DOI: 10.1143/jjap.51.10ne17
  • NAID: 210000141519
  • Peer Reviewed
• [Journal Article] Nitroxide Radical Molecules as Highly Reactive Redox Mediators in Dye-sensitized Solar Cells (2012)
  • Author(s): F. Kato, A. Kikuchi, T. Okuyama, K. Oyaizu, H. Nishide
  • Journal Title: Angew. Chem. Int. Ed., Volume: 124 Issue: 40 Pages: 10324-10327
  • DOI: 10.1002/ange.201205036
  • Peer Reviewed
• [Journal Article] BODIPY-sensitized Photocharging of Anthraquinone-populated Polymer Layers for Organic Photorechargeable Air Battery (2012)
  • Author(s): K. Oyaizu, Y. Niibori, A. Takahashi, H. Nishide
  • Journal Title: J. Inorg. Organomet. Polym. Volume: 23 Issue: 1 Pages: 243-250
  • DOI: 10.1007/s10904-012-9751-3
  • Peer Reviewed
• [Presentation] Charge transport kinetics in a robust radical-substituted polymer/nanocarbon composite electrode (2017)
  • Author(s): 佐藤歓
  • Organizer: APS March Meeting 2017
  • Place of Presentation: アメリカ、ルイジアナ
  • Year and Date: 2017-03-13
  • Int'l Joint Research
• [Presentation] An Alcohol Polymer for Safe and Clean Hydrogen-Storage and -Release (2016)
  • Author(s): 西出宏之
  • Organizer: International Symposium of Innovation on Polymer Science and Technology
  • Place of Presentation: インドネシア、メダン
  • Year and Date: 2016-11-08
  • Int'l Joint Research / Invited
• [Presentation] An Alcohol Polymer for Safe and Clean Hydrogen-Storage and -Release (2016)
  • Author(s): 西出宏之
  • Organizer: International Conference on Advanced Polymeric Materials
  • Place of Presentation: 韓国、済州
  • Year and Date: 2016-10-06
  • Int'l Joint Research / Invited
• [Presentation] Polymers for Electrochemical Energy-Storage and Signal-Amplification Devices (2016)
  • Author(s): 小柳津研一
  • Organizer: International Conference on Advanced Polymeric Materials
  • Place of Presentation: 韓国、済州
  • Year and Date: 2016-10-05
  • Int'l Joint Research / Invited
• [Presentation] ラジカルポリマー/SWNT 複合電極の作製と全有機二次電池への適用 (2016)
  • Author(s): 佐藤歓
  • Organizer: 平成28年度繊維学会年次大会
  • Place of Presentation: 日本、東京
  • Year and Date: 2016-06-08
• [Presentation] Dynamic Switching of Nematic/Cholesteric/Smectic Liquid Crystals by Reverside Redox Reactions of Radical Polymer (2016)
  • Author(s): 佐藤歓
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 日本、神戸
  • Year and Date: 2016-05-25
• [Presentation] Fluorenone Polymers: A Reversible Charge- and Hydrogen-Storage Material (2015)
  • Author(s): H. Nishide
  • Organizer: 14th Pacific Polymer conference
  • Place of Presentation: Kauai, USA
  • Year and Date: 2015-12-09
  • Int'l Joint Research / Invited
• [Presentation] Fluorenone Polymers: A Safe and Clean Hydrogen Storage Material (2015)
  • Author(s): H. Nishide
  • Organizer: International Symposium Advanced Polymers
  • Place of Presentation: Yokohama, Japan
  • Year and Date: 2015-10-18
  • Int'l Joint Research / Invited
• [Presentation] Organic Radical Polymers: Their Unique Properties and Potential Applications (2015)
  • Author(s): H. Nishide
  • Organizer: Bayer Lectureship Award
  • Place of Presentation: Texas A&M Univ. , USA
  • Year and Date: 2015-09-23
  • Invited
• [Presentation] Redox Polymer for Organic-based Energy-related Devices (2015)
  • Author(s): H. Nishide
  • Organizer: 7th East Asia Symposium on Functional Dyes and Advanced Materials
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2015-09-02
  • Int'l Joint Research / Invited
• [Presentation] Redox Polymers for Organic-Based Energy-Related Devices (2014)
  • Author(s): H. Nishide
  • Organizer: International Polymer Conference 2014
  • Place of Presentation: Tsukuba
  • Year and Date: 2014-12-04
  • Invited
• [Presentation] Redox Polymers for Soft Energy Devices (2014)
  • Author(s): H. Nishide
  • Organizer: Federation of Asian Polymer Societies Symposium 201
  • Place of Presentation: Pune, India
  • Year and Date: 2014-10-30
  • Invited
• [Presentation] Organic Radical Batteries (2014)
  • Author(s): H. Nishide
  • Organizer: Gesellschaft Deutscher Chemiker
  • Place of Presentation: Jena, Germany
  • Year and Date: 2014-09-15
  • Invited
• [Presentation] Radical Polymers as an Ecomaterial (2014)
  • Author(s): H. Nishide
  • Organizer: International Symposium on Ecomaterials
  • Place of Presentation: Kunming, China
  • Year and Date: 2014-08-23
  • Invited
• [Presentation] 有機ラジカル型色素増感太陽電池の高機能化 (2014)
  • Author(s): 小柳津研一, 西出宏之
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋
  • Invited
• [Presentation] 有機ラジカル高分子の創製と機能開拓 (2014)
  • Author(s): 西出宏之
  • Organizer: 日本化学会第94回春季年会
  • Place of Presentation: 名古屋
  • Invited
• [Presentation] ラジカルメディエータを用いた有機太陽電池 (2013)
  • Author(s): 小柳津研一
  • Organizer: 光機能材料研究会第43回講演会
  • Place of Presentation: 東京
  • Invited
• [Presentation] 創電･エネルギー貯蔵分野における高分子未来材料 (2013)
  • Author(s): 小柳津研一
  • Organizer: 第58回高分子夏季大学
  • Place of Presentation: 広島
  • Invited
• [Presentation] 有機ラジカル型色素増感太陽電池-電荷輸送の基礎と応用 (2013)
  • Author(s): 小柳津研一
  • Organizer: 光化学協会370-01光化学応用講座
  • Place of Presentation: 東京
  • Invited
• [Presentation] ラジカルイオン電池の最新動向 (2013)
  • Author(s): 小柳津研一, 西出宏之
  • Organizer: 高分子学会第22回ポリマー材料フォーラム
  • Place of Presentation: 東京
  • Invited
• [Presentation] Redox Polymer-mediated/ Dye-sensitized Solar Cells (2013)
  • Author(s): H. Nishide
  • Organizer: 3rd Polymer Congress of FAPS
  • Place of Presentation: Bangaluru, India
  • Invited
• [Presentation] Redox Polymer-mediated/ Dye-sensitized Solar Cells (2013)
  • Author(s): H. Nishide
  • Organizer: 15th IUPAC International Symposium on Macromolecular Complexes
  • Place of Presentation: Clemson, SC, USA
  • Invited
• [Presentation] Radical Polymers toward an Organic-Based Rechargeable Battery and Photovoltaic Cell (2013)
  • Author(s): H. Nishide
  • Organizer: ACS National Meeting
  • Place of Presentation: Indianapolis, USA
  • Invited
• [Presentation] Well-Controlled Anionic Polymerization of TEMPO-Radical Monomers (2013)
  • Author(s): H. Nishide, T. Sukegawa, K. Oyaizu
  • Organizer: East Asian Symposium on Polymers for Advanced Technologies
  • Place of Presentation: Vladivostok, Russia
  • Invited
• [Presentation] Visualization of O2 and CO2 Distribution in Operating Fuel Cells (2013)
  • Author(s): H. Nishide
  • Organizer: International Conference on Fuel Cells and Hydrogen Technology
  • Place of Presentation: Yogyakarta, Indonesia
  • Invited
• [Presentation] Redox Polymer-mediated/ Dye-sensitized Solar Cells (2013)
  • Author(s): H. Nishide
  • Organizer: 13th Pacific Polymer Conference
  • Place of Presentation: Gaoshan, Taiwan
  • Invited
• [Presentation] Polymers for Energy Storage (2013)
  • Author(s): K. Oyaizu
  • Organizer: POLYCHAR 21, World Forum on Advanced Materials
  • Place of Presentation: Gwangju (Korea)
  • Invited
• [Presentation] 有機ラジカル型色素増感太陽電池 (2013)
  • Author(s): 小柳津研一, 西出宏之
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津
  • Invited
• [Presentation] Polymers for Energy Storage Ecomaterials (2012)
  • Author(s): K. Oyaizu
  • Organizer: The 1st International Symposium on Polymer Ecomaterials (PEM 2012)
  • Place of Presentation: Changchun (China)
  • Invited
• [Presentation] 蓄電ポリマーの設計と有機ラジカル電池･空気二次電池への応用 (2012)
  • Author(s): 小柳津研一
  • Organizer: 高分子学会12-3ポリマーフロンティア21
  • Place of Presentation: 東京
  • Invited
• [Presentation] 有機空気二次電池: 蓄電･導電ポリマーとデバイス設計 (2012)
  • Author(s): 小柳津研一
  • Organizer: 平成24年度化学系学協会東北大会, 高分子コロキウム
  • Place of Presentation: 秋田
  • Invited
• [Presentation] Radical Molecules as Highly Reactive Mediators for Dye-Sensitized Solar Cell (2012)
  • Author(s): K. Oyaizu, H. Nishide, F. Kato
  • Organizer: The Third International Organic Excitonic Solar Cell Conference (IOESC2012)
  • Place of Presentation: Coolum (Australia)
  • Invited
• [Presentation] A Plastic Rechargeable Battery and Photovoltaic Cell Based on Radical Polymers (2012)
  • Author(s): H. Nishide
  • Organizer: Plastic Electronics Symposium
  • Place of Presentation: Changchun (China)
  • Invited
• [Presentation] Radical Polymers as a Cathode Active Material of Lithium Ion Batteries (2012)
  • Author(s): H. Nishide
  • Organizer: 16th International Meeting on Lithium Batteries
  • Place of Presentation: Jeju (Korea)
  • Invited
• [Presentation] Robust and Efficient Charge Storage by Radical Polymer Grafting around Carbon Nanotubes (2012)
  • Author(s): H. Nishide
  • Organizer: 6th International Symposium on Macro-and Supramolecular Architectures and Materials
  • Place of Presentation: Coimbator (India)
  • Invited
• [Book] “高分子ラジカル電池”「分子磁性の新展開」 (2014)
  • Author(s): 小柳津研一, 西出宏之
  • Total Pages: 6
  • Publisher: 化学同人
• [Book] “Organic Batteries”, Encyclopedia of Sustainability Science and Technology, ed by R. A. Meyers (2012)
  • Author(s): H. Nishide, K. Oyaizu
  • Total Pages: 8
  • Publisher: Springer
• [Book] “Polyradicals in Batteries”, Encyclopedia of Radicals in Chemistry, Biology and Materials, ed by C. Chatgilialoglu, A. Studer (2012)
  • Author(s): K. Oyaizu, H. Nishide
  • Total Pages: 9
  • Publisher: Wiley
• [Book] “有機ラジカル電池” 『最先端電池と材料』, 最先端材料システムワンポイントシリーズ, 高分子学会編 (2012)
  • Author(s): 小柳津研一, 西出宏之
  • Total Pages: 8
  • Publisher: 共立出版
• [Patent(Industrial Property Rights)] ベンゾジチオフェンキノンポリマー、電荷貯蔵材料、電極活物質、電極、及び電池 (2013)
  • Inventor(s): 西出宏之他
  • Industrial Property Rights Holder: 西出宏之他
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2013-042822
  • Filing Date: 2013-03-05