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Chemical activity of edge-atom rich carbon nanospaces of quasi high pressure effect

Research Project

Project/Area Number 24241038
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionShinshu University

Principal Investigator

KANEKO Katsumi  信州大学, 先鋭領域融合研究群 環境・エネルギー材料科学研究所, 特別特任教授 (20009608)

Co-Investigator(Kenkyū-buntansha) FUJIMORI Toshihiko  信州大学, 先鋭領域融合研究群環境・エネルギー材料科学研究所, 准教授(特定雇用) (60586824)
ITOH Tsutomu  千葉大学, 分析センター, 特任助教 (40586822)
MINAMI Daiki  信州大学, 先鋭領域融合研究群環境・エネルギー材料科学研究所, 博士研究員 (20642060)
TERRONES Mauricio  信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 特別特任教授 (20597877)
CRUZ Rodolfo  信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 准教授(特定雇用) (30597878)
FERDINAND Tristan  信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 研究員 (40597879)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥46,410,000 (Direct Cost: ¥35,700,000、Indirect Cost: ¥10,710,000)
Fiscal Year 2014: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Fiscal Year 2013: ¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000)
Fiscal Year 2012: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Keywordsナノ空間 / 端原子 / 協奏効果 / ナノチューブ / カーボン / 吸着 / 水 / メタン / カーボンナノ空間 / ナノグラフェン / 高圧効果 / 細孔構造評価 / 直線状硫黄 / 水分子吸着 / イオン液体 / メタンハイドレート / 反応促進 / 混合原子価構造 / 金属硫黄 / グラフェン細孔体 / カーボンナノチューブ / 超高圧効果 / ナノ細孔分子場 / カーボンエッジ原子 / 金属物性 / 高圧合成反応 / 化学活性
Outline of Final Research Achievements

The aim of this study is to elucicate the cooperative effect of graphene-based nanospaces and edge carbons on surface activity. We prepared the nanoporous graphene monolith of the high surface area of 2000 m2/g from edge carbon-rich nanographenes, which shows high water adsorption activity. The nanphthalene-derivative(ND)s as the model of edge carbon-rich molecules were doped in the interstitial spaces of single wall carbon nanotube bundles; the ND-doping increases the electrical conductivity by 50 times and enhances CO2 adsorptivity.
We prepared atomically 1D sulfur chain crystal of metallicity inside carbon nanotube below 0.1 MPa, while the metallica sulfur must be prepared under the compression with more than 90 GPa in the bulk phase. It was found that nanoporous carbon having small mesopores accelerated the formation of methane hydrate by more than 10 times.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (32 results)

All 2015 2014 2013 2012 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Acknowledgement Compliant: 6 results,  Open Access: 6 results) Presentation (12 results) (of which Invited: 7 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] CO2-pressure swing activation for efficient production of highly porous carbons2015

    • Author(s)
      S. Wang, K. Kaneko
    • Journal Title

      Carbon

      Volume: 85 Pages: 245-248

    • DOI

      10.1016/j.carbon.2015.01.004

    • NAID

      120007101483

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Comparative pore structure analysis of highly porous graphene monoliths treated at different temperatures with adsorption of N2 at 77.4 K and of Ar at 87.3 K and 77.4 K2015

    • Author(s)
      S. Wang, D. Minami, K. Kaneko
    • Journal Title

      Micro. Meso. Mater.

      Volume: 209 Pages: 72-78

    • DOI

      10.1016/j.micromeso.2015.01.014

    • NAID

      120007101482

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Methane hydrate formation in confined nanospace can surpass nature2015

    • Author(s)
      M. E. Casco, J. Silvestre-Albero, A. J. Ramirez-Cuesta, F. Rey, J. L. Jorda, A. Bansode, A. Urakawa, I. Pera, M. Martinez-Escandel, K. Kaneko, F. Rodriguez-Reinoso
    • Journal Title

      Nature Comm.

      Volume: 6 Issue: 1 Pages: 6432-6440

    • DOI

      10.1038/ncomms7432

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of the size and position of ion-accessible nanoholes on the specific capacitance of single-walled carbon nanohorns for supercapacitor applications2015

    • Author(s)
      C.-M. Yang, Y.-M. Kim, J. Miyawaki, Y. A. Kim, M. Yudasaka, S. Iijima, K. Kaneko
    • Journal Title

      J. Phys. Chem.C

      Volume: 119 Issue: 6 Pages: 2935-2940

    • DOI

      10.1021/jp510630e

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] High pressure methane storage in porous materials: Are carbon materials in the pole position ?2015

    • Author(s)
      M. E. Casco, M. Martinez-Escandell, E. Gadea-Ramosi, K. Kaneko, J. Silvestre-Albero, F. Rodriguez-Reinoso
    • Journal Title

      Chem. Mater.

      Volume: 27 Issue: 3 Pages: 959-964

    • DOI

      10.1021/cm5042524

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Graphitic nanopores: Water capture in carbon cuboids.2015

    • Author(s)
      K. Kaneko
    • Journal Title

      Nature Chem.

      Volume: 7 Issue: 3 Pages: 194-196

    • DOI

      10.1038/nchem.2193

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-semiconductor transition like behavior of naphthalene-doped single wall carbon nanotube bundles2014

    • Author(s)
      F. Khoerunnisa, A. Morelos-Gomez, H. Tanaka, T. Fujimori, D. Minami, R. Kukobat,T. Hayashi , S.Y. Hong, Y.C. Choi, M. Miyahara, M. Terrones, M. Endo, K. Kaneko
    • Journal Title

      Faraday Dis.

      Volume: 273 Pages: 145-156

    • NAID

      120007101484

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 461. Enhanced CO2 adsorptivity of SWCNT by polycyclic aromatic hydrocarbon intercalation2014

    • Author(s)
      F. Khoerunnisa・D. Minami・T. Fujimori・S.Y. Hong・Y.C. Choi・H. Sakamoto・M. Endo・K. Kaneko
    • Journal Title

      Adsorption

      Volume: 20 Issue: 2-3 Pages: 301-309

    • DOI

      10.1007/s10450-013-9578-4

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Activation routes for high surface-area graphene monoliths from graphene oxide colloids2014

    • Author(s)
      S. Wang, F. Tristan, D. Minami, T. Fujimori, R. Cruz-Silva, M.Terrones, K. Takeuchi , K. Teshima, F. Rodriguez-Reinoso, M. Endo, K. Kaneko
    • Journal Title

      Carbon

      Volume: 76 Pages: 220-231

    • DOI

      10.1016/j.carbon.2014.04.071

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 456. Conducting Linear Chains of Sulfur inside Carbon Nanotubes2013

    • Author(s)
      T. Fujimori, A. Morelos-Gómez, Z. Zhu, H. Muramatsu, R. Futamura, K. Urita, M. Terrones, T. Hayashi, M. Endo, S. Y. Hong, Y. C. Choi, D. Tománek , K. Kaneko
    • Journal Title

      Nature Comm.

      Volume: 4 Issue: 1 Pages: 2162-2169

    • DOI

      10.1038/ncomms3162

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 459. Separation of CO2-CH4 mixtures on defective single walled carbon nanohorns-tip does matter2013

    • Author(s)
      S. Furnaiak, A. P. Terzyk, P. Kowalxzyk, K. Kaneko, P. A. Gauden
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 15 Issue: 39 Pages: 16468-16476

    • DOI

      10.1039/c3cp52342j

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 455. Formation and Properties of Selenium Double-Helices inside Double-Wall Carbon Nanotubes: Experiment and Theory2013

    • Author(s)
      T. Fujimori, R. Batista, D. Santos, T. Hayashi, M. Endo, K. Kaneko, D. Tomanek
    • Journal Title

      ACS Nano

      Volume: 7 Issue: 6 Pages: 5607-5613

    • DOI

      10.1021/nn4019703

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vertically Oriented Propylene Carbonate Molecules and Tetraethyl Ammonium Ions in Carbon Slit Pores2013

    • Author(s)
      M. Fukano, T. Fujimori, J. Ségalini, E. Iwama, P.-J. Taberna, T. Iiyama, T. Ohba, H. Kanoh, Y. Gogotsi, P. Simon, K. Kaneko
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 11 Pages: 5752-5757

    • DOI

      10.1021/jp311896q

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Importance of Thrower-Stone-Wales Defects in Rolled and Flat Graphenes from Surface-Enhanced Raman Scattering2012

    • Author(s)
      T. Fujimori, L. R. Radovic, A. B. Silva-Tapia, M. Endo, K. Kaneko
    • Journal Title

      Carbon

      Volume: 50 Issue: 9 Pages: 3274-3279

    • DOI

      10.1016/j.carbon.2011.12.010

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pore Structure Characterization of High Surface Area Graphene-based Monoliths gp of Different Crystallinity with Physical Adsorption2014

    • Author(s)
      S. Wang, D. Minami,T. Fujimori,T. Hayashi, K.Takeuchi, M. Endo,K. Kaneko
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      大野城まどかぴあ(九州大学),福岡
    • Year and Date
      2014-12-08 – 2014-12-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Enhanced Interfacial Functions of Carbon Nanospaces2014

    • Author(s)
      K. Kaneko
    • Organizer
      Physics at The Fall: Phase Transitions in reduced dimensions
    • Place of Presentation
      Ramada Inn on North Forest Rd, Amherst NY, USA
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Carbon Nanospace-Associated Fundamental Energy and Maeterials Science2014

    • Author(s)
      K. Kaneko
    • Organizer
      International Carbon Festival
    • Place of Presentation
      Convention Center, Jeonju, Korea
    • Year and Date
      2014-11-04 – 2014-11-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Metal-semiconductor Transition Like Behavior of Naphthalene-doped SWCNT Bundles2014

    • Author(s)
      F. Khoerunnisa , A. Morelos-Gomez, T. Fujimori D. Minami, R. Kukobat, T. Hayashi, H. Tanaka, S. Y. Hong, Y. C. Choi, M. Terrones, M. Endo, K. Kaneko
    • Organizer
      Faraday Discussion:New Advances in Carbon Nanomaterials
    • Place of Presentation
      Burlington House, London, UK
    • Year and Date
      2014-09-01 – 2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pore Structure Analysis of High Surface Area Graphene-based Monolith2014

    • Author(s)
      S. Wang, D. Minami, T. Fujimori K. Kaneko
    • Organizer
      Carbon2014
    • Place of Presentation
      International Convention Center,Jeju, Korea
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Comparative Nanopore Characterization withAr and N2 with Ar and N2 adsorption at the boiling temperatures2014

    • Author(s)
      R. Futamura,. S.Wang, F. Kohernnisa, D. Minami,T. Ohba,T. Itoh, J. Silvestre-Albero A. Silvestre-Albero, F. Rodriguez-Reinoso,J. P. . Motta,M. Thommes H. Kanoh, S. Mukai, J. F. Rouquerol, K. Kaneko
    • Organizer
      The 10thInternational Symposium on Characterizationof Porous Solids
    • Place of Presentation
      Granada Exhibition and Conference Centre, Granada, Spain
    • Year and Date
      2014-05-11 – 2014-05-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] PHONON-MEDIATED MOLECULAR TRAPPING IN SINGLE WALL CARBON NANOTUBE AND NANORINGS2013

    • Author(s)
      K. Kaneko
    • Organizer
      Workshop on Adsorption in Compliant Solids
    • Place of Presentation
      パリ大学 フランス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ADSORPTION AND DEFECT-SENSITIVE STRUCTURE OF SINGLE WALLED NANOCARBONS2013

    • Author(s)
      K. Kaneko
    • Organizer
      Poromechanics of adsorption" at the 5th Biot Conference on Poromechanics
    • Place of Presentation
      ウイーン大学、オーストリア
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] IN-PORE SUPERHIGH PRESSURE-AIDED ENERGY-SAVING MOLECULAR2013

    • Author(s)
      K. Kaneko
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      Convention Center in Seoul
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Super-high pressure function of carbon nanospaces and its application to organic synthesis2012

    • Author(s)
      K. Kaneko
    • Organizer
      IUMRS-International Conference on Electronic Materials 2012
    • Place of Presentation
      横浜
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] In-pore superhigh pressure effect on solid phase transition and organic crystal synthesis2012

    • Author(s)
      K. Kaneko
    • Organizer
      2012 AIChE Annual Meeting
    • Place of Presentation
      ピッツバーグ、米国
    • Related Report
      2012 Annual Research Report
  • [Presentation] Energy saving-carbon nanospace engineering2012

    • Author(s)
      K. Kaneko
    • Organizer
      10th China-Japan-Korea Joint Symposium on Carbon Materials to Save the Earth
    • Place of Presentation
      広州、中国
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] Electronic Processes in Organic Electronics2015

    • Author(s)
      Toshihiko Fujimori, Fitri Khoerunnisa, Tomonori Ohba, Suzana Gotovac-Atlagic, Hideki Tanaka, and Katsumi Kaneko
    • Total Pages
      432
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] Adsorption Properties, Chapter 5 in Comprehensive Inorganic ChemistryII,2013

    • Author(s)
      15. Y. Hattori, T. Ohba, K. Kaneko
    • Total Pages
      19
    • Publisher
      Elsevier
    • Related Report
      2013 Annual Research Report
  • [Book] Novel Carbon Adsorbent2012

    • Author(s)
      S. Utsumi ,T. Ohba, H. Tanaka, K. Kaneko
    • Publisher
      Elsevier
    • Related Report
      2012 Annual Research Report
  • [Remarks] 信州大学エキゾチック・ナノカーボンの創成と応用プロジェクト拠点、研究者・研究チーム紹介、金子克美

    • URL

      http://www.shinshu-u.ac.jp/project/encs/team/kaneko/

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 単層カーボンナノチューブ、それを含む電極シート、それの製造方法、および、それの分散体の製造方法2014

    • Inventor(s)
      金子克美、藤森利彦、南太規、Fitri K.、Aaron M.G
    • Industrial Property Rights Holder
      信州大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-002667
    • Filing Date
      2014-01-09
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] カーボンナノチューブ及びその製造方法2013

    • Inventor(s)
      金子 克美、藤森 利彦
    • Industrial Property Rights Holder
      信州大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-11-21
    • Related Report
      2013 Annual Research Report
    • Overseas

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Published: 2013-05-15   Modified: 2019-07-29  

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