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Control of edge atomic structure of carbon mono-atomic layer and research of spin-based phenomena and magnet application

Research Project

Project/Area Number 24241046
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionAoyama Gakuin University

Principal Investigator

HARUYAMA Junji  青山学院大学, 理工学部, 准教授 (70296383)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥47,320,000 (Direct Cost: ¥36,400,000、Indirect Cost: ¥10,920,000)
Fiscal Year 2014: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2013: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2012: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Keywordsグラフェン / エッジ / 平坦バンド / 強磁性 / 偏極スピン / 水素終端 / 磁石 / スピントロニクス素子 / グラフェンナノメッシュ / 平坦バンド強磁性 / トンネル磁気抵抗素子 / コバルト電極 / TMR比 / 黒リン / ナノメッシュ / エッジ原子配列 / 終端 / 希少元素フリー磁石 / エッジスピン / フラットバンド強磁性 / 磁性元素フリー磁石 / ナノ細孔アレイ
Outline of Final Research Achievements

We have fabricated graphene nanomesh (GNM), which has honeycomb-like array of nanopores with low defects and low contamination, by non-lithographic method within reproducibility as high as over 70%. Controlling atomic structure of the pore edge to zigzag by critical temperature annealing resulted in realization of flat-band ferromagnetism. High-efficiency GNM magnet, which has the strength was obtained by HSQ resist treatment of this GNM and irradiating electron beam, because mono-hydrogenation of the edge dangling bond was realized through this process. TMR structure was realized by using this magnetic GNM as an electrode and TMR ratio over 20% was realized even at room temperature. These results open doors to rare-magnetic-element free magnets and spintronic devices.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (51 results)

All 2015 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 6 results,  Acknowledgement Compliant: 7 results) Presentation (35 results) (of which Invited: 17 results) Book (6 results) Remarks (2 results)

  • [Journal Article] Tunneling magnetoresistance phenomena utilizing graphene magnet electrodes2014

    • Author(s)
      T. Hashimoto, S. Kamikawa, J. Haruyama, D. Soriano, J. G. Pedersen, S. Roche
    • Journal Title

      Appl.Phys.Lett.

      Volume: 105 Pages: 183111-183111

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Graphene edge spins: -Spintronics and Magnetism in graphene nanomeshes2014

    • Author(s)
      T. Hashimoto, S. Kamikawa, Y. Yagi, J. Haruyama, H. Yang, M. Chshiev
    • Journal Title

      Nanosystems: Physics, Chemistry, Mathmatics Journal

      Volume: 5 Pages: 25-38

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Edge-sensitive semiconductive behaviors in low-defect narrow graphene nanoribbons2014

    • Author(s)
      S. Kamikawa, T. Shimizu, Y. Yagi, J. Haruyama
    • Journal Title

      Nanomaterials and Nanotechnology

      Volume: April 14 Pages: 1-9

    • DOI

      10.5772/58466

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] High-Efficiency Graphene Nanomesh Magnets Realized by Controlling Hydrogenation of Pore Edges2014

    • Author(s)
      T. Kato, T. Nakamura, J. Kamijyo, T. Kobayashi, Y. Yagi, J. Haruyama
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104 Pages: 252410-252410

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electronic Properties of Nanopore Edges of Ferromagnetic Graphene Nanomeshes at High Carrier Densities under Ionic-Liquid Gating2014

    • Author(s)
      T. Hashimoto, S. Kamikawa, Y. Yagi, J. Haruyama
    • Journal Title

      Materials Sciences and Applications

      Volume: 5 Pages: 1-9

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electron-Spin-Based Phenomena Arising from Pore Edges of Graphene Nanomeshes2013

    • Author(s)
      K. Tada, N. Kosugi, K. Sakuramoto, T. Hashimoto, K. Takeuchi, Y. Yagi, J. Haruyama, H. Yang, M. Chshiev
    • Journal Title

      Jorrnal of superconductivity and novel magnetisms

      Volume: 26 Pages: 1037-1037

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Graphene and Graphene Nanomesh Spintronics2013

    • Author(s)
      J. Haruyama
    • Journal Title

      Special Issue on "Carbon Nanoelectronics" in Electronics

      Volume: 2 Pages: 368-386

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Magnetism and spintronics arising from Graphene edges2012

    • Author(s)
      J.Haruyama
    • Journal Title

      Innovative Graphene Technologies: Developments, Characterization and Evaluation

      Volume: 2 Pages: 7-26

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 微量水素終端したグラフェンにおけるスピン軌道相互作用と電子波位相破壊の抑制2015

    • Author(s)
      上條潤一、片桐勇人、加藤建彰、中村壮智、勝本信吾、江澤雅彦、春山純志、B. Ozyilmaz
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 黒リン単原子層の特異な電子物性2015

    • Author(s)
      片桐勇人、牧野竜也、大畠智佳、中村壮智、勝本信吾、江澤雅彦、篠原久典、春山純志
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 黒リン単原子層のエッジ磁性2015

    • Author(s)
      中西雄大, 大畠智佳, 岩城稜麿, 野村くみ子, 江澤雅彦, 篠原久典, 春山純志
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] MoS2 単原子層への電子線照射・構造転移と電子物性2015

    • Author(s)
      牧野竜也、片桐勇人、大畠智佳、中村壮智、勝本信吾、末永知和、春山純志
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン化ゲルゲートを配した金属伝導カーボンナノチューブ膜の電子物性2015

    • Author(s)
      本間友大、菊地涼、山田俊矢、大畠知佳、春山純志、Apparao Rao
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素化グラフェンにおけるスピン注入2015

    • Author(s)
      中村壮智,橋本義昭,春山純志,家泰弘,勝本信吾
    • Organizer
      2014日本物理学会年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Magnetism arising from edges of nanomesh of mono(few)-atomic layered2015

    • Author(s)
      Y. Nakanishi, C. Ohata, R. Iwaki. k. Nomura, M. Ezawa, H. Shinohara, J. Haruyama
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electronic properties of thin films of all-metallic carbon nanotubes2015

    • Author(s)
      T. Honma, R. Kikuchi, S. Yamada, C. Ohata, M. Koyata, J. Haruyama, A. Rao
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electron-wave dephasing suppressed by spin-orbit interaction in slightly hydrogenated graphene within a topological insulating regime2015

    • Author(s)
      J. Kamijo, Y. Katagiri, T. Kato, T. Nakamura, S. Katsumoto, M. Ezawa, B. Ozyilmaz,
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Anomalous electronic properties of mono(few)-atomic layers of black phosphorus2015

    • Author(s)
      Y. Katagiri, T. Makino, C. Ohata, T. Nakamura, S. Katsumoto1, M. Ezawa, H. Shinohara,
    • Organizer
      第48回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Graphene spintronics; -graphene as topological insulator-2014

    • Author(s)
      J. Haruyama
    • Organizer
      Asian conference on Nanotechnology
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-12-16 – 2014-12-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene and graphene nanomesh spintronics2014

    • Author(s)
      J. Haruyama
    • Organizer
      The 9th international conference on surfaces, coatings, and nanostructured materials
    • Place of Presentation
      Dublin, Ireland
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Self-assembled graphene nanomesh spintronics and magnetism2014

    • Author(s)
      J. Haruyama
    • Organizer
      The 5th international conference on Nanostructures self-assembly
    • Place of Presentation
      Marseille, France
    • Year and Date
      2014-07-07 – 2014-07-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene spintronics as topological insulator2014

    • Author(s)
      J. Haruyama
    • Organizer
      Graphene Week 2014; The 8th International Conference on the Fundamental Science of Graphene and Applications of Graphene-Based Devices
    • Place of Presentation
      Gothenburg, Sweden
    • Year and Date
      2014-06-23 – 2014-06-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] opological insulator, spintronics, and magnetism in graphenes2014

    • Author(s)
      J. Haruyama
    • Organizer
      International Conference on Superconductivity and Magnetism
    • Place of Presentation
      Antalya, Turkey
    • Year and Date
      2014-04-27 – 2014-05-02
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene spintronic and magnetic devices2013

    • Author(s)
      J.Haruyama
    • Organizer
      The 17th International workshop on the Physics of Semiconductor Devices
    • Place of Presentation
      Noida, India
    • Year and Date
      2013-12-01 – 2013-12-05
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 単原子膜研究開発の現状と将来2013

    • Author(s)
      春山純志
    • Organizer
      科学技術振興機構 戦略的創造研究推進事業準備会議
    • Place of Presentation
      科学技術振興機構
    • Year and Date
      2013-10-07
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Spin-based phenomena in graphenes2013

    • Author(s)
      J.Haruyama
    • Organizer
      The 3rd Annual World Congress of Nano-Science &Technology
    • Place of Presentation
      China
    • Year and Date
      2013-09-26 – 2013-09-28
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] SiC熱分解形成グラフェンへの強磁性ナノ細孔アレイの創製とその物性2013

    • Author(s)
      加藤建彰, 上條潤一, 岸本将広, 橋本泰樹, 八木優子, 春山純志, 日比野浩樹, 藤田和博,橋本義昭, 勝本信吾、家泰弘
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2013-09-25 – 2013-09-28
    • Related Report
      2013 Annual Research Report
  • [Presentation] 強磁性グラフェンナノ細孔アレイで創製したTMR構造の物性2013

    • Author(s)
      上條潤一, 加藤建彰, 橋本泰樹, 上川正太, 八木優子, 春山純志, 藤田和博, 橋本義昭,勝本信吾, 家泰弘
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2013-09-25 – 2013-09-28
    • Related Report
      2013 Annual Research Report
  • [Presentation] Graphene spintronics2013

    • Author(s)
      J.Haruyama
    • Organizer
      International conference on Nanoscale Magnetism
    • Place of Presentation
      Istanbul, Turkey
    • Year and Date
      2013-09-02 – 2013-09-06
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Spintronics, magnetism, and superconductivity in graphenes and carbon nanotubes2013

    • Author(s)
      J.Haruyama
    • Organizer
      University Colledge of London, Seminer
    • Place of Presentation
      London, UK
    • Year and Date
      2013-08-06
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Graphene spintronics on graphene edges2013

    • Author(s)
      J.Haruyama
    • Organizer
      International conference on Advanced Carbon Nanostructures
    • Place of Presentation
      St.Petersberg, Russia
    • Year and Date
      2013-07-01 – 2013-07-05
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Graphene spintronics2013

    • Author(s)
      J. Haruyama
    • Organizer
      International conference on Electronic Materials and Applications
    • Place of Presentation
      Orland, Florida
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Spintronics and magnetism using graphene edge spins2013

    • Author(s)
      J. Haruyama
    • Organizer
      International conference on emerging technologies; Micro to Nano
    • Place of Presentation
      Goa, India
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Magnetism and spintronics arising from graphene edges2012

    • Author(s)
      J. Haruyama
    • Organizer
      International Conference on Superconductivity and Magnetism,
    • Place of Presentation
      Istanbul, Turkey
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Magnetism and spintronics arising from graphene edges2012

    • Author(s)
      J. Haruyama
    • Organizer
      4th Worldwide Universities Network (WUN) International Conference on Spintronics
    • Place of Presentation
      Sydney, Australia
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Graphene edges: Physics and applications2012

    • Author(s)
      J. Haruyama
    • Organizer
      C2C Workshop: Progress in Nanoscience and Materials
    • Place of Presentation
      Shang hai, China
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Graphene magnets and spintronics arising from graphene edges2012

    • Author(s)
      J. Haruyama
    • Organizer
      The 5th Szeged International Workshop on Advances in Nanoscience
    • Place of Presentation
      Szedo, Hungary
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Novel spintronic phenomena arising from pore-edge polarized spins of ferromagnetic graphene nanomeshes2012

    • Author(s)
      N. Kosugi, Y. Hashimoto, K. Sakuramoto, K. Takeuchi, S.Kamikawa, Y. Yagi, J. Haruyama, Y. Hashimoto, K. Fujita, Y.Kato, S. Katsumoto, Y. Iye, P. Zhao, S. Maruyama, A. Rao
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェンシンポジウム
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Magnetic behaviors sensitive to foreign-atom termination of pore-edge in graphen nanomeshes2012

    • Author(s)
      K. Takeuchi, K. Sakuramoto, N. Kosugi, Y. Hashimoto, Y. Yagi, J. Haruyama, P. Zhao, S. Maruyama, A. Rao
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェンシンポジウム
    • Place of Presentation
      東北大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 電気二重層を含む各種方法でキャリアドープしたナノチューブ薄膜の磁化・電気特性2012

    • Author(s)
      中村悠紀、竹内啓悟、上川正太、八木優子、春山純志、藤田和博、加藤悠人、橋本義昭、勝本信吾、家泰弘、T.Thurakitseree、丸山茂夫、A.Rao
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 電気二重層を形成した低欠陥グラフェンナノメッシュの物性2012

    • Author(s)
      里見槙平、中村悠紀、上川正太、春山純志、藤田和博、加藤悠人、橋本義昭、勝本信吾、家泰弘、趙 沛、丸山茂夫、A.Rao
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低欠陥グラフェンナノメッシュの細孔エッジ起因異常磁気抵抗2012

    • Author(s)
      小杉直輝、櫻元健志、上川正太、橋本泰樹、春山純志、藤田和博、加藤悠人、橋本義昭、勝本信吾、家泰弘、趙 沛、丸山茂夫、A.Rao
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低欠陥グラフェンナノメッシュのキャリアドープ細孔エッジと磁化特性2012

    • Author(s)
      竹内啓悟、櫻元健志、上川正太、八木優子、春山純志、趙 沛、丸山茂夫、A.Rao
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Book] Graphene spintronics and magnetism:The Graphene Optoelectronics. Synthesis, Characterization, Properties, and Applications2014

    • Author(s)
      J. Haruyama
    • Total Pages
      15
    • Publisher
      WILEY-VCH Verlag
    • Related Report
      2014 Annual Research Report
  • [Book] Carbon-based new superconductors; Toward high Tc2014

    • Author(s)
      J. Haruyama
    • Total Pages
      302
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2014 Annual Research Report
  • [Book] MATERIAL STAGE:グラフェン磁石創製の可能性:希少磁性元素を用いないウエアラブル磁石2013

    • Author(s)
      春山純志
    • Total Pages
      20
    • Publisher
      技術情報協会
    • Related Report
      2013 Annual Research Report
  • [Book] 導電・絶縁材料の電気および熱伝導特性制御2013

    • Author(s)
      春山純志
    • Total Pages
      293
    • Publisher
      Science & Nanotechnology社
    • Related Report
      2012 Annual Research Report
  • [Book] 高温超伝導現象と用途開発最前線2013

    • Author(s)
      春山純志
    • Total Pages
      542
    • Publisher
      (株)エヌ・ティー・エス出版
    • Related Report
      2012 Annual Research Report
  • [Book] グラフェンの機能と応用展望II2012

    • Author(s)
      春山純志
    • Total Pages
      271
    • Publisher
      (株)シーエムシー出版
    • Related Report
      2012 Annual Research Report
  • [Remarks] 春山研究室ホームページ

    • URL

      http://www.ee.aoyama.ac.jp/haru-lab/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 春山研究室ホームページ

    • URL

      http://www.ee.aoyama.ac.jp/haru-lab/

    • Related Report
      2012 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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